• 제목/요약/키워드: cis-trans photoisomerization

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나노구조 유기초박막의 광변위특성 (Photo Displacement Properties of Nano structure Organic Ultra Thin Films)

  • 송진원;최영일;조수영;김영근;이경섭
    • 한국전기전자재료학회:학술대회논문집
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    • 한국전기전자재료학회 2004년도 추계학술대회 논문집 Vol.17
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    • pp.468-471
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    • 2004
  • Monolayers of lipids on a water surface have attracted much interest as models of biological membranes, but also as precursors of multilayer systems premising many technical applications. Until now, many methodologies have been developed in order to gain a better understand. Photoisomerization in monolayers of a novel azobenzene compound, azobenzene dendrimer, was investigated for the first time by means of the absorption spectrum and Maxwell displacement current (MDC) technique. Dendrimers are well-defined macromolecules exhibiting a tree-like structure, first derived by the cascade molecule approach. According to the absorption spectrum, trans-to-cis conversion ratio was estimated to the third generation of azobenzene dendrimer deposited onto a glass substrate. Temperature-dependent induced charge with trans-cis isomerization was also measured by means of MDC technique.

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아조벤젠 유기단분자의 광제어에 관한 연구 (A Study on the Light Control of Azobenzene Organic Monolayers)

  • 김성진;정헌상;이경섭
    • 한국전기전자재료학회:학술대회논문집
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    • 한국전기전자재료학회 2000년도 춘계학술대회 논문집 전자세라믹스 센서 및 박막재료 반도체재료 일렉트렛트 및 응용기술
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    • pp.139-142
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    • 2000
  • Displacement current was generated in the light stimulus. Solution of azobenzene molecules (8A5H) have to character trans-to-cis. The Maxwell displacement current measuring technique has been applied for the investigation of azobenzene organic thin films under alternating photoirradiation with ultraviolet($\lambda_1$) and visible($\lambda_2$) light. also, As laser beam(630~670nm) investigate light response. As result, ultraviolet($\lambda_1$) and visible($\lambda_2$) light see photoisomerization response, but laser beam not appear photoisomerization in current that differ wave range reagent.

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지방산과 인지질의 혼합비에 따른 단분자 LB막의 광이성질화 현상에 관한 연구 (Photoisomerization of Monolayer LB Films mixed with Fatty Acid and Phospholipid at mixture ratios)

  • 박근호;강동완;김성일;박태곤
    • 한국전기전자재료학회:학술대회논문집
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    • 한국전기전자재료학회 2000년도 하계학술대회 논문집
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    • pp.479-482
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    • 2000
  • We investigated UV-vis absorbances to observe photoisimerization and effect of temperature using the mixture solution in chloroform and the LB monolayer mixed with DLPE and 8A5H containing azobenzene which shows reversible cis-trans isomerization irradiated by alternate lights. We could find that the absorption spectrum of the mixtures solution and LB monolayer was reversibly induced to photoisomerization irradiated by Uv of both and visible lights, in addition the absorbance by alternate temperatures.

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나노구조 덴드리머의 변위특성 (Displacement Properties of Nano Structure Dendrimer)

  • 송진원;이경섭
    • 대한전기학회:학술대회논문집
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    • 대한전기학회 2004년도 하계학술대회 논문집 C
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    • pp.1724-1726
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    • 2004
  • Monolayers of lipids on a water surface have attracted much interest as models of biological membranes, but also as precursors of multilayer systems promising many technical applications. Until now, many methodologies have been developed in order to gain a better understand. Photoisomerization in monolayers of a novel azobenzene compound, azobenzene dendrimer, was investigated for the first time by means of the absorption spectrum and Maxwell displacement current (MDC) technique. Dendrimers are well-defined macromolecules exhibiting a tree-like structure, first derived by the cascade molecule approach. According to the absorption spectrum, trans-to-cis conversion ratio was estimated to the third generation of azobenzene dendrimer deposited onto a glass substrate. Temperature-dependent induced charge with trans-cis isomerization was also measured by means of MDC technique.

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기능성 LB단분자막의 변위특성에 관한 연구 (A Study on the Displacement Properties of Functional LB Monolayers)

  • 송진원;최영일;이경섭
    • 대한전기학회:학술대회논문집
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    • 대한전기학회 2003년도 추계학술대회 논문집 전기물성,응용부문
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    • pp.114-116
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    • 2003
  • Monolayers of lipids on a water surface have attracted much interest as models of biological membranes, but also as precursors of multilayer systems promising many technical applications. Until now, many methodologies have been developed in order to gain a better understand. Photoisomerization in monolayers of a novel azobenzene compound, azobenzene dendrimer, was investigated for the first time by means of the absorption spectrum and Maxwell displacement current (MDC) technique. Dendrimers are well-defined macromolecules exhibiting a tree-like structure, first derived by the cascade molecule approach. According to the absorption spectrum, trans-to-cis conversion ratio was estimated to the third generation of azobenzene dendrimer deposited onto a glass substrate. Temperature-dependent induced charge with trans-cis isomerization was also measured by means of MDC technique.

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${\beta}$-스티릴나프탈렌의 방사화학적 시스-트란스 이성질화 반응 (Radiochemical cis-trans Isomerization of ${\beta}$-Styrylnaphthalene)

  • 심상철
    • 대한화학회지
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    • 제20권4호
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    • pp.290-294
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    • 1976
  • ${\beta}$-스티릴나프타렌의 방사화학적 이성질화 반응을 G값과 방사정류상태를 측정하여 연구하였다. 여기서 얻은 결과와 광화학적 이성질화 반응의 연구결과를 비교함으로써 이 올레핀의 벤젠 용액을 ${\gamma}$-선으로 쪼여주면 들뜬 단일상태와 삼중상태가 다 이성질화 반응에 참여함을 알았다.

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혼합 유기박막의 자격 전류 (Stimulus Current of Mixed Organic Thin Films)

  • 조수영;이경섭
    • 대한전기학회:학술대회논문집
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    • 대한전기학회 2000년도 추계학술대회 논문집 학회본부 C
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    • pp.464-466
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    • 2000
  • In the study We measured the MDC across lipidazobenzene monolayer system was the substrate. We discuss the cis-trans isomerization in Langmuir-Blodgett(LB) films and examine the relationship between the structure of mixed LB films and the generation of MDCs due to photoisomerization. As results, mixed induce monolayer of view to memory and switching, it's own function by particles level think. Also, transmission results of stimulus signal it's form by current to appear.

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Reversible Optical Information Stroage of Self-Assembled Alternating Multilayer Films: Bipolar Amphiphile-Polyelectrolyte

  • 홍종달;박응수;박애리
    • Bulletin of the Korean Chemical Society
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    • 제19권11호
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    • pp.1156-1160
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    • 1998
  • Alternating multilayer films of a cationic bipolar amphiphile and an anionic polyelectrolyte were prepared by a self-assembly method based on electrostatic attraction between opposite charges. The bipolar amphiphile contains an azobenzene unit in order to allow for a trans-cis photoisomerization to take place. Optical birefringence or dichroism was induced in the self-assembled film upon linearly polarized light irradiation. This dichroism could be reversibly written and erased by irradiation with light of an appropriate wavelength.

Optically Induced Anisotropy in Photoresponsive Sol-Gel Matrix Bearing a Silylated Disperse red 1

  • 최동훈;조강진;차영관;오상준
    • Bulletin of the Korean Chemical Society
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    • 제21권12호
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    • pp.1222-1226
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    • 2000
  • We synthesized the simple triethoxysilanes (SGDR1) bearing a disperse red 1 for thin film fabrication. The thin films were prepared using the solution of SGDR1 after hydrolysis and condensation. The films were annealed at two different temperatures such as $150^{\circ}C$ and $200^{\circ}C$. Trans-to-cis photoisomerization was observed under the exposure of 532 nm light with UV-Vis absorption spectroscopy. The kinetic study of photoisomerization was performed in the film. Reorientation of the polar azobenzene molecules induced optical anisotropy under a linearly polarized light at 532 nm. The effect of aggregation of the chromophores and annealing of the silicon oxide in the matrix were studied on the dynamic properties of isomerization and induced birefringence.

의료용 초박막 액정의 광배향 제어와 광변위 전류 특성 (Properties of Photo-regulation of Liquid Crystal Alignment and Generation of Maxwell-displacement-current for Application with a Medical Engineering Device)

  • 이호식;안준호;김우연;;이원재
    • 한국전기전자재료학회논문지
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    • 제19권12호
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    • pp.1160-1166
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    • 2006
  • Maxwell-displacement-current (MDC) measuring technique has been applied for the investigation of monolayers of poly(vinyl alcohol)s bearing azobenzene side-chains (6Az5PVA) mixed with p-pentyl-p'-cyano-biphenyls (5CBs) on a water surface. For mixed monolayers containing trans-form 6Az5PVA and LCs, displacement current due to photo isomerization was not generated with alternative photo-irradiation with UV and svisible light. In contrast, for mixed monolaters containing cis-form 6Az5PVA and LCs, displacement current was generated. Finally, it was found that the alignment layers deposited in cis-form could photoregualte the orientation of LCs.