Journal of the Korean Chemical Society (대한화학회지)

Korean Chemical Society (대한화학회)
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Radiochemical cis-trans Isomerization of ${\beta}$-Styrylnaphthalene

${\beta}$-스티릴나프탈렌의 방사화학적 시스-트란스 이성질화 반응

  • Sang Chul Shim (Department of Chemical Science, The Korea Advanced Institute of Science) ;
  • George S. Hammond (Department of Chemistry, University of California)
  • 심상철 (한국과학원 화학 및 화학공학과) ;
  • Published : 1976.08.30
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Abstract

Radiation-induced cis-trans isomerization of ${\beta}$-styrylnaphthalene is studied by determination of G values and the radiostationary states. The results are compared with data obtained in direct and sensitized photoisomerization of the compound. Both the excited singlet and triplet states are involved in the isomerization of ${\beta}$-styrylnaphthalene in the radiolysis of benzene solution.

${\beta}$-스티릴나프타렌의 방사화학적 이성질화 반응을 G값과 방사정류상태를 측정하여 연구하였다. 여기서 얻은 결과와 광화학적 이성질화 반응의 연구결과를 비교함으로써 이 올레핀의 벤젠 용액을 ${\gamma}$-선으로 쪼여주면 들뜬 단일상태와 삼중상태가 다 이성질화 반응에 참여함을 알았다.

Keywords

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