• Journal of the Korea Organic Resources Recycling Association
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• v.30 no.4
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• pp.67-83
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• 2022

Biochar is a carbon material produced through the pyrolysis of agricultural biomass with limited oxygen condition. It has been suggested to enhance the carbon sequestration and mineralization of soil carbon. Objective of this study was to investigate soil potential carbon mineralization and carbon dioxide(CO₂) emissions in different soils cooperated with barely straw and livestock manure biochars in the closed chamber. The incubation was conducted during 49 days using a closed chamber. The treatments consisted of 2 different biochars that were originated from barley straw and livestock manure, and application amounts were 0, 5, 10 and 20 ton ha^-1 with different soils as upland, protected cultivation, converted and reclaimed. The results indicated that the TC increased significantly in all soils after biochar application. Mineralization of soil carbon was well fitted for Kinetic first-order exponential rate model equation (P<0.001). Potential mineralization rate ranged from 8.7 to 15.5% and 8.2 to 16.5% in the barely straw biochar and livestock manure biochar treatments, respectively. The highest CO₂ emission was 81.94 mg kg^-1 in the upland soil, and it was more emitted CO₂ for barely straw biochar application than its livestock biochar regardless of their application rates. Soil amendment of biochar is suitable for barely straw biochar regardless of application rates for mitigation of CO₂ emission in the cropland.

• Korean Journal of Environmental Agriculture
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• v.34 no.3
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• pp.155-160
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• 2015

BACKGROUND: Objective of this study was to investigate adsorption characteristics of $NH_4-N$ to biochar produced from rice hull in respective to mitigation of greenhouse gases. METHODS AND RESULTS: $NH_4-N$ concentration was analyzed by UV spectrophotometer. For adsorption experiment of $NH_4-N$ to biochar, input amount of biochar was varied from 0.4 to 10 g/L with 30 mg/L $NH_4-N$ solution. Its adsorption characteristic was investigated with application of Langmuir isotherm. Adsorption amount and removal rates of $NH_4-N$ were decreased at 53.9% and increased at 20.2% with 10 g/L compared to 0.4 g/L, respectively. The sorption of $NH_4-N$ to biochar produced from rice hull was fitted well by a Langmuir model. The largest adsorption amount of $NH_4-N$ ($q_m$) and binding strength constant (b) were calculated as 0.4980 mg/g, and 0.0249 L/mg, respectively. It was observed that dimensionless constant ($R_L$) was 0.58. CONCLUSION: It was indicated that biochar produced from rice hull is favorably absorbed $NH_4-N$, because this value lie within 0< $R_L$ <1.

• Journal of Soil and Groundwater Environment
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• v.22 no.6
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• pp.66-73
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• 2017

Empirical erosion models like Universal Soil Loss Equation (USLE) models have been widely used to make spatially distributed soil erosion vulnerability maps. Even if the models detect vulnerable sites relatively well utilizing big data related to climate, geography, geology, land use, etc within study domains, they do not adequately describe the physical process of soil erosion on the ground surface caused by rainfall or overland flow. In other words, such models are still powerful tools to distinguish the erosion-prone areas at large scale, but physics-based models are necessary to better analyze soil erosion and deposition as well as the eroded particle transport. In this study a physics-based soil erosion modeling system was developed to produce both runoff and sediment yield time series at watershed scale and reflect them in the erosion and deposition maps. The developed modeling system consists of 3 sub-systems: rainfall pre-processor, geography pre-processor, and main modeling processor. For modeling system validation, we applied the system for various erosion cases, in particular, rainfall-runoff-sediment yield simulation and estimation of probable maximum sediment (PMS) correlated with probable maximum rainfall (PMP). The system provided acceptable performances of both applications.

• Journal of Applied Biological Chemistry
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• v.62 no.4
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• pp.407-415
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• 2019

The biological half-life of pesticides applied on crops is the key indicator for ensuring the safety of agricultural products. The biological half-life is affected by the several factors like growing conditions of the crop, climate, application method, and physicochemical properties of pesticides. In this study, the biological half-life was calculated and the degradation rates of six triazole fungicides sprayed on perilla leaves were evaluated. Moreover, the statistical analysis confirmed the correlation between the biological half-life and physicochemical properties of six triazole pesticides. The recoveries of the six pesticides were between 84.8-104.9%, which satisfied the residual pesticide analysis criteria. The biological half-life of six pesticides sprayed on perilla leaves, calculated using the first-order kinetics model, ranged between 6.4-15.1 days. When the biological half-life and the physicochemical properties were correlated using the principal component analysis: pKa and Log P, the biological half-life was found to be affected by PC1. The correlation coefficient between biological half-life and physicochemical properties (pKa), calculated by Spearman rank-order correlation, was R² = -0.928 (p <0.01). Biological half-life has been shown to correlate with pKa. In conclusion, it can be used as a database for the relationship between biological half-life and physicochemical properties and will contribute to ensure safe supply of agricultural products.

• Korean Journal of Environmental Agriculture
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• v.39 no.3
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• pp.171-177
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• 2020

BACKGROUND: Recently, biomass conversion from agricultural wastes to carbon-rich materials such as biochar has been recognized as a promising option to maintain or increase soil productivity, reduce nutrient losses, and mitigate greenhouse gas emissions from the agro-ecosystem. This experiment was conducted to select an optimum conditions for enhancing the NH₄-N adsorption capacity of rice hull activated biochar. METHODS AND RESULTS: For deciding the proper molarity of KOH for enhancing its porosity, biochars treated with different molarity of KOH (0, 1, 2, 4, 6, 8) were carbonized at 600℃ in the reactor. The maximum adsorption capacity was 1.464 mg g^-1, and an optimum molarity was selected to be 6 M KOH. For the effect of adsorption capacity to different carbonized temperatures, 6 M KOH-treated biochar was carbonized at 600℃ and 800℃ under the pyrolysis system. The result has shown that the maximum adsorption capacity was 1.76 mg g^-1 in the rice hull activated biochar treated with 6 M KOH at 600℃ of pyrolysis temperature, while its non-treated biochar was 1.17 mg g^-1. The adsorption rate in the rice hull activated biochar treated with 6 M KOH at 600℃ was increased at 62.18% compared to that of the control. Adsorption of NH₄-N in the rice hull activated biochar was well suited for the Langmuir model because it was observed that dimensionless constant (R_L) was 0.97 and 0.66 at 600℃ and 800℃ of pyrolysis temperatures, respectively. The maximum adsorption amount (q_m) and the bond strength constants (b) were 0.092 mg g^-1 and 0.001 mg L^-1, respectively, for the rice hull activated biochar treated with 6 M KOH at 600℃ of pyrolysis. CONCLUSION: Optimum condition of rice hull activated biochar was 6M KOH at 600℃ of pyrolysis temperature.

• Journal of the Korean earth science society
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• v.45 no.1
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• pp.1-18
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• 2024

This study analyzed the effect of warming on PM_2.5 aerosol production in mid-latitude East Asia during June 2020 using PM_2.5 aerosol anomalies, which were identified by incorporating meteorological and climate data into the Weather Research Forecasting model coupled with Chemistry (WRF-Chem) model. The decadal temperature change trend over a 30-year period (1991-2020) in East Asia showed that recent warming has been greater in summer than in winter. Summer warming in East Asia generated low and high pressure in the lower and upper troposphere, respectively, over China. The boundary between the lower tropospheric low and upper tropospheric high pressure sloped along the terrain from the Tibetan Plateau to Korea. The eastern China, Yellow Sea, and Korean regions experienced a convergence of warm and humid southwesterly airflows originating from the East China Sea with the development of a northwesterly Pacific high pressure. In June 2020, the highest temperatures were observed since 1973 in Korea. Meanwhile, enhanced warming in East Asia increased the production of PM_2.5 aerosols that travelled long distances from eastern China to Korea. PM_2.5 anomalies, which were derived solely by inputting meteorological and climatic data (1991-2020) into the WRF-Chem model and excluding emission variations, showed a positive distribution extending from eastern China to South Korea across the Yellow Sea as well as over the Pacific Northwest. Thus, the contribution of warming to PM_2.5 aerosols in East Asia during June 2020 was more than 50%. In particular, PM_2.5 aerosols were transported from eastern China to Korea through the Yellow Sea, where the warm and humid southwesterly airflows implied wet scavenging of sulfate but promoted nitrate production.

• Journal of the Korean Association of Geographic Information Studies
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• v.15 no.4
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• pp.162-174
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• 2012

To visualize the characteristics of vertical seawater temperature data, in the ocean having 3D spatial characteristics, 2D thematic maps like horizontal seawater temperature distribution map at each depth layer and 3D volume model using 3D spatial interpolation are used. Although these methods are useful to understand oceanographic phenomena visually, there is a limit to analyze the spatial pattern of vertical temperature distribution or the relationship between vertical temperature characteristics and other oceanic factors (seawater chemistry, marine organism, climate change, etc). Therefore, this study aims to determine the spatial distribution characteristics of vertical temperature profiles in the South Sea of Jeju by quantifying the characteristics of vertical temperature profiles by using an algorithm that can extract the thermocline parameters, such as mixed layer depth, maximum temperature gradient and thermocline thickness. For this purpose spatial autocorrelation index (Moran's I) was calculated including mapping of spatial distribution for three parameters representing the vertical temperature profiles. Also, after grouping study area as four regions by using cluster analysis with three parameters, the characteristics of vertical temperature profiles were defined for each region.

• Journal of Appropriate Technology
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• v.7 no.2
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• pp.162-171
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• 2021

The Korean government proposed the K-SDGs in 2019 to promote the UN SDGs, but the role and tasks of science and technology, an important means of implementing the SDGs, have not been materialized. Accordingly, the role of science and technology ODA for the SDGs was established through the Ministry of Science and ICT's policy research project 'Science and Technology ODA Promotion Roadmap for Spreading the New Southern Policy and Realizing the 2030 SDGs'. In addition, goals, strategies, and core tasks for the next 10 years were derived in 10 fields such as water, climate change, energy, and ICT. In this paper, we analyze 30 key tasks of the ODA promotion roadmap for science and technology for the realization of SDGs, and propose mid- and short-term tasks and implementation plans for effective roadmap promotion. Among the key tasks in each field, four common elements were derived: ICT/smartization, a global problem-solving center, cooperation/communication platform, and business model/startup support platform/living lab that can create and integrate roadmap implementation conditions. In addition, the four mid- and short-term tasks, 1) Establishment of science and technology ODA network, 2) Establishment of living lab business platform linked to start-up support business, 3) Local smartization of recipient countries, and 4) Expand and secure sustainability of global problem-solving centers, were set in relation to the implementation of the detailed roadmap. For the derived mid- and short-term tasks, detailed implementation plans based on the ICTization of global problem-solving centers were presented. The implementation of the mid- and short-term tasks presented in this paper can contribute to the more effective achievement of the science and technology ODA roadmap, and it is expected that Korea's implementation of SDGs will also achieve high performance.