• 제목/요약/키워드: chemical water quality

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데이터마이닝 기법을 적용한 취수원 수질예측모형 평가 (Evaluation of Water Quality Prediction Models at Intake Station by Data Mining Techniques)

  • 김주환;채수권;김병식
    • 환경영향평가
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    • 제20권5호
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    • pp.705-716
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    • 2011
  • For the efficient discovery of knowledge and information from the observed systems, data mining techniques can be an useful tool for the prediction of water quality at intake station in rivers. Deterioration of water quality can be caused at intake station in dry season due to insufficient flow. This demands additional outflow from dam since some extent of deterioration can be attenuated by dam reservoir operation to control outflow considering predicted water quality. A seasonal occurrence of high ammonia nitrogen ($NH_3$-N) concentrations has hampered chemical treatment processes of a water plant in Geum river. Monthly flow allocation from upstream dam is important for downstream $NH_3$-N control. In this study, prediction models of water quality based on multiple regression (MR), artificial neural network and data mining methods were developed to understand water quality variation and to support dam operations through providing predicted $NH_3$-N concentrations at intake station. The models were calibrated with eight years of monthly data and verified with another two years of independent data. In those models, the $NH_3$-N concentration for next time step is dependent on dam outflow, river water quality such as alkalinity, temperature, and $NH_3$-N of previous time step. The model performances are compared and evaluated by error analysis and statistical characteristics like correlation and determination coefficients between the observed and the predicted water quality. It is expected that these data mining techniques can present more efficient data-driven tools in modelling stage and it is found that those models can be applied well to predict water quality in stream river systems.

낙동강 수계의 섬유 및 화학 산업폐수로부터 발생하는 미량유해화학물질의 모니터링 (Monitoring of Micro Noxious Chemicals Caused by Fiber and Chemistry Industrial Wastewater on the Nakdong River Water System)

  • 김만일;강미아
    • 지질공학
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    • 제16권2호
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    • pp.145-152
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    • 2006
  • 다양한 산업의 발달은 우리 인간이 사용해야 하는 수자원으로 여러 가지 형태의 위해성을 함유하는 유해화학물질들의 수적 양적 증가를 초래하였다. 이로 인해 효율적인 수자원의 이용을 위해서는 수자원으로 유입되는 오염원의 사전 처리가 필수적인 것으로 인지되어 국내에서도 수자원으로 유입되는 오염물질에 대해 총량으로 방류업체의 수질을 규제하기 시작했다. 그러나 아직까지도 규명되지 않은 화학물질들이 대다수를 차지하므로 이에 대한 모니터링이 매우 중요한 역할로 자리하고 있다. 본 연구에서는 낙동강 수계로 유입되는 섬유 및 화학 산업폐수를 중심으로 미량유해화학물질을 계측하여 이들이 낙동강 수계에 미치는 유해성을 검토하였다. 대상으로 한 7개 업체로부터의 유입수와 방류수에서 검출되는 VOCs(volatile organic compounds) 중에서는 클로로포름(chloroform)이 가장 높은 빈도로 검출되었으며, 동일한 업체에서도 노출수준이 일정하지 않아 이의 관리에 어려움이 예상된다. 그러나 이들 업체의 방류수가 유입되는 하수처리장에서는 콜로로포름의 처리효율이 높아(88% 이상) 낙동강 수계의 영향은 그리 크지 않을 것으로 추정된다. 한편, 섬유/화학관련 산업체의 유입수와 방류수로부터 노출되는 EU지정우선물질에 대해 조사한 결과, 검출현황에 대한 일정한 경향을 찾을 수 없을 뿐만 아니라 국내자료의 축적도 거의 없는 상태임을 감안하여 지속적인 모니터링을 통해 국가정책에 활용 할 수 있는 자료구축을 해 나가야 할 것이다.

가축분뇨 액비 살포가 새만금유역에서의 논토양과 수질에 미치는 영향 (Effect of Livestock Liquid Manure Released at a Rice Field on Quality of Soil and Water in the Saemangeum Watershed)

  • 김미숙;곽동희
    • 상하수도학회지
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    • 제30권1호
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    • pp.19-31
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    • 2016
  • The Saemangeum watershed is required to manage water pollution effectively but the effect of liquid manure (LM) on soil and water quality in the basin is not clearly identified as yet. This study aims at assessing the effect on soil of a rice field and water quality of water bodies near the rice field during rice-crop time period to find out the effect of LM, the effect of rainfall, and the effect of rice-crop environment on soil and water quality by analyzing data of nitrogen components. As a result of the LM distribution, $NO_3-N$ was much higher than other N components in the entire soil layers and it was accelerated by rainfall right after the LM distribution. Compared to chemical fertilizer (CF), LM was slightly affected but still influenced on the surface water quality. During weak rainfall, low nitrogen concentration in topsoil was resulted as NH3-N decreased and Org-N and $NO_3-N$ increased. $NO_3-N$ concentration in the water of irrigation canals increased with time. During intensive rainfall, $NO_3-N$ and Org-N of the soil were measured highly in the submerged condition, while the water quality of the rice field was lower due to flooding into the irrigation canal as well as the growth of the rice plants. Also, total nitrogen was increased more than 7 times and it showed serious water quality deterioration due to LM and excessive fertilizer distribution, and rainfall during all rice-crop processes. The effect of LM on water quality should be studied consistently to provide critical data while considering weather condition, cropping conditions, soil characteristics, and so on.

주거단지 건설이 하천에 미치는 생태영향평가 (Environmental Impact Assessments along with Construction of Residential and Commercial Complex)

  • 안광국;한정호;이재훈
    • 환경영향평가
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    • 제21권5호
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    • pp.631-648
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    • 2012
  • The integrative ecological approaches of chemical assessments, physical habitat modelling, and multi-metric biological health modelling were applied to Gwanpyeong Stream within Gap-Stream watersheds to evaluate environmental impacts on the constructions of residential and commercial complex. For the analysis, the surveys conducted from 45 sites of reference streams within the Gap-Stream watershed and 3 regular sites during 2009 - 2010. Physical habitat health, based on the habitat model of Qualitative Habitat Evaluation Index(QHEI) declined from the headwaters(good - fair condition) to the downstream(poor condition). Chemical water quality, based turbidity and electric conductivity(EC), was degraded toward to the downstream, and especially showed abrupt increases, compared to the values of control streams(CS). Also, concentrations of chlorophyll-a in the downstreams were greater compared to the control stream(CS), indicating an eutrophication. Biological health conditions, based on the Index of Biological Integrity(IBI) using fish assemblages, averaged 19.3 which is judged as a fair condition by the biological criteria of the Ministry of Environment, Korea. The comparisons of model metric values in sensitive species and riffle-benthic species on the Maximum Species Richness Line(MSRL) of 45 reference streams indicated a massive disturbances in all sampling locations. Also, tolerance guild and trophic guild analyses suggest that dominances of tolerant species and omnivores were evident, indicating a biological degradation by habitat disturbances and organic matter pollutions. There was no distinct longitudinal variations of IBI model values from the headwater to the downstream in spite of slight chemical and habitat health gradients among the sampling sites. Overall, integrative ecological health(IEH) scores, based on the chemical, physical, and biological parameters, were low compared to the 45 reference streams due to physical and chemical disturbances of massive constructions of the residential and commercial complex. This stream, thus showed a tendency of typical urban streams which are disturbed in the chemical water quality, habitat structures, and biological integrity. Effective stream management plans and restoration strategies are required in this urban stream for improving integrative stream health.

성숙임목수확벌채가 토양의 화학성분과 계류수질에 미치는 영향 (The Effects of Timber Harvesting on Soil Chemical Ingredients and Stream Water Quality)

  • 박재현;우보명;김우룡;안현철;김재수
    • The Korean Journal of Ecology
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    • 제23권1호
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    • pp.9-15
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    • 2000
  • 이 연구는 성숙활엽수림 개벌수확지에서 벌채로 인한 토양의 화학성분 및 계류수질에 미치는 영향을 구명할 목적으로 1993년부터 1998년까지 전남 광양 백운산 지역 천연활엽수림 벌채지(서울대학교 농업생명과학대학 부속 남부연습림내 제 26 임반)에서 수행하였다. 이 연구를 위하여 1993년에 벌채한 13ha의 벌채지와 이와 연접한 비벌채지를 조사?연구대상지로 선정하였다. 이 조사지 에서 1993년부터 1998 년까지 토양의 화학성분과 계류수질을 측정?분석한 결과, 벌채후 1년, 2년이 경과되는 동안 전질소, 치환성 이온인 K/sup +/, Na/sup +/, Ca/sup 2+/, Mg/sup 2+/은 벌채전 보다 양적으로는 감소하였으며, 벌채후 5년이 경과된 뒤에는 벌채 2년 경과후 보다 유의적으로 증가하였으나, 토양의 화학성분은 변화하지 않았다. 또한, 벌채 당해년도와 그 다음 해,그리고 벌채후 5년이 경과되었을 때 벌채지 계류수의 BOD, pH등은 하천수질환경기준에 의한 상수원수 1급 기준에 도달하였으며, Cd, Pb, Cu 둥 중금속과 유기인은 검출되지 않았다 계류수의 색도, 탁도, 냄새, 맛, NH/sub 4//sup +/-N, NO/sub 3//sup -/-N, 일반세균수, 대장균군 둥 8개 항목은 먹는 물 수질기준에 적합하여 벌채지 인근지역 주민들이 음용수로 이용하는 데에는 영향이 없는 것으로 해석되었다. 그러나 계류수질평가항목 중 BOD는 벌채후 1년, 2년이 경과되는 동안 하천수질환경기준에 의한 상수원수 1급 기준의 최고치인 1 ppm에 도달하는 둥 수질이 악화될 우려가 있기 때문에 대규모 산림 벌채계획은 계류수질보전 을 고려하여 시행하여 야 할 것으로 생각된다.

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QFD 기법을 이용한 특정 유해가스 노출제어 이온선택성 보호복 소재개발연구 (Study of Development of Selective Removal Adsorption Ion Exchange Resin Materials for Fabricated with Chemical-biological Cloth by QFD)

  • 송화선;구일섭;김인식
    • 품질경영학회지
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    • 제43권3호
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    • pp.359-372
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    • 2015
  • Purpose: Through studying the expert's and non-experts panel responses to the questions regarding the attributes of chemical-biological protection cloth quality in terms of the levels of customer demand and technical factors has been studied. We are applied to a QFD matrix with find out the relationship between the selective removal efficiency of chemical-biological cloth and the guidelines of technical approach. Methods: We fabricated several composite of ion-exchange resins with selectively permeable performance designed to facilities water vapor transport and selective adsorption of the harmful gases. With these materials, we characterized on the selectively permeable performance to identify ion-exchange resin with chemical-biological protective cloth. Results: Results showed that ion exchange materials possessed performance with selectively efficiencies as NH3, SOx, NOx and HCl gas. The selective adsorption amount of ammonia and hydrogen gases were $90-80{\mu}g/g$ with TRILITE SCR-BH sulfonated ion exchange resin. The PP non-woven/ion exchange resin adsorbent materials possessed performance with water vapor permeability were 1,100-1,350 g/m2/day, it's was two times high value compare with activated carbon. With these materials, we characterized selectively removal efficiency to identify new ion-exchange material with chemical-biological protective capability. Conclusion: This study shows that a QFD aids in deciding with of the adsorption parameters to optimized with chemical-biological protection cloth manufacturing.

유한요소법에 의한 하구의 수질모델 BAYQUAL (BAYQUAL Model for the Water Quality Simulation of a Bay Using Finite Element Method)

  • 류병로;한양수
    • 한국환경과학회지
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    • 제8권3호
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    • pp.355-361
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    • 1999
  • The aim of this study is to develop the water quality simulation model (BAYQUAL) that deal with the physical, chemical and biological aspects of fate/behavior of pollutants in the bay. BAYQUAL is a two dimensional, time-variable finite element water quality model based on the flow simulation model in bay(BAYFLOW). The algorithm is composed of a hydrodynamic module which solves the equations of motion and continuity, a pollutnat dispersion module which solves the dispersion-advection equation. The applicability and feasibility of the model are discussed by applications of the model to the Kwangyang bay of south coastal waters of Korea. Based on the field data, the BAYQUAL model was calibrated and verified. The results were in good agreement with measured value within relative error of 14% for COD, T-N, T-P. Numerical simulations of velocity components and tide amplitude(M2) were agreed closely with the actual data.

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농업유역의 생태환경 모니터링 기법 연구 (Monitoring of Agro-Ecological Environments at Small Watershed)

  • 박승우;윤광식
    • 농촌계획
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    • 제2권2호
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    • pp.91-102
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    • 1996
  • Monitoring techniques for afro-ecological environments were studied, Hydrologic and ecological components in conjunction with water quality were monitored in the Balkan watershed. The hydrologic monitoring program consists of four water level gauging stations along creeks and stream at the watershed having 26.5 km2. Stage - storage relationship of reservoir, rainfall amount of the watershed, and rating curve of the stream gauging stations were established. Soil type, land use, hydrologic soil group, population and economic activities within the watershed were surveyed. Water quality data from the streams were sampled weekly and chemical analysis was conducted. Temporal variations of water quality were investigated and water quality map of each reach of stream was made to identify spatial variations. Seasonal and spatial variations of vegetation densities along stream in the watershed were investigated using grid, Density variations of insect species such as arthropod, flying insect, spider spices, rice insects were also monitored to determine seansonal surveying density. These monitored data will be used to develop monitoring techi%ues and afro - ecological environment models.

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Assessment of Water Quality using Multivariate Statistical Techniques: A Case Study of the Nakdong River Basin, Korea

  • Park, Seongmook;Kazama, Futaba;Lee, Shunhwa
    • Environmental Engineering Research
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    • 제19권3호
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    • pp.197-203
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    • 2014
  • This study estimated spatial and seasonal variation of water quality to understand characteristics of Nakdong river basin, Korea. All together 11 parameters (discharge, water temperature, dissolved oxygen, 5-day biochemical oxygen demand, chemical oxygen demand, pH, suspended solids, electrical conductivity, total nitrogen, total phosphorus, and total organic carbon) at 22 different sites for the period of 2003-2011 were analyzed using multivariate statistical techniques (cluster analysis, principal component analysis and factor analysis). Hierarchical cluster analysis grouped whole river basin into three zones, i.e., relatively less polluted (LP), medium polluted (MP) and highly polluted (HP) based on similarity of water quality characteristics. The results of factor analysis/principal component analysis explained up to 83.0%, 81.7% and 82.7% of total variance in water quality data of LP, MP, and HP zones, respectively. The rotated components of PCA obtained from factor analysis indicate that the parameters responsible for water quality variations were mainly related to discharge and total pollution loads (non-point pollution source) in LP, MP and HP areas; organic and nutrient pollution in LP and HP zones; and temperature, DO and TN in LP zone. This study demonstrates the usefulness of multivariate statistical techniques for analysis and interpretation of multi-parameter, multi-location and multi-year data sets.

3차원 수리모델을 이용한 한강 상수원구간 지류영향 분석 및 수질오염사고 시나리오 모의 (Impact Analysis of Tributaries and Simulation of Water Pollution Accident Scenarios in the Water Source Section of Han River Using 3-D Hydrodynamic Model)

  • 김은정;박창민;나미정;박현;김복순
    • 한국물환경학회지
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    • 제34권4호
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    • pp.363-374
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    • 2018
  • The Han River serves as an important water resource for the city of Seoul, Korea and in the neighboring metropolitan areas. From the Paldang dam to the Jamsil submerged weir, the 4 water intake stations that are located for the Seoul metropolitan population were under review in this study. Therefore the water quality management in this section is very important to monitor, analyze and review to rule out any safety concerns. In this study, a 3-D hydrodynamic model, EFDC (Environmental Fluid Dynamics Code), was applied to the downstream of the Paldang Dam in the Han River, which is about 23 km in length, to determine issues related to water resource management. The 3-D grid was composed of 2,168 horizontal grids and three vertical layers. In this case, the hydrodynamic model was calibrated and verified with an observed average daily water surface elevation, water temperature and flow rate data for 3 years (2013~2015). The developed EFDC model proved to reproduce the hydrodynamics of the Han River well. The composition ratios of the noted incoming flows at the monitored intake stations for 3 years and their flow patterns in the river were analyzed using the validated model. It was found that the flow of the Wangsuk Stream depended on the Paldnag dam discharge, and it was noted that the composition ratios of the stream at the intake stations changed accordingly. In a word, the Wangsuk Stream moved mainly along the right bank of the Han River under the condition of a normal dam flow. As can be seen, when the dam discharge rate was low, the incidence of lateral mixing was often seen. The scenario analyses were also conducted to predict the transport of conservative pollutants as in the case of a chemical spill accident. Generally speaking, when scenarios were applied, the arrival time and concentration of pollutants at each intake station was thus predicted.