• Title/Summary/Keyword: chemical testing

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Mineralogical Characterization of Asbestos in Soil at Daero-ri, Seosan, Chungnam, Korea (충남 서산 대로리 일대 토양 내 석면의 광물학적 특성)

  • Kim, Jaepil;Jung, Haemin;Song, Suckwhan;Lim, HoJu;Lee, WooSeok;Roh, Yul
    • Economic and Environmental Geology
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    • v.47 no.5
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    • pp.479-488
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    • 2014
  • Naturally occurring asbestos (NOA) from disturbance of rocks and soils has been overlooked as a source of exposure that could potentially have a detrimental impact on human health. But, few researches on mineralogical characteristics of NOA occurred in soils have been reported in Korea. Therefore, the objective of this study was to investigate the mineralogical characteristics of NOA occurred in soils at Daero-ri area, Seosan, Chungnam Province, Korea. Sedimentation method was used for particle size separation of the asbestos-containing soils. XRD and PLM analyses were used to characterize mineralogical characteristics and mineral assemblages in soils. SEM-EDS and TEM-EDS analyses were used to characterize mineral morphology and chemical composition. Particle size analyses of the asbestos-containing soils showed they were composed of 26-93% sand, 4-23% silt and 3-70% clay. Soil texture of the soils was mainly sand, sandy loam, sandy clay, and clay. PLM analyses of the soil showed that most of the soil contained asbestiform tremolite and actinolite. The average content of asbestos in the soil was 1.5 wt. %. Therefore, the soil can be classified into asbestos-contaminated soils based on U. S. Environmental Protection Agency classification (content of asbestos in contaminated soil > 1%). Morphologically different types of tremolite such as long fibrous, needle-like, fiber bundle, bladed and prismatic forms co-existed. Prismatic tremolite was dominant in sand fraction and asbestiform tremolite was dominant in silt fraction. This study indicates that the prismatic form of tremolite transform gradually into a fibrous form of tremolite due to soil weathering because tremolite asbestos was mainly existed in silt fraction rather than sand fraction.

A STUDY ON THE BOND STRENGTHS BETWEEN GLASS IONOMER CEMENT BASES AND COMPOSITE RESINS (글래스 아이오노머 이장재와 복합레진간의 결합강도에 관한 연구)

  • Kim, Min-Hee;Kim, Shin;Jeong, Tae-Sung
    • Journal of the korean academy of Pediatric Dentistry
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    • v.26 no.3
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    • pp.520-527
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    • 1999
  • For the purpose of providing some suggestions in selection of filling materials used in 'sandwich technique', the bond strengths between glass ionomer cement bases and composite resins were investigated and compared. For lining materials, 'Vitrebond' and 'Ketac-fil' were used. Using these two as bases, 10 of each following resins were built up on the top ; Z-100 (light curing resin) Clear-fil (chemical curing resin), Bis-core (dual cure resin), Dyract (compomer), therfore 10 specimens of each group and total of 80 specimens were made. After storing specimens in $37^{\circ}C$ deionized water for 24 hours, the shear bond strengths were measured under universal testing machine with 50 kg of full load scale and 1mm/min of cross-head speed and obtained the results as follows : 1. Over Vitrebond base, Z-100 showed the lowest bond strength but the other three did not show any difference in bond strength. 2. Over Ketac-fil base, Clear-fil showed the highest bond strength followed by Dyract, Bis-core, and Z-100 showed the lowest bond strengths. 3. Whereas Clear-fil showed the similar bond strengths on the Vitrebond base as other resins, it showed the highest bond strength on Ketac-fil base, which showed some difference in bond strength by differing GIC bases. 4. The bond strengths between base materials and composite resin showed a stronger resin-dependence tendency in cases with Ketac-fil bases rather than with Vitrebond bases.

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Flexural strength of various kinds of the resin bridges fabricated with 3D printing (3D 프린팅으로 제작된 여러 종류의 레진브릿지의 굴곡강도에 대한 연구)

  • Park, Sang-Mo;Kim, Seong-Kyun;Park, Ji-Man;Kim, Jang-Hyun;Jeon, Yoon-Tae;Koak, Jai-Young
    • Journal of Dental Rehabilitation and Applied Science
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    • v.33 no.4
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    • pp.260-268
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    • 2017
  • Purpose: Manufacturing with AM (Additive manufacturing) technique has many advantages; but, due to insufficient study in the area, it is not being widely used in the general clinic. In this study, differences of flexural strength among various materials of 3 unit fixed dental prosthesis were analyzed. Materials and Methods: A metal jig for specimens that had a 3-unit-fixed dental prosthesis figure were fabricated. The jigs were made appropriately to the specifications of the specimens. Three different kinds of materials of specimens which were NC (mathacrylic esther based), DP-1 (Bisphenol A epoxy acrylate type oligomer based), and DT-1 (urethane acrylate based) were printed with DLP machine. Five specimens for each kind of material were printed with an angle of $30^{\circ}$ from the horizontal surface. The specimens were placed on the jig and the flexural strength was measured and recorded using Universal testing machine. The recorded data was analyzed in SPSS using One-way ANOVA and Tukey HSD to determine the significance of the differences of flexural strength among the groups. Results: The flexural strengths of each group were the followings: NC, $1119{\pm}305$ N; DP-1, $619{\pm}150$ N; DT-1, $413{\pm}65N$. Using One-way ANOVA and Tukey Honestly Significant Difference test, significant difference was found between NC and the other groups (P < 0.05), but there was no significant difference between DP-1 and DT-1 (P > 0.05). Conclusion: Higher flexural strength was shown in 3-unit-fixed dental prosthesis that were 3D printed using a DLP machine with NC material.

A comparative study on bond strength and adhesive failure pattern in bracket bonding with self-etching primer (Self-etching Primer를 이용한 교정용 브라켓 부착시 전단결합강도와 파절양상에 관한 비교연구)

  • Kim, You-Kyoung;Lee, Jin-Woo;Cha, Kyung-Suk
    • The korean journal of orthodontics
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    • v.34 no.4 s.105
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    • pp.325-332
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    • 2004
  • A self-etching primer that combines the etchant and primer in one chemical compound saves time and should be mote cost-effective to the clinician and patient. The purpose of this study was to evaluate the clinical effectiveness of a self-etching primer by measuring shear bond strengths according to various conditions and observing adhesive failure patterns. For this Investigation, 120 upper and lower premolars extracted for orthodontic purposes were used and randomly divided into six groups of twenty teeth each. Human premolars were embedded in a metal cylinder with orthodontic resin. Metal brackets and ceramic brackets were bonded with XT primer and self-etching primer by means of XT adhesive. Upon curing, plasma arc light and visible light were used. After bonding, the shear bond strength was tested by Instron universal testing machine, and the amount of residual adhesive that remained on the tooth after debonding was measured by stereoscope and assessed with an adhesive remnant index. The results were as fellows: 1. When brackets were bonded, if other conditions remained the same, there was no significant difference in shear bond strength due to the type of primer - either self-etching primer or XT primer. 2. When metal brackets were bonded, there was no significant difference in shear bond strength according to the source of light - plasma arc light or visible light - and type of primer. 3. There was a very significant difference in shear bond strength according to the type of brackets - metal or ceramic brackets. The shear bond strength of ceramic brackets was stronger than metal brackets. 4. When the adhesive failure patterns of metal brackets bonded with self-etching primer were observed by using the adhesive remnant index, the bond failure of the metal bracket occurred more frequently at the bracket-adhesive. The failure of the ceramic bracket, however, occurred more frequently at the enamel-adhesive interface. The adhesive failure patterns of metal brackets bonded with XT primer observed the same patterns. The above results suggest that self-etching primer can be clinically useful for bonding the brackets without fear of a decrease in shear bond strength.

Changes of Mating Type Distribution and Fungicide-resistance of Phytophthora infestans Collected from Gangwon Province (강원지역 감자 역병균 Phytophthora infestans의 교배형 및 약제저항성 변화)

  • Park, Kyeong-Hun;Ryu, Kyoung-Yul;Yun, Jeong-Chul;Jeong, Kyu-Sik;Kim, Jeom-Soon;Kwon, Min;Kim, Byung-Sup;Cha, Byeong-Jin
    • Research in Plant Disease
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    • v.16 no.3
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    • pp.274-278
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    • 2010
  • Potato late blight caused by Phytophthora infestans was the most constrain disease at potato cultivation areas. The mating type distribution and fungicides response of P. infestans were investigated to elucidate the changes of pathogen from Gangwon province. On the fungal isolates in 2006, 58.7% were A1 mating type and 41.3% were A2 mating type. In 2007, A1 mating type isolates increased to 93.3% and A2 mating type isolates were collected from Jinbu areas as much as 6.7%. About 234 isolates analysed for metalaxyl response, the results was resistance 73.7%, intermediate 18.8% and sensitive 7.5% in 2006. And it was resistance 59.4%, intermediate 4.0% and sensitive 36.6% in 2007. It meant that mating type distribution and fungicide response were very different over the collection sites. Minimal inhibition concentration (MIC) of dimethomorph examined with 126 isolates in 2006 and 106 isolates in 2007. MIC over $1.0\;{\mu}g/ml$ was 56.3% in 2006 and it was 3.8% in 2007. The average $EC_{50}$ value of P. infestans was $0.37\;{\mu}g/ml$ in 2006, but it decreased to $0.12\;{\mu}g/ml$ in 2007. Fungicides response and pathogenesis of P. infestans should be monitored continuously to enhance the chemical efficacy at potato fields.

Effect of Annual and Basal Dressing with Liquid Pig Manure on Growth and Quality of Rice in Double Cropping System of Rice-Malting Barley (벼.맥주보리 작부체계에서 돈분액비 연용이 벼 생육과 미질에 미치는 영향)

  • Lee, Seong-Tae;Seo, Dong-Cheol;Cho, Ju-Sik;Dahlgren, Randy A.;Lee, Young-Han
    • Korean Journal of Soil Science and Fertilizer
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    • v.43 no.5
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    • pp.624-630
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    • 2010
  • In order to investigate the effects of continual pre-plant application of liquid pig manure (LPM) on growth and quality of rice in double cropping system of rice and malting barley, the liquid pig manure was applied after harvesting rice and malting barley for 3 years. Field experiment was designed with non-fertilizer, chemical fertilizer (CF) 100% recommended by soil testing, rice (LPM 50%+CF 50%)+malting barley (CF 100%), rice (LPM 50%+CF 50%)+malting barley (LPM 50%+CF 50%), rice (LPM 100%)+malting barley (CF 100%) and rice (LPM 100%)+malting barley (LPM 100%). The yield of rice was increased by 13% with increasing culm length and No. of panicle per hill as 482 kg $10a^{-1}$ in rice (LPM 100%)+malting barley (LPM 100%) plot compare with 427 kg $10a^{-1}$ in rice (CF 100%)+malting barley (CF 100%) plot. Whereas, lodging index was high in rice (LPM 100%)+malting barley (LPM 100%) plot by increasing of internodes length from 3rd to 4th and decreasing of breaking strength. When the quality of milled rice was compare with rice (CF 100%)+malting barley (CF 100%) plot, it was decreased by increasing of protein contents and decreasing of rate of perfect grain in rice (LPM 100%)+malting barley (LPM 100%) plot. The content of amylose was not significant by 19.4~22.0%. Toyo-taste value was not different in LPM 100% and CF 100% plot. Rice could be grown with only liquid pig manure 100%, but considering yield and quality of rice and lodging risk, basal fertilization by LPM 50% and top-dressing by CF 50% application was recommended for rice cultivation.

Changes in Fe, and Mn Content and Lime Requirement Based on Soil pH Testing in Sweet Persimmon Fields (단감 과원 토양 Fe, Mn 함량 변화와 pH 분석을 통한 석회소요량 추천)

  • Lee, Young-Han;Choi, Seong-Tae;Lee, Seong-Tae;Hong, Kang-Pyo;Song, Won-Doo;Lee, Jin-Ho;Cho, Ju-Sik
    • Korean Journal of Soil Science and Fertilizer
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    • v.43 no.5
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    • pp.584-589
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    • 2010
  • Sweet persimmon yield can be limited by soil pH. This study was performed to rapidly determine the optimal level of lime requirement in sweet persimmon field. Soil chemical properties such as Fe, Mn, and Zn were analyzed soil samples of 31 sweet persimmon fields at Gyeongnam Province every two months from April to October in 2008. The available Fe, Mn, and Zn content were significantly high top soil (76.5 mg $kg^{-1}$ for Fe, 46.1 mg $kg^{-1}$ for Mn, and 16.9 mg $kg^{-1}$ for Zn, respectively), and subsoil (55.5 mg $kg^{-1}$ for Fe, 35.9 mg $kg^{-1}$ for Mn, and 12.3 mg $kg^{-1}$ for Zn, respectively) in April. Furthermore, the Mn content was significantly decreased since April compared to other micronutrients. We found a significant negative correlation between soil pH and lime requirement (r=0.881, $p{\leq}0.001$ for top soil, and r=0.855, $p{\leq}0.001$ for subsoil). We suggest that a conversion factor is -171 top soil pH + 1,148 to lime requirement (kg $10a^{-1}$) for top soil, and -190 subsoil pH + 1,247 to lime requirement (kg $10a^{-1}$) for subsoil in sweet persimmon fields. These results supported that the improvement of lime requirement by soil pH value is necessary to rapidly apply to field, and prevent micronutrients over uptake by persimmon plant.

EVA Sheet and Butyl Rubber based Waterproofing·Anti-Corrosion Sheet for Corrosion Maintenance and Repairing in the Interior Side of the Large Steel Pipes in Water Treatment Facilities (상수도용 대구경 녹 발생 강관 내부의 보수 및 성능 유지를 위한 EVA 시트와 부틸고무를 합지한 자착식 방수방식 시트의 부착성능 평가)

  • An, Ki-Won;Kim, Byoung-Il;Oh, Sang-Keun
    • Journal of the Korean Recycled Construction Resources Institute
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    • v.5 no.3
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    • pp.267-274
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    • 2017
  • This study discusses the applicability of environmental friendly EVA based butyl rubber self-adhesive waterproof sheet designed to prevent corrosion of large scale pipes used in the water treatment facilities during th water treatment process. The experiments conducted tested the waterproofing sheet's adhesion strength on the steel surface of the pipes and checked for whether the material has the proper response properties against the various environmental conditions. In addition, it the sheet adhered to the steel pipe was to see if the adhesion hold against the water pressure due to the ingress of inflow water. Finally, the waterproofing sheet's adhesion strength was tested on a rusted steel surface to confirm whether the material has the necessary properties to secure stable adhesion strength and prevent corrosion of steel pipes at the same time during the process of installation or maintenance. As a result, the self-adhesive waterproof sheets showed that all attachments in the untreated, long term pressuring, immersion in chemical substance (hydrochloric acid, hypochlorous acid, sodium hydroxide), low temperature ($-20^{\circ}C$) conditions showed a adhesion performance of higher than 1.5N/mm, which is the performance standard of KS F 4934. Also, in the testing to check for the adhesion property against inverse water pressure, it was observed that the adhesion failure did not occur even up to $3.0N/mm^2$ pressure. Also, in the process of assessing the adhesion performance on rusted steel surface, specimens after 12 hours of corrosion treatment was shown to have 2.1N/mm, and specimens after 168 hours of corrosion treatment was shown to have 2.0N/mm adhesion strength performance.

Organic acid and quality change in Flammulina velutipes fruit body by various storage temperature treatments and packaging films application (포장필름을 달리한 팽이버섯의 저장 온도별 품질변화 및 유기산 함량)

  • Kim, Kyung-Je;Jin, Seong-Woo;Choi, Bong-Suk;Kim, Jin-Kyeong;Koh, Young-Woo;Kim, A-Rum-Chan;Seo, Kyoung-Sun
    • Journal of Mushroom
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    • v.13 no.2
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    • pp.119-124
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    • 2015
  • This study was carried out to characterize the chemical components of Flammulina velutipes during storage by different packaging film application for developing export winter mushroom to south east asia area. Changes of weight and growth rate from Flammulina velutipes were the lowest in testing packaging film at $15^{\circ}C$ among the films. The pH changes of Flammulina velutipesg was the highest in imported packaging film at $25^{\circ}C$. The changes of colors was measured by Hunter's color value, L value and yellowness (+b) were slightly decreased during storage. But the L value and yellowness (+b) were not affected by packaging films. Six organic acids were detected such as oxalic acid, lactic acid, malic acid, citric acid, acetic acid and succinic acid. The content of total organic acids were increased by storage period.

Preliminary Study on Desizing and Dyeing Using Low Temperature Plasma (저온 플라즈마를 이용한 호발 및 염색 선행연구)

  • Bae, Paek-Hyun;Jo, Hun-Je;Kim, Hyo-Jin;Lee, Yeon-Hee;Park, Sung-Min;Kim, Jeong-Gyu;Jung, Jin-Ho
    • Journal of Korean Society of Environmental Engineers
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    • v.27 no.9
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    • pp.946-951
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    • 2005
  • In this wort plasma treatment was evaluated as an alternative clean desizing technology. Size materials such as PVA(polyvinyl alcohol), PACL(polyacrylic acid esters) and their mixture on PET(polyethylene terephthalate) fabrics were treated by $N_2$ and $O_2$ plasma. $O_2$ plasma was more efficient in size removal than $N_2$ plasma, and the removal of PVA was higher than that of PACL. SEM(scanning emission microscopy) pictures of the plasma treated samples directly proved the disappearance of sizing agents. After $O_2$ plasma treatment, the PET fabrics were subjected to conventional desizing process. Compared with untreated fabrics, the desizing effluent from the treated fabrics gave lower TOC, COD and $BOD_5$ values. This indicates plasma treatment not only serves to directly remove sizing agents but also offered several advantages by changing the chemical properties of sizing agents. Lastly, the effect of plasma desizing process on dyeing was examined using color difference and dyeing fastness tests. The CCM(computer color matching) results showed rotor difference between PET fabric desized by $O_2$ plasma treatment for 20 min and reference PET fabric desized by the conventional wet desizing process was around 1. This suggests the treated PET fabric can be directly subjected to dyeing process without any additional process. The plasma treated fabric also gave a good result of dyeing fastness so that grades of laundering, crocking, heat and light fastness were same or even better than the reference PET fabric did.