• Title/Summary/Keyword: chemical testing

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The study on the Hydrogen Characteristics of MmNi4.5Mn0.5 Hydrogen Storage Alloy (MmNi4.5Mn0.5계 수소저장합금의 수소화 특성에 관한 연구)

  • Kang, Kil-Ku;Kang, Sei-Sun;Kwon, Ho-Young;Lee, Rhim-Youl
    • Journal of Hydrogen and New Energy
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    • v.13 no.2
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    • pp.151-158
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    • 2002
  • The hydorgen storage alloys were produced by melting in arc melting furnace and then solution heat treated at $1,100^{\circ}C$ followed by pulverization. The chemical analysis on the samples showed that the major elements of misch metal(Mm) were La, Ce, Pr and Nd with impurity less than 1wt.%. X-ray diffraction indicated that the structure for these samples were a single phase of hexagonal with $CaCu_5$ type. Compared to the initial particle size $100{\sim}110{\mu}m$, the many fine cracks were found and particle size decreased to $14{\mu}m$ for $MmNi_{4.5}Mn_{0.5}$ after hydriding/dehydring test run. To activate the sample the vessel filled with hydrogen storage alloys was first evacuated for for at $70^{\circ}C$ and then treated for 10.5hr under hydrogen pressure of 20atm for $MmNi_{4.5}Mn_{0.5}$ alloy. The experimental data showed that the hydrogen storage alloy of $MmNi_{4.5}Mn_{0.5}$ had superior adsorption and description properties within a temperature rang of $40^{\circ}C{\sim}80^{\circ}C$ and also they had a good P-C-T curve.

Sulfate Attack According to the Quantity of Composition of Cement and Mineral Admixtures (시멘트 화학성분(C3A)과 무기 혼화재에 따른 황산염 침투 특성)

  • Ahn, Nam-Shik;Lee, Jae-Hong;Lee, Young-Hak
    • Journal of the Korea Institute of Building Construction
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    • v.11 no.6
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    • pp.547-556
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    • 2011
  • The primary factors affecting concrete sulfate resistance are the chemical composition of the Portland cement, and the chemistry and quantity of mineral admixtures. To investigate the effect of those on the sulfate attack, the testing program involved several different mortar mixes using the standardized test, ASTM C1012. Four different cements were evaluated, including one Type I cement, two Type I-II cements, and one Type V cement. Mortar mixes were also made with mineral admixtures, as each cement was combined with three different types of mineral admixtures. One Class F fly ash, one Class C fly ash, and one ground granulated blast furnace slag (GGBFS) were added in various percent volumetric replacement levels. Expansion measurements were taken and investigated with the expansion criteria recommended by ASTM.

Comparison of bond strength between denture base resin and reline resin (의치상 레진과 이장 레진 간의 결합강도 비교)

  • Geum, Young-Hee;Kim, Busob
    • Journal of Technologic Dentistry
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    • v.39 no.3
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    • pp.161-167
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    • 2017
  • Purpose: We compare the bond strength of heat-cured PMMA of Lucitone 199 and QC-20 and Tokuyama Rebase Resin of self-cured resin, which are widely used and well accepted in clinical practice. In order to test the mechanical bonding and chemical bonding, we will compare the bond strength between EstheShot Bright, Smiletone, Repair and Rebase resins. Methods: The denture base resin used in this study was PMMA heat-cured QC-20 and Lucitone 199, polyamide resin EstheShot Bright, Smiletone. And Two types of self-curing Rapid Repair and Tokuyama Rebase were used as resection resins. To measure the bond strength, the denture specimens were fabricated in the size of $10{\times}64{\times}3.5mm$ as instructed by the manufacturer. A surface treatment agent was applied to the cut surfaces of each denture specimen, and the specimens were placed in a preformed silicone mold, and autoclaved excimer resins were prepared. The bending strength of the fabricated specimens was measured using a universal testing machine (STM-5, United Calibration Co., U.S.A.) to measure the three-point bending strength. Results: In both polycarbonate and polyacetal resin, a special resin surface treatment agent showed higher bonding strength than the resin surface treatment agent(p<0.05). Regardless of the type of surface treatment, polycarbonate showed higher bond strength than polyacetal resin(p<0.05). Conclusion: It is considered desirable to use a special surface treating agent for the thermoplastic denture base resin such as polycarbonate and polyacetal resin.

Effect of C/Ti Atom Ratio on the Deformation Behavior of TiCχ Grown by FZ Method at High Temperature

  • Shin, Soon-Gi
    • Korean Journal of Materials Research
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    • v.23 no.7
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    • pp.373-378
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    • 2013
  • In order to clarify the effect of C/Ti atom ratios(${\chi}$) on the deformation behavior of $TiC_{\chi}$ at high temperature, single crystals having a wide range of ${\chi}$, from 0.56 to 0.96, were deformed by compression test in a temperature range of 1183~2273 K and in a strain rate range of $1.9{\times}10^{-4}{\sim}5.9{\times}10^{-3}s^{-1}$. Before testing, $TiC_{\chi}$ single crystals were grown by the FZ method in a He atmosphere of 0.3MPa. The concentrations of combined carbon were determined by chemical analysis and the lattice parameters by the X-ray powder diffraction technique. It was found that the high temperature deformation behavior observed is the ${\chi}$-less dependent type, including the work softening phenomenon, the critical resolved shear stress, the transition temperature where the deformation mechanism changes, the stress exponent of strain rate and activation energy for deformation. The shape of stress-strain curves of $TiC_{0.96}$, $TiC_{0.85}$ and $TiC_{0.56}$ is seen to be less dependent on ${\chi}$, the work hardening rate after the softening is slightly higher in $TiC_{0.96}$ than in $TiC_{0.85}$ and $TiC_{0.56}$. As ${\chi}$ decreases the work softening becomes less evident and the transition temperature where the work softening disappears, shifts to a lower temperature. The ${\tau}_c$ decreases monotonously with decreasing ${\chi}$ in a range of ${\chi}$ from 0.86 to 0.96. The transition temperature where the deformation mechanism changes shifts to a lower temperature as ${\chi}$ decreases. The activation energy for deformation in the low temperature region also decreased monotonously as ${\chi}$ decreased. The deformation in this temperature region is thought to be governed by the Peierls mechanism.

Pipe Stiffness Prediction of GRP Flexible Pipe (GRP 연성관의 관강성 예측)

  • Lee, Young-Geun;Kim, Sun-Hee;Park, Joon-Seok;Yoon, Soon-Jong
    • Journal of the Korean Society for Advanced Composite Structures
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    • v.2 no.3
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    • pp.18-24
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    • 2011
  • In this paper, we present the load-deflection behavior of GRP pipes. GRP buried pipes are widely used in construction in the advantage of their superior mechanical and physical characteristics such as high chemical resistance, high corrosion resistance, right weight, smooth surface of the pipe, and cost effectiveness from soil-structure interaction. To design flexible pipes to be buried underground, it should be based on the ASTM D2412(2010). When applying ASTM D 2412(2010) to the design, pipe stiffness(PS) must be predetermined by the parallel-plate test which requires tedious and laborious working process. To overcome such problems, the finite element simulations for finding the load-deflection behavior of the GRP flexible pipes is installed at UTM testing machine. In the finite element simulations, basic data, such as the modulus of elasticity of the material and cross-sectional dimension, is used. From the investigation, we found that the difference between experimental result and analytical prediction is less than 15% when the pipe deflected 3% and 5% of its vertical diameter although the pipe material is not uniform across the cross-section.

The Environmental Impact Quotient on Fruit and Vegetables Pesticides in Korea (국내 과채류에 등록된 농약에 대한 환경영향지수)

  • Oh, Kyeong-Seok;Lee, Byung-Moo;Sung, Ha-Jung;Oh, Hong-Gyu;Ihm, Yang-Bin;Kyung, Kee-Sung
    • The Korean Journal of Pesticide Science
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    • v.7 no.2
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    • pp.123-130
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    • 2003
  • The Environmental Impact Quotient(EIQ) has been used to organize the extensive toxicological and soil residue data available on some fruit vegetables pesticides into a usable form for field use. It addresses a majority of the environmental concerns that are encountered in agricultural systems including farm worker, consumer, ecological and environmental safety. The EIQ made use of the rating system by using the EIQ equation. The EIQ of pesticides registered for oriental melon was higher than that of other in terms of farm worker, consumer and environmental safety. Pesticides registered for red pepper showed highest EIQ in ecosystem. The EIQ decreased in order of insecticide> fungicide> herbicide> plant growth regulator. The environment Impact Quotient for the pesticides registered in fruit and vegetables decrease gradually.

TENSILE BOND STRENGTH OF FOUR PORCELAIN REPAIR SYSTEMS (파절된 도재면에 대한 수종의 도재 수리 시스템의 인장결합강도)

  • Jeon Young-A;Yang Byung-Duk;Lee Ho-Jin;Park Ju-Mi;Song Kwang-Yeob
    • The Journal of Korean Academy of Prosthodontics
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    • v.43 no.2
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    • pp.149-157
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    • 2005
  • Statement of problem. Dental ceramics exhibit excellent esthetic property, compressive strength, chemical durability biocompatibility and translucency. However, it suffers from inherent brittle fractures. Various techniques and materials for intraoral porcelain repair has been suggested. Purpose. This study is to compare the tensile bond strength of four commonly used porcelain repair systems (Vivadent, Bisco, Ulttadent, Voco) and to insure the best system for the clinical application to the fractured porcelain. Materials and methods. A total of fifty specimens were fabricated. Specimens were stored in $37^{\circ}C$ distilled water for 7 days and thermocycling was performed(1000 cycles), and subjected to a tensile force parallel to the repair resin and porcelain interface by use of an Universal Testing Machine. Result. 1. Voco showed the highest tensile bond strength. In decreasing order, the tensile bond strength of the other materials was as follows : Ultradent, Bisco, Vivadent. 2. There was a statistically significant difference between the porcelain repair systems(Voco, Ultradent > Bisco, Yivadent) (p<0.05). 3. SEM examination of prepared porcelain surfaces revealed that the surface treated with Voco showed brittle fracture. However, Ultradent, Bisco and Vivadent showed ductile fracture. 4. All specimens treated with four porcelain repair systems showed adhesive failure between porcelain and composite resin.

A Study on the Field Application of Alkaline Tunnel Wastewater to Neutralization Using CO2 (터널시공 시 이산화탄소(CO2)를 이용한 알칼리성 폐수의 중화처리 현장적용 연구)

  • Park, Young-Jin;Lee, Ho-Chul
    • Journal of the Korean Geotechnical Society
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    • v.36 no.8
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    • pp.27-34
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    • 2020
  • Strong alkaline waste water is generated in large quantities due to using Concrete, shotcrete and various compounds in tunnel construction sites. As the release of this alkaline waste water will contaminate the stream water, it has to be neutralized. Currently, this waste water is mainly neutralized by using sulfuric acid or hydrochloric acid, but the risks of corrosion and handling of facilities are inherent and the chemical control act requires strict management measures. Therefore, using CO2 (carbon dioxide) as an alternative has been highlighted and various indoor experiment studies have been conducted to prove its potential. However, it is difficult to apply CO2 to the site because it is still completely lacking in field application research and shows different characteristics from indoor experiments. In this study, the actual site applicability is verified through field testing.

Development of Cleaning Agents for Solar Silicon Wafer (태양광 실리콘 웨이퍼 세정제 개발)

  • Bae, Soo-Jeong;Lee, Ho-Yeoul;Lee, Jong-Gi;Bae, Jae-Heum;Lee, Dong-Gi
    • Clean Technology
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    • v.18 no.1
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    • pp.43-50
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    • 2012
  • Cleaning procedure of solar silicon wafer, following ingot sawing process in solar cell production is studied. Types of solar silicon wafer can be divided into monocrystalline or multicrystalline, and slurry sawn wafer or diamond sawn wafer according to the ingot growing methods and the sawing methods, respectively. Wafer surface and contaminants can vary with these methods. The characterisitics of contaminants and wafer surface are investigated for each cleaning substrate, and appropriate cleaning agents are developed. Physical properties and cleaning ability of the cleaning agents are evaluated in order to verify the application in the industry. The wafers cleaned with the cleaning agents do not show any residual contaminants when analyzed by XPS and regular patterns are formed after texturization. Furthermore, the cleaning agents are applied in the production industry, which shows superior cleaning results compared to the existing cleaning agents.

A Study for Development of a Korean Pain Measurement Tool(II). A Study for Testing Ranks of Words in each Subclass of a Korean Pain Measurement Tool (동통 평가도구 개발을 위한 연구 -한국 통증 어휘별 강도 순위의 유의도 및 신뢰도 검사-)

  • 이은옥;송미순
    • Journal of Korean Academy of Nursing
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    • v.13 no.3
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    • pp.106-118
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    • 1983
  • The main purpose of this study is to systematically classify words indicating pain in terms of their ranks in each subclass. This study is a part of developing a Korean Pain Measurement Tool. This study didnot include exploration of each word's dimension such as sensory or affective. Eighty three Korean words tentatively classified in 19 subclasses in previous study were used for this study. At least three to six words were included in each subclass and the words were randomly placed in which each subject indicates their rank of pain degree. One hundred and fifty nursing students and one hundred clinical nurses were requested to indicate the rank of each word. One hundred and sixteen students and eighty three nurses completed the ratings for analysis. The data were collected from June 1983 to July 1983. The data using ordinal scale were analyzed by Friedman ANOVA to test significant difference between rank means. All of pain words indicated significant rank mean difference in all of 19 subclasses. Some of the words were either cancelled or replaced by other words, or rearranged for their ranks. Subclasses of which words were cancelled were 1) Simple stimulating pain, 2) Punctuate pressure, 3) peripheral nerve pain, 4) radiation pain, 5) punishment-related pain, and 6) suffering-related pain. Subclasses of which words were replaced or rearranged were 1) incisive pressure, 2) constrictive pressure, 3) dull pain, 4) tract pain, 5) digestion-related pain and 6) fear-related pain. Four subclasses such as traction pressure, thermal, cavity pressure, and fatigue- elated pain indicated significant differences among rank means in each subclasses and showed no visible overlaps of the ranks among means. Further research is needed using high level measurement of pain degree of each word and more sophisticated analysis of the pain degrees. Three pain words which would be related to chemical stimulation were newly explored and included as a new subclass. Through this study, the total number of subclasses increases from 19 to 20 and the total number of Korean words in the scale decreases from 83 to 80.

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