• Title/Summary/Keyword: chemical stability

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Facile Modulation of Electrical Properties on Al doped ZnO by Hydrogen Peroxide Immersion Process at Room Temperature

  • Park, Hyun-Woo;Chung, Kwun-Bum
    • Applied Science and Convergence Technology
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    • v.26 no.3
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    • pp.43-46
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    • 2017
  • Aluminum-doped ZnO (AZO) thin films were deposited by atomic layer deposition (ALD) with respect to the Al doping concentrations. In order to explain the chemical stability and electrical properties of the AZO thin films after hydrogen peroxide ($H_2O_2$) solution immersion treatment at room temperature, we investigated correlations between the electrical resistivity and the electronic structure, such as chemical bonding state, conduction band, band edge state below conduction band, and band alignment. Al-doped at ~ 10 at % showed not only a dramatic improvement of the electrical resistivity but also excellent chemical stability, both of which are strongly associated with changes of chemical bonding states and band edge states below the conduction band.

Effects of Oil type on the Stability of Oil-in-Water Lipid Nanoemulsion

  • Lee, Seung-Jun;Han, Sa Ra;Jeong, Jae Hyun;Kim, Jong-Duk
    • Journal of the Korean Applied Science and Technology
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    • v.33 no.4
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    • pp.667-675
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    • 2016
  • Nanoemulsions are actively used in several applications for pharmaceutical, cosmetic and chemical industries. In this study, we propose the use of microfluidizer known as high pressure homogenizer to prepare lipid nanoemulsion as a potent cosmetic delivery carrier. The lipid nanoemulsions were prepared by O/W emulsion with hydrogenated lecithin and different type of oils. Effects of oil type on the stability of the lipid nanoemulsion were investigated with Dynamic Light Scattering (DLS) and Zeta-potential. Arbutin was used as model drug for transdermal administration through hairless mouse skin. Transdermal arbutin delivery using the lipid nanoemulsions was studied with HPLC method.

Enhanced Thermal Stability of a Silica/Stainless Steel Composite Membrane via the Soaking-Rolling Method

  • Lee, Dong-Wook;Nam, Seung-Eun;Bongkuk Sea;Ihm, Son-Ki;Lee, Kew-Ho
    • Proceedings of the Membrane Society of Korea Conference
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    • 2004.05a
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    • pp.175-178
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    • 2004
  • Concerning the application of the inorganic composite membranes to high temperature process such as the catalytic dehydrogenation of hydrocarbons, important aspects to consider in the application include the improvement of the thermal stability and good permeability.(omitted)

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Effect of Siloxane Oligomer on Thermal Stability and Internal Stress of Epoxy Resins (실록산 올리고머가 에폭시 수지의 열안정성 및 내부응력에 미치는 영향)

  • Kwak, Geun-Ho;Park, Soo-Jin;Park, Jun-Ha;Kim, Kong-Soo
    • Applied Chemistry for Engineering
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    • v.10 no.5
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    • pp.701-706
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    • 1999
  • The effect of siloxane oligomer content on thermal stability and internal stress of DGEBA epoxy resin was investigated. Siloxane-epoxy polymers having terminal epoxy group were prepared by reaction of siloxane-DDM prepolymer with DGEBA epoxy resin. Thermal stability was studied in terms of the initial decomposition temperature(IDT), temperature of maximum rate of weight loss($T_{max}$), integral procedural decomposition temperature(IPDT), and decomposition activation energy($E_t$) using TGA data. The thermal stability increased with increasing the siloxane oligomer content and showed a maximum value in the case of 5 wt% siloxane oligomer content in the blend system. While, the coefficient of thermal expansion(${\alpha}_r$) and the flexural modulus($E_r$) allowed us to study internal stress of the blend system. As the content of siloxane oligomer increases, the internal stress systematically decreases as decreasing both ${\alpha}_r$ and $E_r$.

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Ionic Liquid as a Solvent and the Long-Term Separation Performance in a Polymer/Silver Salt Complex Membrane

  • Kang, Sang-Wook;Char, Kook-Heon;Kim, Jong-Hak;Kang, Yong-Soo
    • Macromolecular Research
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    • v.15 no.2
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    • pp.167-172
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    • 2007
  • The reduction behavior of silver ions to silver nanoparticles is an important topic in polymer/silver salt complex membranes to facilitate olefin transport, as this has a significant effect on the long-term performance stability of the membrane. In this study, the effects ofthe solvent type on the formation of silver nanoparticles, as well as the long-term membrane performance of a solid polymer/silver salt complex membrane were investigated. These effects were assessed for solid complexes of poly(N-vinyl pyrrolidone) $(PVP)/AgBF_4$, using either an ionic liquid (IL), acetonitrile (ACN) or water as the solvent for the membrane preparation. The membrane performance test showed that long-term stability was strongly dependent on the solvent type, which increased in the following order: IL > ACN >> water. The formation of silver nanoparticles was more favorable with the solvent type in the reverse order, as supported by UV-visible spectroscopy. The poor stability of the $(PVP)/AgBF_4$ membrane when water was used as the solvent might have been due to the small amount of water present in the silver-polymer complex membranes actively participating in the reduction reaction of the silver ions into silver nanoparticles. Conversely, the higher stability of the $(PVP)/AgBF_4$, membrane when an IL was used as the solvent was attributable to the cooperative coordination of silver ions with the IL, as well as with the polymer matrix, as confirmed by FTIR spectroscopy.

Stability of Matrine and Oxymatrine from the Biopesticide from Sophora flavescens under Aquatic and Soil Environment (고삼 추출물을 주성분으로 하는 유기농자재의 alkaloid계 살충성분 2종의 토양 및 수계 노출 안정성)

  • Kim, Jin Hyo;Choi, Geun-Hyoung;Lim, Sung-Jin;Park, Byung-Jun
    • Korean Journal of Environmental Agriculture
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    • v.34 no.1
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    • pp.1-5
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    • 2015
  • BACKGROUND: The stabilities of the two alkaloidal insecticides of S. flavescens including matrine and oxymatrine are important factor to establish expiry date and usage manual for crop protection. However, the environmental stability of the compounds had not been studied with the extract and its commercial biopesticide. METHODS AND RESULTS: The environmental stabilities of the two alkaloids were performed with extract of S. flavescens, and its two commercial biopesticides both in controlled aquatic and soil conditions. The half-lives of the total matrines for the extract and its two commercial biopesticides were estimated over 200 days both under aerobic and anaerobic water condition. Under dry soil condition, the initial decay rates of the matrines were calculated 0.0804-0.1275 ($t_{1/2}$ 5.4-8.6 days), and the half-lives under wet soil condition were calculated 33.0-231 days. Total soil bacteria on the wet soil ranged 6.0-8.0 log CFU/g-soil during the experiments period. CONCLUSION: The aquatic mixture of the extract showed excellent stability both with the extract and its biopesticides, however, the stability of soil mixture were shorter than the aquatic mixture, suggesting that soil metal consider as a catalyst for the degradation of the two alkaloids.

In the presence of organic solvent stability of CiP [coprinus cinereus peroxidase] (유기용매에서의 CiP [coprinus cinereus peroxidase]의 안정성)

  • Kim, Han-Sang;Cho, Dae-Haeng;Kim, Yong-Hwan
    • KSBB Journal
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    • v.23 no.4
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    • pp.340-344
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    • 2008
  • Coprinus cinereus peroxidase (CiP) was often used as a catalyst for oxidative polymerization of a variety of phenol derivatives to produce a new class of polyphenols. Economical point of view, to know the mechanism of enzyme deactivation is significantly important because cost of enzyme is critically high. Hydrogen peroxide being used as oxidizing agent induced deactivation of peroxidase by destruction of heme structure. In the presence of hydrogen peroxide the stability of peroxidase was unexpectedly improved by adding organic solvent. Especially 2-propanol significantly improved enzyme stability among tested solvents. Radical scavenging by organic solvents may play a major role in protecting peroxidase from the oxidation of oxidizing radicals.

Effect of Concentration of Trioctylphosphine Oxide and Thenoyltrifluoroacetone on the Preparation and Stability of Colloidal Liquid Aphrons (Trioctylphosphine Oxide와 Thenoyltrifluoroacetone의 농도가 콜로이드 액상 에이프런의 제조와 안정성에 미치는 영향)

  • Yeo, Kil Hwan;Jeon, Sang Jun;Hong, Won Hi;Lee, Hong Ki
    • Clean Technology
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    • v.12 no.1
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    • pp.45-51
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    • 2006
  • Colloidal Liquid Aphrons(CLAs) were prepared from different solvents such as nonpolar hydrocarbons, alcohols, and amines. Water-soluble surfactant and oil-soluble surfactant were used in this study. The effect of PVR (phase volume ratio) and concentration of extractant on the stability of CLA was investigated. The stability of CLA was affected by PVR. As PVR was increased, the stability of CLA was decreased.

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Stability of concentrated Colloidal Liquid Aphrons containing a quaternary ammonium salt in the continuous phase (사차 암모늄 염을 함유하는 농축된 콜로이드 액상 에이프런의 연속상에서의 안정성)

  • Hahm, Hyung Chul;Hong, Won Hi;Lee, Choul Ho
    • Clean Technology
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    • v.7 no.4
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    • pp.291-297
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    • 2001
  • In this study, the stability of concentrated colloidal liquid aphrons (CLAs) containing Aliquat 336 was measured. CLAs in the continuous phase are stabilized by water-soluble surfactant and oil-soluble surfactant. To compare the stability of CLAs, half-life was introduced. According to the change of state of solution, the rate of break-up of concentrated CLAs changed rigorously at critical coagulation concentration. Critical coagulation concentration was measured with changing pH. The effects of ionic strength and concentration of Sodium Dodecyl Benzene Sulfonate (SDBS) on the stability of concentrated CLAs in the continuous phase were also investigated.

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A Study on the Determination for Rated Voltage Considering the Stability in the Refinery and Chemical Plant by Isolated Power System (독립계통 정유·화학플랜트의 안정도를 고려한 정격전압 결정에 관한 연구)

  • Shin, Ho-Jeon;Cho, Man-Young;Chung, In-Sung;Kim, Jin-Seok;Kim, Jae-Chul
    • The Transactions of The Korean Institute of Electrical Engineers
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    • v.65 no.1
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    • pp.200-207
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    • 2016
  • Nowadays, it is a global trend to build refinery or chemical plants with an isolated system in a place distant from the center of a city. In the refinery or chemical plants equipped with an isolated system, induced motors mostly take the load, and the scale of high-voltage electric motors reaches from several kW up to several MW. Therefore, it is needed to examine the effects of electric motors on the power system closely in the stages of planning and designing a plant to build a stable power system. This study is aimed to investigate how to decide rated voltage in consideration of stability which has not been considered in the stages of planning and designing so far in order to secure stability for the power system.