• 제목/요약/키워드: chemical materials

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Diels-Alder Cycloaddition of Cyclopentadiene with Ethylacrylate Catalyzed by Mesoporous Al-MCM-48 and Al-MCM-41 Catalysts

  • Shon, Jeong-Kuk;Sim, Jae-Yi;Thakur, Santosh Singh;Ko, Eun-Mi;Kong, Soo-Sung;Choi, Ji-Yun;Kang, Min;Senapati, Bidyut Kumar;Choi, Doo-Seoung;Ryu, Do-Hyun;Kim, Ji-Man
    • Bulletin of the Korean Chemical Society
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    • 제29권10호
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    • pp.1993-1997
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    • 2008

  • In the present work, Diels-Alder reaction of cyclopentadiene with ethylacrylate has been carried out by using two types of mesoporous solid acid catalysts (Al-MCM-41, Al-MCM-48) with different pore structures. The specific topology of Al-MCM-48 (cubic Ia3d structure composed of two independent 3-D channel systems) exhibit higher activity and stereo-control than those of Al-MCM-41 (hexagonal packing of 1-D channels). The physical properties of Al-MCM-48 catalyst, such as high accessibility of reactants to the acid sites, spatial confinement in the nanoscopic reactors, and 3-D channel network structure that are effective adsorption and diffusion of reactants, play a crucial role in the present study.

  • https://doi.org/10.5012/bkcs.2008.29.10.1993 인용 PDF KSCI