• Title/Summary/Keyword: chemical index

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Characterization of Wetness Index in Western Area of Yangsan Fault, Sangbuk-myeon, Kyeongnam-do (경상남도 상북면 양산단층 서부지역에 대한 습윤지수 특성 연구)

  • Kim, Sung-Wook;Han, Ji-Young;Lee, Son-Kap;Kim, Sang-Hyun;Kim, Choon-Sik;Kim, In-Soo
    • Proceedings of the Korean Geotechical Society Conference
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    • 2004.03b
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    • pp.904-909
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    • 2004
  • The study area adjoins with Yangsan fault in Sangbuk-myeon, Samsam-ri, Kyongsang-namdo and consist of the natural steep slope. After drawing data layer which have altitude by using digital topography data, it is converted to lattice DEM of $10m{\times}10m$ size. From this, gradient map of unit lattice, slant direction map and shadow relif map are made. Using flow apportioning algorithm, upper slope contributing area and wetness index by established lattice can be calculated. Area that have high wetness index shows lineament structure of northwest-southeast direction, and this agrees with shear fracture system. The result of electricity specific resistance survey in the study area shows that area of high wetness index has low electricity specific resistance anomaly. That is, wetness index conforms with distribution of fractured zone that accompanied chemical weathering of rock. Therefore, wetness index can be used as the method of detecting fractured zones and judging the stability of the area.

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Refractive Index Changes of Polymer Film by Photochemical Reactions (광반응에 의한 고분자 필름의 굴절률 변화)

  • 조정환;신미영;이종하;김성수;송기국
    • Polymer(Korea)
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    • v.28 no.6
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    • pp.545-550
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    • 2004
  • The refractive index of thin copolymer film was controlled by photo-degradation of chromophores in the copolymer. FTIR and UV/Vis spectroscopy were employed to elucidate the effect of chemical structure on refractive index changes after photobleaching. The decrease of refractive index of the film by photobleaching can be ascribed to the decrease of polarizability of polymer molecules through breakage of C =C bond in the chromophore. Due to the selective photoreaction of the chromophores which align along the film plane, refractive index of the copolymer film measured in TE mode decreases faster than that in TM mode. Polarized ATR-FTIR spectroscopy was used to verify such a difference in refractive index of the film.

A Calculation of Compression Index of the South Coast Soft Clay Utilizing Field Measurement (계측자료를 활용한 남해안 연약 점성토의 압축지수 산정)

  • Lee, Changouk;Park, Choonsik;Kwon, Hyeonjin;Kim, Jonghwan
    • Journal of the Korean GEO-environmental Society
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    • v.16 no.6
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    • pp.23-30
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    • 2015
  • This study analyzed degree of disturbance, using specimens by laboratory test with large block specimens and piston samplers collected from the Korea's two typical soft ground districts: South coast Gwangyang and Yangsan. To assess the characteristics of compression index of laboratory test incurred by disturbance, the compression index of laboratory test was compared with the back analysis compression index resulting from the analysis of the measured settlement. The analysis of specimen disturbance of the laboratory test results with the piston specimens of the two districts found that the qualities of most specimens were poor and the settlement predicted by the laboratory test compression index was underestimated. The analysis of test material taken from nearby areas proved that the disturbance degrees of large block specimens were lower than that of the piston specimens. The hyperbolic method, Hoshino method, Asaoka method, and ${\sqrt{S}}$ method, all of which are predictive methods using measured settlement, were employed to reach a conclusion that reliabilities of each predictive method except predictive material of a few points were the same. To compensate the disturbance effects on compression index of the piston specimens, we suggested a new modification formula that estimates compression index of piston specimens, using Schmertmann's corrected compression index, and back analysis compression index from the analysis of predictive settlement.

Conservation status assessment of archaeological bone from Fourier Transform Infrared Spectroscopy and histological Analysis (적외선 분광 분석과 조직 분석을 통한 출토 인골의 보존 상태 평가)

  • Lee, Jeongwon;Kim, Sue Hoon;Kim, Yun-Ji;Cho, Eun Min;Kang, Soyeong
    • 보존과학연구
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    • s.35
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    • pp.87-98
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    • 2014
  • Fourier transform infrared spectroscopy(FTIR-ATR) was applied to chemical analysis for conservation status of 10 human bone remains from Joseon Dynasty. The result of crystallinity index (CI) is $4.25{\pm}0.78$, carbonate to carbonate ratio (C/C) is $0.91{\pm}0.04$ and cabonate content (C/P) is $0.19{\pm}0.06$. The higher histological index (HI) confirmed CI and C/P value was increased and C/C value was reduced. While C/C or C/P values analysis is possible. While DNA analysis can be extracted from the bone, C/C values are lower or C/P values are higher was found to the analysis is possible. Chemical assessment of FTIR and histological index consequence is expected to be applicable as a basis for comprehensive understanding of the conservation status excavated bones.

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Human Toxicity Index and Toxic Substances Emissions in Korea Industries (한국의 산업별 독성물질 배출과 인체유해도 측정 -산업연관분석의 응용-)

  • Rhee, Hae-Chun;Kim, Ik;Hur, Tak
    • Environmental and Resource Economics Review
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    • v.15 no.4
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    • pp.643-672
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    • 2006
  • This study has assessed the industrial human toxicity index by means of toxic substances emissions in South Korean industry. The data used in analysis are the 146 kinds of the toxic chemicals emissions and final demands, total outputs in the input-output table. As a results, human carcinogenic index was $11.86198{\times}10^3$ for overall industries, and $0.26360{\times}10^3$ for average. The industries of higher human toxicity index can be ranked as follows: Mother vehicles and parts (7.85033) > Pig iron and crude steel(4.57409) > Primary iron and steel products(4.36668) > Other transportation equipments and parts(3.43293) > Inorganic basic chemical products(2.64379), etc. Such result can be considered as the priority order of regulation based on industrial characteristics, when the demand and industrial policies should be carried out for the deduction fof toxic substances.

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Determination of the Cetane Number, Derived Cetane Number and Cetane Index for Diesel Fuel by Additives (첨가제에 따른 경유연료의 세탄가 유도세탄가 및 세탄지수 분석)

  • Lim, Young-Kwan;Kim, Jong-Ryeol;Jung, Choong-Sup;Yim, Eui Soon;Kim, DongKil
    • Korean Chemical Engineering Research
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    • v.48 no.3
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    • pp.375-381
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    • 2010
  • Cetane number of diesel fuel for compression ignition engine is one of main properties for fuel ignition quality. Recently the cetane index has been replaced the cetane number in order to resolve the disadvantage of CFR engine test, but these two value have slightly difference values due to addition of various additives. In this study, we analyzed the cetane number, derived cetane number and cetane index for diesel fuel which was blended with various ratios of biodiesel, kerosene and cetane improver as additives. As a result, Cetane number showed the similar value with derived cetane number, but cetane index showed quite different value with cetane number when biodiesel and cetane improver were used as additives.

Study on the Ophthalmic Lens Materials with High Refractive Index Containing Vinylanisole (Vinylanisole을 포함한 고굴절률 안의료용 렌즈 재료에 관한 연구)

  • Kim, Tae-Hun;Sung, A-Young
    • Journal of the Korean Chemical Society
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    • v.54 no.6
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    • pp.755-760
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    • 2010
  • This study used 3-vinylanisole and 4-vinylanisole with the cross-linker EGDMA (ethylene glycol dimethacrylate), HEMA (2-hydroxyethyl methacrylate), MMA (methyl methacrylate), NVP (N-vinyl-2-pyrrolidone) and the initiator AIBN (azobisisobutyronitrile) for copolymerization. Measurement of the physical characteristics of the copolymerized material showed that the refractive index is 1.4496 - 1.4894, water content 22.93 - 35.50%, visible transmittance 88.8 - 90.8%. Also, measurements showed that the refractive index increased while the water content decreased as the ratio of 3-vinylanisole and 4-vinylanisole increased. And in cases of copolymer with 3-vinylanisole, 4-vinylanisole (added 15%) the results showed transmittance of 52.8 - 82.2%, 13.2 - 26.2% respectively for UV-A and UV-B showing that they have UV-blocking effects. Based on the results of this study, the produced copolymer can be estimated to be suitable for use as ophthalmic lens material for high refractive index and UV- blocking effects.

Synthesis of UV Curable 4,4'-Thiodibenzenethiol-based Epoxy Acrylate and Their Refractive Index Behavior (4,4'-Thiodibenzenethiol을 이용한 광경화형 에폭시 아크릴레이트 합성과 굴절률에 관한 연구)

  • Baek, Seung-Suk;Lee, Sang Won;Hwang, Seok-Ho
    • Polymer(Korea)
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    • v.37 no.1
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    • pp.121-126
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    • 2013
  • UV-curable high refractive index di-functional epoxy acrylate, 4,4'-thiodibenzenethiol diglycidyl ether diacrylate, was synthesized from acrylic acid and 4,4'-thiodibenzenethiol diglycidyl ether that was obtained by reacting 4,4'-thiodibenzenethiol and epichlorohydrin using a direct method (Taffy process). Its chemical structure was identified by $^1H$ NMR and FTIR. After its dilution with a reactive diluent, 2-phenoxythiol ethyl acrylate as 5, 10, 15, 20, and 30 wt% content, the relationship between their viscosity and refractive index was investigated. Their degree of cure decreased with increasing the amount of reactive diluent, and the refractive index of UV-cured film increased with increasing the degree of cure.

Characterization of Wood Chip Ash Generated from a Power Plant (열병합 발전소에서 발생한 우드칩 분진에 대한 특성 분석)

  • Bang, Jung Won;Kim, Soo-Ryong;Kim, Younghee;Kim, Mido;Kang, Won-Seok;Cho, Kye-Hong;Kwon, Woo-Teck
    • Resources Recycling
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    • v.26 no.1
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    • pp.11-15
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    • 2017
  • The amount of the wood chip ash is expected to increase continuously as demand of wood chip-based heat and electricity increase. Thus, there is increased interest in wood chip ash utilization. In this study, as a program of utilization in wood chip ash, the physical and chemical properties of wood chip ashes generated from a combined heat and power plant were investigated. The chemical analysis showed that the main contents of wood chip ash are composed of silica, alumina and alkali. A possibility of reuse as secondary cementitious materials was investigated by the analysis of strength activity index, and compared with coal ash. The highest value for Strength activity index of wood chip fly ash was 78% at 90 days curing time. This result revealed that wood chip fly ash has the potential to be utilized as the admixture for cementitious material.

Hyperspectral imaging technique to evaluate the firmness and the sweetness index of tomatoes

  • Rahman, Anisur;Park, Eunsoo;Bae, Hyungjin;Cho, Byoung-Kwan
    • Korean Journal of Agricultural Science
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    • v.45 no.4
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    • pp.823-837
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    • 2018
  • The objective of this study was to evaluate the firmness and the sweetness index (SI) of tomatoes with a hyperspectral imaging (HSI) technique within the wavelength range of 1000 - 1550 nm. The hyperspectral images of 95 tomatoes were acquired with a push-broom hyperspectral reflectance imaging system, from which the mean spectra of each tomato were extracted from the regions of interest. The reference firmness and sweetness index of the same sample was measured and calibrated with their corresponding spectral data by partial least squares (PLS) regression with different preprocessing methods. The calibration model developed by PLS regression based on the Savitzky-Golay second-derivative preprocessed spectra resulted in a better performance for both the firmness and the SI of the tomatoes compared to models developed by other preprocessing methods. The correlation coefficients ($R_{pred}$) were 0.82, and 0.74 with a standard error of prediction of 0.86 N, and 0.63, respectively. Then, the feature wavelengths were identified using a model-based variable selection method, i.e., variable importance in projection, from the PLS regression analyses. Finally, chemical images were derived by applying the respective regression coefficients on the spectral image in a pixel-wise manner. The resulting chemical images provided detailed information on the firmness and the SI of the tomatoes. The results show that the proposed HSI technique has potential for rapid and non-destructive evaluation of firmness and the sweetness index of tomatoes.