• 대한화학회지
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• 제59권5호
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• pp.407-412
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• 2015

A preconcentration procedure for determination of palladium by laser thermal lens spectrometry (TLS) is proposed. It is based on cloud point extraction of palladium(II) ions as 2-(3,5-dichloro-2-pyridylazo)-5-dimethylaminoaniline (3,5-diCl-PADMA) complexes using octylphenoxypolyethoxyethanol (Triton X-114) as surfactant. The effects of various experimental conditions such as pH, concentration of ligand and surfactant, equilibration temperature and time on cloud point extraction were studied. Under the optimized conditions, the calibration graph was linear in the range of 0.15~6 ng mL⁻¹, and the detection limit was 0.04 ng mL⁻¹ with an enrichment factor of 22. The sensitivity was enhanced by 846 times when compared with the conventional spectrophotometric method. The recovery of palladium was in the range of 96.6%~104.0%. The proposed method was applied to the determination of palladium in water samples.

• Korean Chemical Engineering Research
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• 제55권4호
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• pp.520-529
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• 2017

Viscosity data were measured at 298.15 K and 308.15 K for formamide + 1-propanol, 2-propanol, 1-butanol, 2-methyl-1-propanol or 2-methyl-2-propanol mixtures. For an equimolar mixture, deviation in viscosity follows the sequence: 2-methyl-2-propanol >2-methyl-1-propanol>1-butanol>2-propanol>1-propanol. The viscosity data were further analyzed in terms of graph theory. Free energy of activation was also calculated from experimental viscosity data along with previously reported excess volume data. The deviation in viscosity and free energy of activation were fitted to Redlich-Kister polynomial equation. The viscosity data were also correlated by correlations like Grunberg-Nissan, Tamura-Kurata, HindMcLaughlin-Ubbelohde, and Katti-Chaudhari relation. Various adjustable parameters, $G_{12}$, $T_{12}$, $H_{12}$, and $W_{vis}/RT$, of various correlations were used to predict viscosity deviation of binary mixtures. Positive value of $G_{12}$ indicates strong interaction in the studied systems. Grunberg-Nissan relation has lowest deviation among the four correlations for formamide + 1-propanol or 2-propanol mixtures; and for mixtures of formamide with 1-butanol or 2-methyl-1-propanol, TamuraKurata has lowest deviation. Grunberg-Nissan gives lowest deviation for formamide + 2-methyl-2-propanol mixtures.

• 센서학회지
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• 제24권4호
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• pp.270-273
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• 2015

One of the main problems when working the chemical sensor is the lack of repeatability and reproducibility of the sensor response. If the problem is not properly taken into consideration, the stability and reliability of the system using chemical sensors would be decreased. In this paper we analyzed the sensor's drift of short term and proposed a compensation method for reducing the effects of the drift in order to improve the stability and the reliability of the chemical sensor. The sensor drift was analyzed by a trend line graph and CV(coefficient of variation) was used to quantify. And we compensated for the drift by using the internal normalization. As a result it was found that the value of CV was decreased after compensation.

• 대한화학회지
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• 제60권5호
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• pp.327-341
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• 2016

This study explores the effective visual resources in the “regularity in chemical reactions” unit of ninth grade science textbooks (2009 revised version). The frequency and role of visual resources were initially examined, and the students’ perceptions of visual resources were investigated. The results of the analysis represented the learning material presentation (68%), motivational categories (14%), guide to inquiry procedures (9%), and inquiry results and summaries (8%). According to the investigation of the students’ perceptions of visual resources, the most effective visual resource for motivation is a photograph depicting physical and chemical changes, such as in bread baking and the most effective for learning material presentations in mass conservation, definite proportion, and stoichiometric concept units were a cartoon, graph, and formula representing stoichiometric phenomena, respectively. The most effective resource for guide to inquiry (experimental) procedures were photographs of both instruments and sequential experiment processes; and in the inquiry results and summary category, incomplete tables and graphs for students to work on themselves. The aims of this research are to increase the usefulness of visual resources in the teaching-learning activity and provide informative supplements for the development and improvement of visual resources, according to the students’ perceptions.

• Journal of applied mathematics & informatics
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• 제29권5_6호
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• pp.1075-1080
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• 2011

Among the numerous topological indices considered in chemical graph theory, only a few have been found noteworthy in practical application, Randi$\acute{c}$ index is one of them. The dendrimer nanostars is a synthesized molecule built up from branched unit called monomers. In this article, we compute the Randi$\acute{c}$ index of two types of polymer dendrimers and a fullerene dendrimer.

• Korean Journal of Chemical Engineering
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• 제35권12호
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• pp.2327-2335
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• 2018

Fluid catalytic cracking (FCC) is an important chemical process that is widely used to produce valuable petrochemical products by cracking heavier components. However, many difficulties exist in modeling the FCC process due to its complexity. In this study, a dynamic process model of a FCC process is suggested and its structural observability is analyzed. In the process modeling, yield function for the kinetic model of the riser reactor was applied to explain the product distribution. Hydrodynamics, mass balance and energy balance equations of the riser reactor and the regenerator were used to complete the modeling. The process model was tested in steady-state simulation and dynamic simulation, which gives dynamic responses to the change of process variables. The result was compared with the measured data from operating plaint. In the structural analysis, the system was analyzed using the process model and the process design to identify the structural observability of the system. The reactor and regenerator unit in the system were divided into six nodes based on their functions and modeling relationship equations were built based on nodes and edges of the directed graph of the system. Output-set assignment algorithm was demonstrated on the occurrence matrix to find observable nodes and variables. Optimal locations for minimal addition of measurements could be found by completing the whole output-set assignment algorithm of the system. The result of this study can help predict the state more accurately and improve observability of a complex chemical process with minimal cost.

• 센서학회지
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• 제25권4호
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• pp.291-296
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• 2016

The ideal chemical sensor must show the similar result under the same condition for accurate measurement of gases regardless of time. However, the actual responses of chemical sensors have been shown the lacks of repeatability and reproducibility because of the drift which has been caused by aging and pollution of the sensor and the environment change such as temperature and humidity. If the problems are not properly taken into considerations, the stability and reliability of the system using chemical sensors would be decreased. In this paper, we analyzed the sensor's drift and applied the three different compensation methods(DWT( Discrete Wavelets Transform), Baseline Manipulation, Internal Normalization) for reducing the effects of the drift in order to improve the stability and the reliability of short term of the chemical sensors. And in order to compare the results of the methods, the standard deviation was used as a criterion. The sensor drift was analyzed by a trend line graph. We applied the three methods to the successive data measured for three days and compared the results. As a result of comparison, the standard deviation of DWT showed lowest value. (Before compensation: 7.1219, DWT: 1.3644, Baseline Manipulation: 2.5209, Internal Normalization: 3.1425).

• 지능정보연구
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• 제2권1호
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• pp.11-26
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• 1996

본 논문에서는 화학공정의 이상 진단을 위한 지식 기반 조업 지원 시스템의 개발에 관하여 살펴보고자 한다. 조업지원 시스템에서 가장 핵심적인 부분은 공정에 비정상 상황이 발생한 경우 이를 감지하고, 공정에 발생한 증상들을 분석하여 이상의 근본 원인을 찾아내는 작업-이상 진단이다. 이상 진단을 효과적으로 수행하기 위해서는 적절한 데이터의 해석이 매우 중요한데, 기존의 데이터 해석법들은 정상상태에 기반한 방법들을 동적거동을 효과적으로 표현하기에는 어려움이 많다. 본 연구에서는 RBF에 기반한 신경망을 사용하여 동적을 효과적으로 표현할 수 있는 정성적인 데이터 해석 모듈을 구축하였으며, 이 모듈에서는 공정에서 측정된 정략적인 센서값들을 정성적인 정보로 가공하여 이상진단 모듈에 제공한다. 본 연구에서는 효과적인 이상진단을 위하여 기존의 인과관계 그래프 모델(Cause Effect DiGraph)에 기반한 두가지 그래프 모델을 개발하였다. RCED(Reduced Caue Effect Digraph)는 공정의 측정 변수만으로 공정의 인과관계를 표현하는 오프라인으로 구축된 지식베이스 모델이며, PGTT(Pattern Graph Through Time)는 공정에서 발생한 증상간의 인과관계를 실시간으로 나타내는 동적인 모델이다. 이상, 신경망에 기반한 정성적인 데이터 해석 모듈과 이상진단 모듈을 전문가 시스템 도구인 G2를 DEC AlphaStation 상에서 폴리프로필렌 공정에 대한 조업지원전문가 시스템을 구축하고 이를 적용하여보았다.

• Bulletin of the Korean Chemical Society
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• 제25권2호
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• pp.253-259
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• 2004

Some new topological indices based on the distance matrix and Randic connectivity (as graph invariants) are proposed. The calculation of these indices is simple and they have good discriminating ability toward alkanes. Incorporating the number of carbon atoms to one of the calculated indices gives a highly correlating topological index (Sh index) which found to correlate with selected physicochemical properties of wide range of alkanes, specially, their boiling points. Most of the investigated properties are well modeled (with $r^2$> 0.99) by the Sh index. Meanwhile, the resulting regressions were compared with the results based on the well-established Randic and newly reported Xu indices and, in most cases, better results were obtained by the Sh index. Moreover, multiple linear regression analysis of the alkane properties via calculated indices gives highly correlating models with low standard errors.

• Bulletin of the Korean Chemical Society
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• 제24권9호
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• pp.1261-1264
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• 2003

A method for the determination of trace amount of sulfide based on the addition reaction of sulfide with methyl green at pH 7.5 and $25{\circ}C$ is described. The reaction is monitored spectrophotometrically by measuring the decrease in absorbance of the dyestuff at 637 nm by the initial rate and fixed time method. The calibration graph is linear in the range 30-1200 ppb. The theoretical limit of detection was 0.014 ppm. Seven replicate analysis of a sample solution containing 0.70 ppm sulfide gave a relative standard deviation of 1.5%. The interfering effects of various ions on sulfide determination have been reported and procedures for removal of interference have been described. The proposed method was applied successfully to the determination of sulfide in tap and wastewater samples.