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A Study on the Thermal Characteristics of High Pressure Hydrogen Storage Tank according to Nozzle Angle and Length/Diameter Ratio (고압수소 저장용기의 노즐 각도 및 길이/직경비에 따른 열적 특성 연구)

  • JEONG HWAN YOON;JUNYEONG KWON;KYUNG SOOK JEON;JIN SIK OH;SEUNG JUN OH
    • Transactions of the Korean hydrogen and new energy society
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    • v.34 no.5
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    • pp.431-438
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    • 2023
  • Recently, study on hydrogen is being conducted due to environmental pollution and fossil fuel depletion. High-pressure gas hydrogen commonly used is applied to vehicle and tube trailers. In particular, high-pressure hydrogen storage tank for vehicles must comply with the guidelines stipulated in SAE J2601. There is a charging temperature limitation condition for the safety of the storage tank material. In this study, numerical analysis method were verified based on previous studies and the nozzle angle was changed for thermal management to analyze the increase in forced convection effect and energy uniformity due to the promotion of circulation flow. The previously applied high-pressure hydrogen storage tank has a length/diameter ratio of about 2.4 and was analyzed by comparing the length/diameter ratio with 8. As a result, the circulation flow of hydrogen flowing into the high-pressure hydrogen storage tank is promoted at a nozzle angle of 30° than the straight nozzle and accordingly, the effect of suppressing temperature rise by energy uniformity and forced convection was confirmed.

Comparison of WiFi Protocols for Safety Communication Between Hydrogen Refueling Station and Fuel Cell Electric Vehicle (수소충전소와 수소전기차간의 안전통신을 위한 WiFi 프로토콜 비교)

  • Ha-Jin Hwang;Dong-Geon So;Do-Ho Cha;Hye-Jin Chae;Seo-Hee Jung;Sung-Ho Hwang
    • The Journal of the Institute of Internet, Broadcasting and Communication
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    • v.23 no.6
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    • pp.81-87
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    • 2023
  • SAE J2601 and SAE J2799, the communication protocols between a hydrogen refueling station and a fuel cell electric vehicle, only cover hydrogen charging. In this paper, we measure the hydrogen detection, current, and voltage of a fuel cell electric vehicle and transmit the sensor data to the hydrogen refueling station by changing the WiFi protocol. A small-scale laboratory model was built using Raspberry Pi for sensing, controlling, and transmitting sensor data of a fuel cell electric vehicle. The sensor data was stored in the database of the hydrogen refueling station, and a dashboard was configured using Grafana to analyze the stored data. When hydrogen is detected, the dispenser valve of the hydrogen refueling station is locked. Then, we measured the average transmission delay according to the WiFi protocol. The results showed that IEEE 802.11a is the most suitable WiFi protocol for transmitting sensor data between the hydrogen refueling station and the fuel cell electric vehicle.

Synthesis of Carbon Coated Nickel Cobalt Sulfide Yolk-shell Microsphere and Their Application as Anode Materials for Sodium Ion Batteries (카본 코팅된 니켈-코발트 황화물의 요크쉘 입자 제조 및 소듐 이온 배터리의 음극 소재 적용)

  • Hyo Yeong Seo;Gi Dae Park
    • Journal of Powder Materials
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    • v.30 no.5
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    • pp.387-393
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    • 2023
  • Transition metal chalcogenides are promising cathode materials for next-generation battery systems, particularly sodium-ion batteries. Ni3Co6S8-pitch-derived carbon composite microspheres with a yolk-shell structure (Ni3Co6S8@C-YS) were synthesized through a three-step process: spray pyrolysis, pitch coating, and post-heat treatment process. Ni3Co6S8@C-YS exhibited an impressive reversible capacity of 525.2 mA h g-1 at a current density of 0.5 A g-1 over 50 cycles when employed as an anode material for sodium-ion batteries. However, Ni3Co6S8 yolk shell nanopowder (Ni3Co6S8-YS) without pitch-derived carbon demonstrated a continuous decrease in capacity during charging and discharging. The superior sodium-ion storage properties of Ni3Co6S8@C-YS were attributed to the pitch-derived carbon, which effectively adjusted the size and distribution of nanocrystals. The carbon-coated yolk-shell microspheres proposed here hold potential for various metal chalcogenide compounds and can be applied to various fields, including the energy storage field.

A Study on Impact Resistance Properties with Composition Materials and Installation Conditions of Protective Panel (방호 패널의 구성 재료 및 설치 조건에 따른 내충격 특성에 관한 연구)

  • Seok, Won-Kyun;Kim, Young-Sun;Lee, Yae-Chan;Nam, Jeong-Soo;Kim, Gyu-Yong
    • Journal of the Korea Institute of Building Construction
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    • v.23 no.6
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    • pp.715-726
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    • 2023
  • This study suggested that protective panels should be installed as sacrificial members as a safety design method for structures with potential explosions such as hydrogen charging stations to minimize direct damage to the structure and have resilience. To this end, the focus of the experiment is on quantitatively evaluating the impact of the structure when the protection panel is installed closely or spaced apart from the structure in a high-speed collision situation of the projectile. The experimental design used steel plates instead of concrete structural members mainly used in the past for excellent reproducibility, and the impact of structural members was compared and analyzed through deformation differences on the back of the steel plate. In addition, the impact of changes in the physical properties of the elastic body used as a separation material for the protective member and the difference in shock wave transmission time according to the protective member and the elastic body on the structural member was investigated.

Si@C/rGO Composite Anode Material for Lithium Ion Batteries (리튬 이온 전지용 음극으로서의 Si@C/rGO의 합성)

  • Chaehyun Kim;Sung Hoon Kim;Wook Ahn
    • Journal of the Korean Electrochemical Society
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    • v.27 no.2
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    • pp.73-79
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    • 2024
  • As the use of fossil fuels has gradually increased, so has the emission of greenhouse gases such as carbon dioxide, leading to environmental problems. As a result, lithium-ion batteries (LiB) have emerged as the solution to this issue. To manufacture medium to large-sized lithium-ion batteries (LiB), it requires electrodes with high capacity and fast charging capabilities. Silicon (Si) is considered a next-generation anode with high-capacity properties, so, reduced graphene oxide (rGO) was compounded with Si@resorcinol-formaldehyde resin (RF) composite to prevent the volume expansion of Si. It was confirmed that the composite anode prepared exhibited improved capacity and enhanced stability.

Understanding Thermal Runaway Phenomena in Overcharged Lithium-Ion Batteries (리튬이차전지의 과충전에 의한 열폭주 현상의 이해)

  • Minseo Lee;Ji-sun You;Kyeong-sin Kang;Jaesung Lee;Sungyool Bong
    • Journal of the Korean Electrochemical Society
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    • v.27 no.2
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    • pp.55-72
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    • 2024
  • Secondary batteries are used as an essential renewable energy source in our lives, such as electric vehicles and energy storage systems (ESS), as an alternative to fossil fuels due to global warming. However, cases of battery fires and explosions have been reported due to thermal runaway in secondary batteries due to various causes such as overdischarge, high-speed charging and discharging, and external short circuit, and great efforts are being made to find solutions suitable for each cause. In particular, as cases presumed to be caused by the overcharging process have been reported, this review will examine the chemical reactions of secondary batteries that can occur during the overcharging process and discuss risk investigation methods to check and prevent them.

Study on Dust Explosion Characteristics of Acetylene Black (Acetylene Black의 분진폭발 특성 연구)

  • Jae Jun Choi;Dong Myeong Ha
    • Journal of the Korean Society of Safety
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    • v.39 no.2
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    • pp.38-43
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    • 2024
  • Recently, with the expanding market for electronic devices and electric vehicles, secondary battery usage has been on the rise. Lithium-ion batteries are particularly popular due to their fast charging times and lightweight nature compared to other types of batteries. A secondary battery consists of four components: anode, cathode, electrolyte, and separator. Generally, the positive and negative electrode materials of secondary batteries are composed of an active material, a binder, and a conductive material. Acetylene Black (AB) is utilized to enhance conductivity between active material particles or metal dust collectors, preventing the binder from acting as an insulator. However, when recycling waste batteries that have been subject to high usage, there is a risk of fire and explosion accidents, as accurately identifying the characteristics of Acetylene Black dust proves to be challenging. In this study, the lower explosion limit for Acetylene Black dust with an average particle size of 0.042 ㎛ was determined to be 153.64 mg/L using a Hartmann-type dust explosion device. Notably, the dust did not explode at values below 168 mg, rendering the lower explosion limit calculation unfeasible. Analysis of explosion delay times with varying electrode gaps revealed the shortest delay time at 3 mm, with a noticeable increase in delay times for gaps of 4 mm or greater. The findings offer fundamental data for fire and explosion prevention measures in Acetylene Black waste recycling processes via a predictive model for lower explosion limits and ignition delay time.

The Effect of the Ratio of C45 Carbon to Graphene on the Si/C Composite Materials Used as Anode for Lithium-ion Batteries

  • Hoang Anh Nguyen;Thi Nam Pham;Le Thanh Nguyen Huynh;Tran Ha Trang Nguyen;Viet Hai Le;Nguyen Thai Hoang;Thi Thom Nguyen;Thi Thu Trang Nguyen;Dai Lam Tran;Thi Mai Thanh Dinh
    • Journal of Electrochemical Science and Technology
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    • v.15 no.2
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    • pp.291-298
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    • 2024
  • Due to its high theoretical capacity, Silicon (Si) has shown great potential as an anode material for lithium-ion batteries (LIBs). However, the large volume change of Si during cycling leads to poor cycling stability and low Coulombic efficiency. In this study, we synthesized Si/Carbon C45:Graphene composites using a ball-milling method with a fixed Si content (20%) and investigated the influence of the C45/Gr ratio on the electrochemical performance of the composites. The results showed that carbon C45 networks can provide good conductivity, but tend to break at Si locations, resulting in poor conductivity. However, the addition of graphene helps to reconnect the broken C45 networks, improving the conductivity of the composite. Moreover, the C45 can also act as a protective coating around Si particles, reducing the volume expansion of Si during charging/discharging cycles. The Si/C45:Gr (70:10 wt%) composite exhibits improved electrochemical performance with high capacity (~1660 mAh g-1 at 0.1 C) and cycling stability (~1370 mAh g-1 after 100 cycles). This work highlights the effective role of carbon C45 and graphene in Si/C composites for enhancing the performance of Si-based anode materials for LIBs.

Techno-economic Analysis on the Present and Future of Secondary Battery Market for Electric Vehicles and ESS (전기차와 ESS용 이차전지 시장의 현재와 미래에 대한 기술경제적 분석)

  • Jung Seung Lee;Soo Kyung Kim
    • Journal of Information Technology Applications and Management
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    • v.30 no.1
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    • pp.1-9
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    • 2023
  • Interest in the future of the battery market is growing as Tesla announces plans to increase production of electric vehicles and to produce batteries. Tesla announced an action plan to reduce battery prices by 56% through 'Battery Day', which included expansion of factories to internalize batteries and improvement of materials and production technology. In the trend of automobile electrification, the expansion of the battery market, which accounts for 40% of the cost of electric vehicles, is inevitable, and the size of the electric vehicle battery market in 2026 is expected to increase more than five times compared to 2016. With the development of materials and process technology, the energy density of electric vehicle batteries is increasing while the price is decreasing. Soon, electric vehicles and internal combustion locomotives are expected to compete on the same line. Recently, the mileage of electric vehicles is approaching that of an internal combustion locomotive due to the installation of high-capacity batteries. In the EV battery market, Korean, Chinese and Japanese companies are fiercely competing. Based on market share in the first half of 2020, LG Chem, CATL, and Panasonic are leading the EV battery supply, and the top 10 companies included 3 Korean companies, 5 Chinese companies, and 2 Japanese companies. All-solid, lithium-sulfur, sodium-ion, and lithium air batteries are being discussed as the next-generation batteries after lithium-ion, among which all-solid-state batteries are the most active. All-solid-state batteries can dramatically improve stability and charging speed by using a solid electrolyte, and are excellent in terms of technology readiness level (TRL) among various technology alternatives. In order to increase the competitiveness of the battery industry in the future, efforts to increase the productivity and economy of electric vehicle batteries are also required along with the development of next-generation battery technology.

Experimental Verification on the Extending Flight Time of Solar Paper for Drone using Battery for Electric Vehicles (장기 체공 태양광 드론의 비행시간 연장에 관한 실험적 검증)

  • Wooram Lee
    • Journal of the Institute of Convergence Signal Processing
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    • v.24 no.4
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    • pp.229-235
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    • 2023
  • Recently, for drones to be used for agricultural applications, it is necessary to increase the payload and extending flight time. Currently, the payload and extending flight time are limited by the battery technology for solar paper drone. In addition, charging or replacing the batteries may be a practical solution at the field that requires near continuous operation. In this paper, the procedure to optimize the main power system of an electric hybrid drone that consists of a battery and electric motor is presented. As a result, the solar paper drone flied successfully for 2-3%. The developed solar paper drone consumes and average of 55W when cruising and can receive up to 25W of energy during the day, and its extending flight time was verified through flight tests.