Journal of Powder Materials (한국분말재료학회지)

The Korean Powder Metallurgy & Materials Institute (한국분말재료학회 (*구 분말야금학회))
권호 표지
DOI QR코드

DOI QR Code

Synthesis of Carbon Coated Nickel Cobalt Sulfide Yolk-shell Microsphere and Their Application as Anode Materials for Sodium Ion Batteries

카본 코팅된 니켈-코발트 황화물의 요크쉘 입자 제조 및 소듐 이온 배터리의 음극 소재 적용

  • Hyo Yeong Seo (Department of Urban, Energy, and Environmental Engineering, Chungbuk National University) ;
  • Gi Dae Park (Department of Urban, Energy, and Environmental Engineering, Chungbuk National University)
  • 서효영 (충북대학교 도시에너지환경 융합학부) ;
  • 박기대 (충북대학교 도시에너지환경 융합학부)
  • Received : 2023.08.21
  • Accepted : 2023.09.19
  • Published : 2023.10.28
Download PDF
⟨ Previous Next ⟩

Abstract

Transition metal chalcogenides are promising cathode materials for next-generation battery systems, particularly sodium-ion batteries. Ni3Co6S8-pitch-derived carbon composite microspheres with a yolk-shell structure (Ni3Co6S8@C-YS) were synthesized through a three-step process: spray pyrolysis, pitch coating, and post-heat treatment process. Ni3Co6S8@C-YS exhibited an impressive reversible capacity of 525.2 mA h g-1 at a current density of 0.5 A g-1 over 50 cycles when employed as an anode material for sodium-ion batteries. However, Ni3Co6S8 yolk shell nanopowder (Ni3Co6S8-YS) without pitch-derived carbon demonstrated a continuous decrease in capacity during charging and discharging. The superior sodium-ion storage properties of Ni3Co6S8@C-YS were attributed to the pitch-derived carbon, which effectively adjusted the size and distribution of nanocrystals. The carbon-coated yolk-shell microspheres proposed here hold potential for various metal chalcogenide compounds and can be applied to various fields, including the energy storage field.

Keywords

Acknowledgement

본 논문은 충북대학교 국립대학육성사업(2022)지원을 받아 작성되었습니다.

References

  1. M. Li, J. Lu, Z. Chen and K. Amine: Adv. Mater., 30 (2018) 1800561. 
  2. L. Deguenon, D. Yamegueu and A. Gomna: J. Power Sources, 580 (2023) 233343. 
  3. T. Kim, W. Song, D.-Y. Son, L. K. Ono and Y. Qi: J. Mater. Chem. A, 7 (2019) 2942. 
  4. Y. Wang, B. Liu, Q. Li, S. Cartmell, S. Ferrara, Z. D. Deng and J. Xiao: J. Power Sources, 286 (2015) 330. 
  5. C. Delmas: Adv. Energy Mater., 8 (2018) 1703137. 
  6. J.-Y. Hwang, S.-T. Myung and Y.-K. Sun: Chem. Soc. Rev., 46 (2017) 3529. 
  7. C. Vaalma, D. Buchholz, M. Weil and S. Passerini: Nat. Rev. Mater., 3 (2018) 1. 
  8. C. Dong, L. Wu, Y. He, Y. Zhou, X. Sun, W. Du, X. Sun, L. Xu and F. Jiang: Small, 16 (2020) 2004580. 
  9. H. Liu, M. Jia, Q. Zhu, B. Cao, R. Chen, Y. Wang, F. Wu and B. Xu: ACS Appl. Mater. Interfaces, 8 (2016) 26878.
  10. Y. Zhao, Q. Fu, D. Wang, Q. Pang, Y. Gao, A. Missiul, R. Nemausat, A. Sarapulova, H. Ehrenberg and Y. Wei: Energy Storage Mater., 18 (2019) 51.
  11. Z. Liu, T. Lu, T. Song, X.-Y. Yu, X. W. D. Lou and U. Paik: Energy Environ. Sci., 10 (2017) 1576.
  12. G. K. Veerasubramani, Y. Subramanian, M.-S. Park, G. Nagaraju, B. Senthilkumar, Y.-S. Lee and D.-W. Kim: J. Mater. Chem. A, 6 (2018) 20056.
  13. H. Tan, Y. Feng, X. Rui, Y. Yu and S. Huang: Small Methods, 4 (2020) 1900563.
  14. Z. Hao, X. Shi, Z. Yang, L. Li and S. L. Chou: Adv. Funct. Mater., 32 (2022) 2208093.
  15. Y. Gong, Y. Li, Y. Li, M. Liu, Y. Bai and C. Wu: Small, 19 (2023) 2206194.
  16. G. Huang, T. Chen, Z. Wang, K. Chang and W. Chen: J. Power Sources, 235 (2013) 122.
  17. S. Li, W. He, B. Liu, J. Cui, X. Wang, D.-L. Peng, B. Liu and B. Qu: Energy Storage Mater., 25 (2020) 636.
  18. W. Chen, X. Liu, J. Wu, Q. Wang, Y. Zhang, S. Yan, P. Hou and S. Luo: J. Electroanal. Chem., 929 (2023) 117095.
  19. M. Kim, G. D. Park and Y. C. Kang: Int. J. Energy Res., 46 (2022) 5800.
  20. C. Wu, X. Tong, Y. Ai, D.-S. Liu, P. Yu, J. Wu and Z. M. Wang: Nano-Micro Lett., 10 (2018) 1.
  21. J. Liu, S.Z. Qiao, J. S. Chen, X. W. D. Lou, X. Xing and G. Q. M. Lu: Chem. Commun., 47 (2011) 12578.
  22. Y. J. Hong, M. Y. Son and Y. C. Kang: Adv. Mater., 25 (2013) 2279.
  23. D. S. Jung, Y. N. Ko, Y. C. Kang and S. B. Park: Adv. Powder Technol., 25 (2014) 18.
  24. L. Zhang, Y. Huang, Y.-E. Miao, W. Fan and T. Liu: CompComm, 21 (2020) 100395.
  25. J. H. Kim, G. D. Park and Y. C. Kang: Int. J. Energy Res., 45 (2021) 14910.
  26. X. Liu, X. Li, X. Lu, X. He, N. Jiang, Y. Huo, C. Xu and D. Lin: J. Alloys Compd., 854 (2021) 157132.