• Bulletin of the Korean Chemical Society
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• v.20 no.6
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• pp.667-671
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• 1999

A series of the para-substituted 7-aryl-norbornadienyl cation (3) was prepared in FSO3H/SO2ClF solution at -100℃ and their 13C NMR shifts were measured at -80℃. The plots of the chemical shifts (changes in chemical shifts) of cationic carbon, ΔδC+, aganist our calculated new substituent constant, σc+s, gave an excellent correlation (r=0.994), with a ρc+ value of 12.63. These results indicate that the new substituent constants, σc+s, can be successfully employed to compare the relative charge demand of the carbonium ion by π-and πσ-participation.

• Journal of Digital Convergence
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• v.17 no.7
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• pp.131-138
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• 2019

The world's electricity production ratio is 40% for coal, 20% for natural gas, 16% for hydroelectric power, 15% for nuclear power and 6% for petroleum. Fossil fuels also cause serious problems in terms of price and supply because of the high concentration of resources on the earth. Solar energy is attracting attention as a next-generation eco-friendly energy that will replace fossil fuels with these problems. In this study, we test the charge-operation plan and the discharge operation plan for peak-cut operation by applying the maximum power demand reduction simulation. To do this, we selected the electricity usage from November to February, which has the largest amount of power usage, and applied charge / discharge logic. Simulation results show that the contract power decreases as the peak demand power after the ESS Peak-cut service is reduced to 50% of the peak-target power. As a result, the contract power reduction can reduce the basic power value of the customer and not only the economic superiority can be expected, but also contribute to the improvement of the electric quality and stabilization of the power supply system.

• Journal of the Korea Society of Computer and Information
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• v.24 no.3
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• pp.29-39
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• 2019

In this study, we introduce a model that satisfies energy efficiency and economical efficiency by introducing and demonstrating cogeneration generators in industrial complexes using various actual data collected at the site. The proposed model is composed of three scenarios, ie, full - time operation, scenario operated according to demand, and a fusion type. In this study, the power generation profit and surplus thermal energy are measured according to the operation of the generator, and the thermal energy is traded according to the demand of the customer to calculate the profit and loss including the heat and evaluate the economic efficiency. As a result of the study, it is relatively profitable to reduce the generation of the generator under the condition that the electricity rate is low and the gas rate is high, while the basic charge is not increased. On the contrary, if the electricity rate is high and the gas rate is low, The more you start up, the more profit you can see. These results show that even a cogeneration power plant with a low economic efficiency due to a low "spark spread" has sufficient economic value if it can sell more than a certain amount of heat energy from a nearby customer and adjust the applied power through peak management.

• Journal of the Korean Applied Science and Technology
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• v.33 no.2
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• pp.385-390
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• 2016

In our study, ceramics coatings by additives of nano alumina and magnesia have cured on 304 stainless steel at $170^{\circ}C$ 2h. We designed and experimented the coated specimens that were characterized by laser induced fluorescence spectroscopy using the charge coupled device and scanning electronic microscopy(SEM). The result was revealed the ceramic coatings added fillers has more excellent on adhesive property and scratch resistance, and less weight loss in acid solution than ceramic coatings non-added fillers. Therefore, this study has designed and manufactured the electromagnetic spectrometry with CCD and then analyzed the coatings on 304 stainless steel using the High Resolution Charge Coupled Device in improving the corrosion resistance of 304 stainless steel. Nowadays, coatings of stainless steel have increased by industrial demand in hygienes, aviation, instrumentations and robotics as the industry special application develops.

• Journal of the Korean Ceramic Society
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• v.49 no.6
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• pp.631-636
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• 2012

Conventional SONOS (poly-silicon/oxide/nitride/oxide/silicon) type memory is associated with a retention issue due to the continuous demand for scaled-down devices. In this study, $Al_2O_3/Y_2O_3/SiO_2$ (AYO) multilayer structures using a high-k $Y_2O_3$ film as a charge-trapping layer were fabricated for nonvolatile memory applications. This work focused on improving the retention properties using a $Y_2O_3$ layer with different tunnel oxide thickness ranging from 3 nm to 5 nm created by metal organic chemical vapor deposition (MOCVD). The electrical properties and reliabilities of each specimen were evaluated. The results showed that the $Y_2O_3$ with 4 nm $SiO_2$ tunnel oxide layer had the largest memory window of 1.29 V. In addition, all specimens exhibited stable endurance characteristics (program/erasecycles up to $10^4$) due to the superior charge-trapping characteristics of $Y_2O_3$. We expect that these high-k $Y_2O_3$ films can be candidates to replace $Si_3N_4$ films as the charge-trapping layer in SONOS-type flash memory devices.

• Advances in materials Research
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• v.8 no.1
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• pp.37-46
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• 2019

Electrochemical double layer capacitors (EDLCs) which are fabricated using carbon based electrodes have been emerging at an alarming rate to fulfill the energy demand in the present day world. Activated charcoal has been accepted as a very suitable candidate for electrodes but its cost is higher than natural graphite. Present study is about fabrication of EDLCs using composite electrodes with activated charcoal and Sri Lankan natural graphite as well as a gel polymer electrolyte which is identified as a suitable substitute for liquid electrolytes. Electrochemical Impedance Spectroscopy, Cyclic Voltammetry and Galvanostatic Charge Discharge test were done to evaluate the performance of the fabricated EDLCs. Amount of activated charcoal and natural graphite plays a noticeable role on the capacity. 50 graphite : 40 AC : 10 PVdF showed the optimum single electrode specific capacity value of 15 F/g. Capacity is determined by the cycling rate as well as the potential window within which cycling is being done. Continuous cycling resulted an average single electrode specific capacity variation of 48 F/g - 16 F/g. Capacity fading was higher at the beginning. Later, it dropped noticeably. Initial discharge capacity drop under Galvanostatic Charge Discharge test was slightly fast but reached near stable upon continuous charge discharge process. It can be concluded that initially some agitation is required to reach the maturity. However, the results can be considered as encouraging to initiate studies on EDLCs using Sri Lankan natural graphite.

• Journal of muscle and joint health
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• v.28 no.1
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• pp.18-29
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• 2021

Purpose: This study examined the knowledge and education needs of nurses in charge of adequacy evaluation in small and medium-sized hospitals. Methods: Study participants included 198 nurses in charge of adequacy evaluation in small and medium-sized hospitals. Data were collected from November 19 to 28, 2020 through an online survey. The data were analyzed by independent t-test and one way ANOVA analysis using the SPSS. Results: The knowledge score for the adequacy evaluation of small and medium-sized hospitals was 11.61±4.10 (total of 20 points), and the educational demand was 3.87±0.88 points on a 5-point scale. Regarding the necessity of education for adequacy evaluation of small and medium-sized hospitals, 80.3% of the participants claimed education as being necessary. "Online video lectures" were the most preferred (22.7%) education method, and "2 times" was the most frequent education (47.0%); "1 hour" was the usual duration of class (48.5%). Conclusion: It is necessary to develop and apply an educational program reflecting the measure of educational needs to improve the knowledge level of nurses in charge of adequacy evaluation in small and medium-sized hospitals.

• KSCE Journal of Civil and Environmental Engineering Research
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• v.26 no.1D
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• pp.49-58
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• 2006

The purpose of this study is to develop transportation-sensitive land use densities in a metropolitan context. It analyses traffic impacts according to 20 different development density scenarios in the downtown Seoul, and estimates the density ceiling. The results identify that the transportation-wise sustainable density in the downtown can be extended up to the FAR level of 460% with an option of 2,000 won congestion charge levied on the downtown area. It also finds that the region-wide sustainability measured by congestion level can be improving as the level of congestion charge increases. Without the congestion charge, however, the density ceiling slides down to 430%. It is recommended that, in order to bring in higher density developments in the region, transportation demand management (TDM) measures are indispensible.

• The Journal of Korean Academic Society of Nursing Education
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• v.4 no.2
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• pp.131-146
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• 1998

The study was attempted and executed to reach the following conclusions. The period was May 1st through June 15th, 1998 and the subjects were 302 teachers consisting of School Nurses and general teachers in Pusan city. 1) The degrees of recognition of sexual roles by the subjects were compared as follows : The average point as to the recognition of sexual roles in the occupational functions by the school nurses was 2.41, higher than that of the general teachers. The average points as to the recognition of sexual roles in the attitudes by the school nurses was 2.28, higher than that of the general teachers. The average points as to the recognition of sexual roles in the abilitis was 2.26, higher than that of the general teachers. These ascertain that school nurses recognize the man has higher superities in the occupational functions, the attitudes and the abilities than the woman. 2) The degrees of demand of sexual education by the subjects were compared as follows : As to the degrees of demand of sexual education, the school nurses showed higher demand than the general teachers in the concepts such as 'the society and sexualities, physiology and actual education'. 3) The levels of the consciousness of sexual education by the subjects were compared as follows : the general teachers showed the more strict attitudes than the school nurses against the lascivious sex objects and wanted the punishment against the related students and the general teachers have myth. They claimed that their family have no relation with the sexual violence or pornography. As to the masturbation, the general teachers showed the more conservative attitudes. 4) The opinions by the subjects as to the well-qualified person in charge of sexual education in school were compared as follows : 77.3% of the school nurses, and 36.1% of the general teachers supported the school nurses.

• The Transactions of The Korean Institute of Electrical Engineers
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• v.67 no.10
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• pp.1278-1285
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• 2018

For saving electricity bill, energy storage system(ESS) is being installed in factories, public building and commercial building with a Time-of-Use(TOU) tariff which consists of demand charge(KRW/kW) and energy charge(KRW/kWh). However, both of peak reduction and ESS special tariff are not considered in an analysis of initial cost payback period(ICPP) on ESS. Since it is difficult to reflect base rate by an amount of uncertain peak demand reduction during mid-peak and on-peak periods in the future days. Therefore, the ICPP on ESS can be increased. Based on this background, this paper presents the advanced analysis method for the ICPP on ESS. In the proposed algorithm, the representative days of monthly electricity consumption pattern for the amount of peak reduction can be found by the k­means clustering algorithm. Moreover, the total expected energy costs of representative days are minimized by optimal daily ESS operation considering both peak reduction and the special tariff through a mixed-integer linear programming(MILP). And then, the amount of peak reduction becomes a value that the sum of the expected energy costs for 12 months is maximum. The annual benefit cost is decided by the amount of annual peak reduction. Two simulation cases are considered in this study, which one only considers the special tariff and another considers both of the special tariff and amount of peak reduction. The ICPP in the proposed method is shortened by 18 months compared to the conventional method.