• Title/Summary/Keyword: changes of grain size

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The Effects of Substrate Temperature on Electrical and Physical Properties of ZnO:Al for the Application of Solar Cells (태양전지 응용을 위한 ZnO:Al 박막의 전기적·물리적 특성에서 증착 온도의 영향)

  • Park, Chan Il
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.34 no.1
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    • pp.39-43
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    • 2021
  • In the case of ZnO:Al thin films, it is the best material that can replace ITO that is mainly used as a transparent electrode in electronic devices such as solar cells and flat-panel displays. In this study, ZnO:Al films were fabricated by using the RF dual magnetron sputtering method at various substrate temperatures. As the substrate temperature increased, the crystallinity of the ZnO:Al thin films was improved, and the electrical conductivity and electrical properties of the thin film improved owing to the increase in grain size. In addition, the surface roughness of the ZnO:Al thin films increased due to changes in the surface and density of the thin films. Moreover, the substrate temperature increased the density of thin films and improved their transmittance. To be applied to solar cells and other several electronic devices in the future, the hardness and adhesion properties of the thin film improve as the substrate temperature increases.

A Study on the Landscape Change and Management Plan for Seomjin River Chimsil Wetland through Aerial Photograph and Sediment Analysis (항공사진 및 퇴적물 분석을 통한 섬진강 침실습지 경관변화와 관리방안)

  • Lee, Seong-Ho;JANG, Dong-Ho
    • Journal of The Geomorphological Association of Korea
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    • v.27 no.3
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    • pp.25-39
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    • 2020
  • This study analyzed the management plan of Seomjin River Chimsil Wetland by identifying landscape changes through aerial photographs analysis and concentrations of sedimentation. Geophysical Landscape Change Analysis showed that vegetation accounts for more than half of the total area. The Barren land and water body was somewhere repeatedly increased and decreased and made an irregular form in the study area. The soil was acidic, and no eurtophication was shown, but it was potential to form wetland. In addition, the research area has been terrestrification of sand bar for a long period of time, forming a soil layer. Although the characteristics of river deposits were shown in the study area, the grain size was a particulate matter, and the sorting was 'very poorly sorted'. In some areas of Seomjin River Chimsil Wetland, sand bars were formed, but most areas were undergoing to terrestrification. Therefore, in order to preserve the riverine area and to serve by a bridge between the land ecosystem and the underwater ecosystem, it is very necessary to remove some vegetation, create a proper waterway, and restore the wetland.

Spectral Reflectance of Mongsanpo Tidal Flat, Korea, by using Spectroradiometer Experiments and Landsat Data

  • Kim, Bum-Jun;Lee, Sungsoon;Lee, Hoonyol
    • Korean Journal of Remote Sensing
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    • v.33 no.4
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    • pp.411-422
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    • 2017
  • This research aims to analyze spectral reflectance of intertidal zone and its changes under various environmental conditions. We sampled sand of Mongsanpo tidal flat, Korea, and measured its spectral reflectance by using a spectroradiometer under various water contents, compositions and granularity. We also simulated the reflectance of Landsat 7 ETM+ and compared it with an actual satellite data. Five locations were selected for sampling from the coastline towards the ocean. Grain size diminished stepwise from the coastline to ocean direction, while spectral reflectance differed with wavelength. Water contents lowered the overall reflectance especially at the water absorption bands. Spectral reflectance data were then converted into the simulated one by using Landsat 7 ETM+ spectral reflectance function to be compared with the actual Landsat 7 ETM+ images. It showed the decrease of the spectral reflectance due to the increase of moisture contents from seashore towards the ocean. It is shown that Landsat 7 ETM+ imagery can be efficient to extract moisture contents in the tidal flat while compositional analysis needs satellite sensors with much higher spectral resolution.

Electrocaloric effect in heterolayered potassium tantalate niobate thin films prepared by sol-gel method

  • Byeong-Jun Park;Sam-Haeng Lee;Ji-Won Kim;Joo-Seok Park;Sung-Gap Lee
    • Journal of Ceramic Processing Research
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    • v.22 no.2
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    • pp.214-220
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    • 2021
  • Heterolayered potassium tantalate niobate(KTN(70/30)/KTN(30/70)) thin films on Pt/Ti/SiO2/Si substrates prepared by the sol-gel process and spin coating method. When sintered at 700 ℃ or higher, the X-ray diffraction intensities of the perovskite phase were greatly increased, and it was observed as the main phase of the KTN heterolayered thin film. As the sintering temperature increased from 650 ℃ to 800 ℃, the average grain size increased from 146nm to 380 nm, and the average thickness of the KTN films coated six times was about 394-441 nm. Dielectric constant and dielectric loss of the KTN film sintered at 750 ℃ and room temperature showed good properties of about 2850 and 0.573, respectively, and all films exhibited the typical dielectric relaxation characteristics. The phase transition temperature of KTN thin film was around 12-13 ℃. Remanent polarization and the coercive field of KTN film sintered at 750 ℃ showed excellent properties of 23.98 μC/cm2 and 35.41 kV/cm, respectively. Adiabatic temperature changes (ΔT) and electrocaloric strength of the KTN films sintered at 750 ℃ at 60 ℃ were 2.67℃ and 0.012 KcmkV-1, respectively.

Microwave Dielectric Properties of 0.95Ca0.85Nd0.1TiO3−0.05LnAlO3 (Ln=Sm, Dy, Er) Ceramics

  • Kim, Eung-Soo;Jeon, Chang-Jun
    • Journal of the Korean Ceramic Society
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    • v.44 no.10
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    • pp.537-541
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    • 2007
  • Microwave dielectric properties of $0.95 Ca_{0.85}Nd_{0.1}TiO_3-0.05LnAlO_3$ (Ln=Sm, DH, Er) were investigated as a function of sintering temperature and lanthanide ion type. A single perovskite phase with an orthorhombic structure was obtained throughout the entire range of composition. The dielectric constant (K) was dependent upon the dielectric polarizabilities and the B-site bond valence in the $ABO_3$ perovskite structure. The quality factor (Qf) of the specimens with $ErAlO_3$ was smaller than those with $SmAlO_3\;and/or\;DyAlO_3$ due to the smaller grain size. The temperature coefficient of resonant frequency (TCF) could be controlled from $107.28ppm/^{\circ}C$ at Ln=Sm to $87.23ppm/^{\circ}C$ at Ln=Er due to the changes of B-site bond valence in the $ABO_3$ perovskite structure.

Structural Analyses and Properties of $Ti_{1-x}Al_xN$ Films Deposited by PACVD Using a $TiCl_4/AlCl_3/N_2/Ar/H_2$ Gas Mixture ($TiCl_4/AlCl_3/N_2/Ar/H_2$ 반응계를 사용하는 플라즈마화학증착법에 의한 $Ti_{1-x}Al_xN$ 박막의 구조분석 및 물성)

  • 김광호;이성호
    • Journal of the Korean Ceramic Society
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    • v.32 no.7
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    • pp.809-816
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    • 1995
  • Ti1-xAlxN films were successfully deposited on high speed steel and silicon wafer by plasma-assisted chemical vapor deposition using a TiCl4/AlCl3/N2/Ar/H2 gas mixture. Plasma process enabled N2 gas to nitride AlCl3, which is not possible in sense of thermodynamics. XPS analyses revealed that the deposited layer contained Al-N bond as well as Ti-N bond. Ti1-xAlxN films were polycrystalline and had single phase, B1-NaCl structure of TiN. Interplanar distance, d200, of (200) crystal plane of Ti1-xAlxN was, however, decreased with Al content, x. Al incorporation into TiN caused the grain size to be finer and changed strong (200) preferred orientation of TiN to random oriented microstructure. Those microstructural changes with Al addition resulted in the increase of micro-hardness of Ti1-xAlxN film up to 2800Kg/$\textrm{mm}^2$ compared with 1400Kg/$\textrm{mm}^2$ of TiN.

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Improvement of Chloride Induced Stress Corrosion Cracking Resistance of Welded 304L Stainless Steel by Ultrasonic Shot Peening

  • Hyunhak Cho;Young Ran Yoo;Young Sik Kim
    • Corrosion Science and Technology
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    • v.23 no.4
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    • pp.266-277
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    • 2024
  • Due to its good corrosion and heat resistance with excellent mechanical properties, 304L stainless steel is commonly used in the fabrication of spent nuclear fuel dry storage canisters. However, welds are sensitive to stress corrosion cracking (SCC) due to residual stress generation. Although SCC resistance can be improved by stress relieving the weld and changing the chloride environment, it is difficult to change corrosion environment for certain applications. Stress control in the weld can improve SCC resistance. Ultrasonic shot peening (USP) needs further research as compressive residual stresses and microstructure changes due to plastic deformation may play a role in improving SCC resistance. In this study, 304L stainless steel was welded to generate residual stresses and exposed to a chloride environment after USP treatment to improve SCC properties. Effects of USP on SCC resistance and crack growth of specimens with compressive residual stresses generated more than 1 mm from the surface were studied. In addition, correlations of compressive residual stress, grain size, intergranular corrosion properties, and pitting potential with crack propagation rate were determined and the improvement of SCC properties by USP was analyzed.

Charaterization of (Bi,La)Ti3O12 Ferroelectric Thin Films on Pt/Ti/SiO2/Si Substrates by sol-gel Method (졸-겔법으로 Pt/Ti/SiO2/Si 기판위에 제작된 (Bi,La)Ti3O12 강유전체 박막의 특성 연구)

  • Hwang, Sun-Hwan;Chang, Ho-Jung
    • Korean Journal of Materials Research
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    • v.12 no.11
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    • pp.835-839
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    • 2002
  • Metal-Ferroelectric-Metal(MFM) capacitors were prepared using $Bi_{3.3}$ $La_{0.7}$ $Ti_3$$O_{12}$ (BLT) ferroelectric thin films which were spin coated on $Pt/Ti/SiO_2$/Si substrates by the Sol-Gel method. BLT thin films annealed at above $650^{\circ}C$ showed polycrystalline structures with typical c-axis preferred orientation. The grain size and surface roughness were increased as the annealing temperature increased from $650^{\circ}C$ to $700^{\circ}C$. In addition, the full width at half maximum (FWHM) values were decreased with increasing annealing temperatures, indicating the improvement of crystallinity. The remanent polarization (2Pr= $Pr^{+}$ $+Pr^{-) }$ and leakage current of the BLT film annealed at $650^{\circ}C$ were about 29.3 $\mu$C/cm$^2$ and $2.3$\times$10^{-8}$$ A/cm^2$ at 3V. There were no distinct changes in the retention charges after $10^{10}$ polarization switching cycles, showing good fatigue property of the annealed BLT films.

The Effect of Sputtering Conditions on Magnetic Properties of CoCrMo/Cr Magnetic Thin Film (CoCrMo/Cr 자성박막의 제조조건이 자기적성질에 미치는 영향)

  • 박정용;남인탁;홍양기
    • Journal of the Korean Magnetics Society
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    • v.3 no.4
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    • pp.320-324
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    • 1993
  • The effect of sputtering conditions on magnetic properties of CoCrMo/Cr magnetic thin film was investigated. Substrate temperature were controlled from R. T to $250^{\circ}C$. The thickness changes of Cr underlayer and CoCrMo magnetic layer were in the range of $1000-2500\AA$ and $300-800\AA$, respectively. Grain size was found to be decreased with increasing magnetic layer thickness(from $500\AA$ to $800\AA$). CoCrMo magnetic layer microstructure showed relatively small dependence on Cr underlayer thickness, substrate temperature. Coercivity increased with increasing Cr underlayer, magnetic layer thickness and substrate temperature. CoCrMo/Cr thin film showed a coercivity of 880 Oe in $700\AA$ magnetic layer thickness and $1000\AA$ Cr underalyer thickness.

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Formation and Recent Changes of the Okjukdong Dunefield, Daecheong Island (대청도 옥죽동 사구의 형성과 최근의 변화)

  • Choi, Kwang Hee;Kong, Hak-Yang
    • Journal of The Geomorphological Association of Korea
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    • v.24 no.4
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    • pp.91-101
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    • 2017
  • The Okjukdong dune in Daecheong Island attracts national attention because of its unique landscape that is not covered by vegetation. However, there has been little knowledge on the timing of the dune formation, associated wind regime, and conservational strategies. In this study, we used OSL dating and grain size analyses to reveal the history of the dune development. In addition, we analyzed the wind regime in the dunefield which is surrounded by artificial coastal forest. The fine sand at Okjukdong underlain by a colluvial gravel layer indicates that the dune has been developed since at least 5 ka. Aeolian sands were found to be deposited around 700 years ago. The dunefield appears to have been severely eroded 30~60 years ago. The dune landscape has been destroyed after constructing a windbreak forest around the dunefield. The sand seems to be moving south and north with the season.