• Title/Summary/Keyword: ceramic composite

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Thermal Shock Resistance of $80Al_2O_3-20Al$ Composites: Experiments and Finite Element Analysis ($80Al_2O_3-20Al$ 복합재료의 내열충격성: 실험과 유한요소 해석)

  • 김일수;신병철
    • Journal of the Korean Ceramic Society
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    • v.37 no.3
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    • pp.201-204
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    • 2000
  • Thermal shock resistance of 80Al2O3-20Al composite and monolithic alumina ceramics was compared. Fracture strength was measured by using a 4-pont bending test after quenching. Thermal stresses of the ceramics and ceramic-metal composites were calculated using a finite element analysis. The bending strength of the Al2O3 ceramics decreased catastropically after quenching from 20$0^{\circ}C$ to $0^{\circ}C$. The bending strength of the composite also decreased after quenching from 200~2$25^{\circ}C$, but the strength reduction was much smaller than for Al2O3. The maximum thermal stress occured in the monolithic alumina ceramics when exposed to a temperature difference of 20$0^{\circ}C$ was 0.758 GPa. The same amount of stress occured in the Al2O3-Al composite when the temperature difference of 205$^{\circ}C$ used.

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Correlatin between the Microstructure and the Electrical Conductivity of SOFC anode, Ni-YSZ : I. Microstructure Analysis (SOFC 음극용 Ni-YSZ 복합체의 미세구조와 전기적 물성간의 상관관계 : I. 미세구조 분석)

  • Moon, Hwan;Lee, Hae-Weon;Lee, Jong-Ho;Yoon, Ki-Hyun
    • Journal of the Korean Ceramic Society
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    • v.37 no.5
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    • pp.479-490
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    • 2000
  • The microstructure of Ni-YSZ composite as an anode of SOFC was investigated as a function of Ni content(10-70 vol%) in order to examine the correlation between microstructural-and electrical property. Image analysis based on quantitative microscopy theory was performed to quantify the microstructural property. We could get the informations about the size and distribution, contiguity and interfacial area of each phase or between the phases from the image analysis. According to the image analysis, contiguity between the same phae was mainly dependent on the amount of the phase while the contiguity between different phases was additionally influenced by the microstructural changes, especailly by the coarsening of the Ni phase. The whole length of pores perimeter was increased as Ni content increased, which indicated the overall microstructural evolution was mostly related with the coarsening of Ni phase. Ni-Ni interfacial area was also gradually increased as Ni content increased but controlled by pore phase at low Ni content region and by YSZ phase at intermediate Ni content region. These quantified microstructural properties were used to characterize the electrical properties of Ni-YSZ composite.

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Dielectric Properties in Cordierite/Glass Composite for LTCC Material (LTCC소재용 Cordierite/Glass Composite계의 유전특성 변화)

  • Hwang, Il-Sun;Shin, Hyo-Soon;Yeo, Dong-Hun;Kim, Jong-Hei
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2007.06a
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    • pp.304-304
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    • 2007
  • 고주파 모률에서 사용되는 기판소재는 저유전율과 낮은 loss 특성을 요구함으로 지속적인 연구를 필요로 한다. 지금까지의 ceramic/glass composite 에서 주로 사용된 ceramic filler는 Al2O3로 낮은 유전률을 구현에 한계가 있었다. Cordierite는 낮은 유전율 (${\varepsilon}_r$ < 4)을 나타내는 filler로서 그 가능성이 높지만 아직까지 보고된 결과들이 미흡한 실정이다. 따라서 본 연구에서는 cordierite filler와 SiO2-B2O3-Al2O3-RO (R : Zn, Sr, Ba, Ca)계의 glass를 혼합하여 LTCC용 기판소재로서의 가능성을 확인하고자 저온 동시소성이 가능한 소결온도인 $850^{\circ}C{\sim}1.000^{\circ}C$ 사이에서 소재의 소결실험을 진행하였다. 소결온도에 따른 상변화, 유전특성을 확인한 결과 filler로 사용된 cordierite상만이 관찰 되었으며 소결조건에 따라 5.0~5.5의 낮은 유전율과 1.000~1,500의 Q를 나타내는 것을 확인 하였다.

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Effect of the marginal position of prosthesis on stress distribution of teeth with abfraction lesion using finite element analysis (보철물 변연의 위치가 abfraction된 치아의 응력 분포에 미치는 영향에 대한 유한요소법적 분석)

  • Kim, Myeong-Hyeon;Lee, Cheong-Hee
    • The Journal of Korean Academy of Prosthodontics
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    • v.52 no.3
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    • pp.202-210
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    • 2014
  • Purpose: The aim of this study was to evaluate the stress concentration and distribution whether restoring the cavity or not while restoring with metal ceramic crown on tooth with abfraction lesion using finite element analysis. Materials and methods: Maxillary first premolar was selected and made a total of 10 finite element model. Model 1 was natural tooth; Model 2 was tooth with metal ceramic crown restoration which margin was positioned above 2 mm from CEJ; Model 3 was tooth with metal ceramic crown restoration which margin was positioned on CEJ; Model 4 was natural tooth which has abfraction lesion; Model 5 and 6 had abfraction lesion and the other condition was same as model 2 and 3, respectively; Model 7 was natural tooth which had abfraction lesion restored with composite resin; Model 8 and 9 was tooth with metal ceramic crown after restoring on abfraction lesion with composite resin; Model 10 was restored tooth on abfraction lesion with composite resin and metal ceramic crown restoration which margin is positioned on lower border of abfraction lesion. Load A and Load B was also designed. Von Mises value was evaluated on each point. Results: Under load A or load B, on tooth with abfraction lesion, stress was concentrated on the apex of lesion. Under load A or load B, on tooth that abfraction lesion was restored with composite resin, the stress value was reduced on the apex. Conclusion: In case of abfraction lesion was restored with composite resin, the stress was concentrated on the apical border of restored cavity regardless of marginal position. It was favorable to place crown margin on the enamel for restoring with metal ceramic crown.

Sintering and Characterization of SiC-matrix Composite Including TRISO Particles (TRISO 입자를 포함하는 SiC 복합소결체의 소결 및 특성 평가)

  • Lee, Hyeon-Geun;Kim, Daejong;Park, Ji Yeon;Kim, Weon-Ju
    • Journal of the Korean Ceramic Society
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    • v.51 no.5
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    • pp.418-423
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    • 2014
  • Fully ceramic micro encapsulated (FCM) nuclear fuel is a concept recently proposed for enhancing the stability of nuclear fuel. FCM nuclear fuel consists of tristructural-isotropic (TRISO) fuel particles within a SiC matrix. Each TRISO fuel particle is composed of a $UO_2$ kernel and a PyC/SiC/PyC tri-layer which protects the kernel. The SiC ceramic matrix is created by sintering. In this FCM fuel concept, fission products are protected twice, by the TRISO coating layer and by the SiC ceramic. The SiC ceramic has proven attractive for fuel applications owing to its low neutron-absorption cross-section, excellent irradiation resistivity, and high thermal conductivity. In this study, a SiC-matrix composite containing TRISO particles was sintered by hot pressing with $Al_2O_3-Y_2O_3$ additive system. Various sintering conditions were investigated to obtain a relative density greater than 95%. The internal distribution of TRISO particles within the SiC-matrix composite was observed using an x-ray radiograph. The fracture of the TRISO particles was investigated by means of analysis of the cross-section of the SiC-matrix composite.

UV-cured Polymer Solid Electrolyte Reinforced using a Ceramic-Polymer Composite Layer for Stable Solid-State Li Metal Batteries

  • Hye Min Choi;Su Jin Jun;Jinhong Lee;Myung-Hyun Ryu;Hyeyoung Shin;Kyu-Nam Jung
    • Journal of Electrochemical Science and Technology
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    • v.14 no.1
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    • pp.85-95
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    • 2023
  • In recent years, solid-state Li metal batteries (SSLBs) have attracted significant attention as the next-generation batteries with high energy and power densities. However, uncontrolled dendrite growth and the resulting pulverization of Li during repeated plating/stripping processes must be addressed for practical applications. Herein, we report a plastic-crystal-based polymer/ceramic composite solid electrolyte (PCCE) to resolve these issues. To fabricate the one-side ceramic-incorporated PCCE (CI-PCCE) film, a mixed precursor solution comprising plastic-crystal-based polymer (succinonitrile, SN) with garnet-structured ceramic (Li7La3Zr2O12, LLZO) particles was infused into a thin cellulose membrane, which was used as a mechanical framework, and subsequently solidified by using UV-irradiation. The CI-PCCE exhibited good flexibility and a high room-temperature ionic conductivity of over 10-3 S cm-1. The Li symmetric cell assembled with CI-PCCE provided enhanced durability against Li dendrite penetration through the solid electrolyte (SE) layer than those with LLZO-free PCCEs and exhibited long-term cycling stability (over 200 h) for Li plating/stripping. The enhanced Li+ transference number and lower interfacial resistance of CI-PCCE indicate that the ceramic-polymer composite layer in contact with the Li anode enabled the uniform distribution of Li+ flux at the interface between the Li metal and CI-PCCE, thereby promoting uniform Li plating/stripping. Consequently, the Li//LiFePO4 (LFP) full cell constructed with CI-PCCE demonstrated superior rate capability (~120 mAh g-1 at 2 C) and stable cycle performance (80% after 100 cycles) than those with ceramic-free PCCE.

Comparison of the Viscosity of Ceramic Slurries using a Rotational Rheometer and a Vibrational Viscometer (회전형 레오미터와 진동형 점도계를 이용한 세라믹 슬러리의 점도 비교)

  • Ji, Hye;Lim, Hyung Mi;Chang, Young-Wook;Lee, Heesoo
    • Journal of the Korean Ceramic Society
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    • v.49 no.6
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    • pp.542-548
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    • 2012
  • The viscosity of a ceramic slurry depends on the slurry concentration, particle shape and size, hydrodynamic interactions, temperature, shear rate, pre-treatment condition and the method of measurement with the selected equipment. Representative ceramic slurries with low to high viscosity levels are selected from colloidal silica, barium titanate slurry and glass frit paste. Rotational rheometers and vibrational viscometers are used to compare the measured viscosity for various ceramic slurries. The rotational rheometer measured the viscosity according to the change of the shear rate or the rotational speed. On the other hand, the vibrational viscometer measured one point of the viscosity in a fixed vibrational mode. The rotational rheometer allows the measurement of the viscosity of a ceramic paste with a viscosity higher than 100,000 cP, while the vibrational viscometer provides an easy and quick method to measure the viscosity without deformation of the ceramic slurry due to the measurement method. It is necessary to select suitable equipment with which to measure the viscosity depending on the purpose of the measurement.

Blast resistance of a ceramic-metal armour subjected to air explosion: A parametric study

  • Rezaei, Mohammad Javad;Gerdooei, Mahdi;Nosrati, Hasan Ghaforian
    • Structural Engineering and Mechanics
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    • v.74 no.6
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    • pp.737-745
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    • 2020
  • Nowadays, composite plates are widely used as high-strength structures to fabricate a dynamic loading-resistant armours. In this study, the shock load is applied by an explosion of spherical TNT charge at a specified distance from the circular composite plate. The composite plate contains a two-layer ceramic-metal armour and a poly-methyl methacrylate (PMMA) target layer. The dynamic behavior of the composite armour has been investigated by measuring the transferred effective stress and maximum deflection into the target layer. For this purpose, the simulation of the blast loading upon the composite structure was performed by using the load-blast enhanced (LBE) procedure in Ls-Dyna software. The effect of main process parameters such as the thickness of layers, and scaled distance has been examined on the specific stiffness of the structure using response surface method. After validating the results by comparing with the experimental results, the optimal values for these parameters along with the regression equations for transferred effective stress and displacement to the target have been obtained. Finally, the optimal values of input parameters have been specified to achieve minimum transferred stress and displacement, simultaneously with reducing the weight of the structure.