• Analytical Science and Technology
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• v.26 no.1
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• pp.27-33
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• 2013

Polyalkylsilanes such as poly(dialkyl)silanes and poly(monoalkyl)silanes were synthesized by sonochemical dechlorination-condensation method from (dialkyl or monoalkyl)chlorosilanes with sodium metal. Those polyalkylsilanes were analyzed for the properties such as thermal behaviors from TGA analysis and obtained ceramic yields of 10-20% for poly(dialkyl)silanes and 40-60% for poly(monoalkyl)silanes. Ceramic composite discs were prepared by the combined mixture of polyalkylsilanes and SiC powder and were tested by TGA and analyzed by SEM and XRD for the application as binder for ceramic composite precursors.

• Journal of the Korean Ceramic Society
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• v.27 no.4
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• pp.457-464
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• 1990

This paper presents the influence of the loading rate on the room temperature fracture toughness of a brittle Al2O3 and a SiC whisker reinforced Al2O3 composite. Dynamic fracture toughness tests were conduced using compressive fatigue pre-cracked notched round bars loaded in tension to produce a stress intensity rate K1=106 MPa√m/sec. The experimental results show that for each loading rate the fracture toughness values obtained for the ceramic matrix composite are higher than the corresponding values for the single phase alumina. In addition, both the reinforced and unreinforced ceramic are singnificantly tougher under dynamic loading than static loading. This dynamic and quasi-static fracture initiation behaviro can be interpreted by identifying quantitatively the mode of fractuer initiation as a function of loading rate.

• Korean Journal of Materials Research
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• v.34 no.3
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• pp.175-183
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• 2024

Geopolymer, also known as alkali aluminum silicate, is used as a substitute for Portland cement, and it is also used as a binder because of its good adhesive properties and heat resistance. Since Davidovits developed Geopolymer matrix composites (GMCs) based on the binder properties of geopolymer, they have been utilized as flame exhaust ducts and aircraft fire protection materials. Geopolymer structures are formed through hydrolysis and dehydration reactions, and their physical properties can be influenced by reaction conditions such as concentration, reaction time, and temperature. The aim of this study is to examine the effects of silica size and aging time on the mechanical properties of composites. Commercial water glass and kaolin were used to synthesize geopolymers, and two types of silica powder were added to increase the silicon content. Using carbon fiber mats, a fiber-reinforced composite material was fabricated using the hand lay-up method. Spectroscopy was used to confirm polymerization, aging effects, and heat treatment, and composite materials were used to measure flexural strength. As a result, it was confirmed that the longer time aging and use of nano-sized silica particles were helpful in improving the mechanical properties of the geopolymer matrix composite.

• Transactions on Electrical and Electronic Materials
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• v.16 no.6
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• pp.351-354
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• 2015

In this study, alumina plates 9~25 μm in size were used as thermal fillers, and epoxy resin was used as a polymer matrix. Oriented alumina plate/epoxy composites were prepared using a rolling method. The effect of ordering alumina plates increased with alumina plate size. The thermal conductivity and flexural strength of the composites were investigated. The horizontal thermal conductivity of the oriented composite was significantly higher than the vertical thermal conductivity. The horizontal thermal conductivity of the 75 wt% alumina content was 8.78 W/mk, although the vertical thermal conductivity was 1.04 W/mk. Ordering of the alumina plate using a rolling method significantly improved the thermal conductivity in the horizontal direction. The flexural strengths of the ordered alumina/epoxy composites prepared at different curing temperatures were measured.

• Journal of the Korean Ceramic Society
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• v.53 no.6
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• pp.707-711
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• 2016

A small diameter of SiC fiber mat can produce much higher heat under microwave irradiation than the other types of SiC materials. Fabrication of high strength SiC fiber consists of iodine vapor curing on polycarbosilane precursor and heat treatment process. The curing stage of polycarbosilane fiber was maintained at $150-200^{\circ}C$ in a vacuum condition under the iodine vapor to fabricate a high thermal radiation SiC fiber. The structure and morphology of the fibers were characterized by Fourier transform infrared (FTIR) spectroscopy, thermogravimetric analysis (TG) and scanning electron microscopy (SEM). In this study, the thermal properties of SiC fiber mats under microwave have been analyzed with an IR thermal camera and its image analyzer. The prepared SiC fiber mats radiated high temperature with extremely high heating rate up to $1100^{\circ}C$ in 30 seconds. The fabricated SiC fiber mats were not oxidized after the heat radiation process under the microwave irradiation.

• Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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• 2006.06a
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• pp.331-332
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• 2006

Ag-ceramic composite materials were investigated as internal electrodes for multilayer ceramic actuators (MLCA). Ag-ceramic pastes were prepared by adding PZT-based ceramic powders to a Ag patse in a range of 0 to 50 wt.%. PZT/Ag-PZT multilayered laminates were fabricated by tape casting and fired at low temperatures below $950^{\circ}C$. The addition of ceramic into the Ag electrode resulted in a decrease in the thermal expansion mismatch between the electrode and the ceramic sheet. The maximum strain of PZT/Ag-PZT multilayered actuators were $9{\times}10^{-4}$ under an electric field of 2.5MV/m. In conclusion, Ag-PZT composite materials are efficient for low cost piezoelectric MLCAs.

• Journal of the Korean Ceramic Society
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• v.52 no.4
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• pp.273-278
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• 2015

${\alpha}-Al_2O_3$ was synthesized by solvothermal synthesis using ${\alpha}-Al_2O_3$ seed, precursor of fine boehmite (Al(OOH)) or gibbsite ($Al(OH)_3$), and 1, 4-butanediol solvent. The seed content and precursor type were selected as variables in order to synthesize ${\alpha}-Al_2O_3$. The formation time of ${\alpha}-Al_2O_3$ was reduced and the size of the particles was decreased with addition of the seed. When the seed content was increased, the size of the synthesized ${\alpha}-Al_2O_3$ was reduced. Morphologies of the as-synthesized ${\alpha}-Al_2O_3$ with ${\alpha}-Al_2O_3$ seed were polyhedron-shaped, while the shape was plate-like or polyhedral without the seed, depending on the additives or the average particle size of the boehmite precursor. The aggregation of as-synthesized ${\alpha}-Al_2O_3$ from boehmite was smaller than that from gibbsite. As-synthesized ${\alpha}-Al_2O_3$, with 140 nm size, was obtained by using the seed and boehmite precursor.

• Journal of the Korean Ceramic Society
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• v.53 no.4
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• pp.386-392
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• 2016

Heat insulation plates of fumed silica were prepared by mixing fumed silica, SiC powder and chopped glass fiber by a high speed mixer followed by pressing of the mixture powder in a stainless steel mold of $100{\times}100mm$. Composition of the plates, particle size of SiC, and type of inorganic binder were varied for observation of their contribution to heat insulation of the plate. The plate was installed on the upper portion of an electric furnace the inside temperature of which was maintained at $400^{\circ}C$ and $600^{\circ}C$, for investigation of heat transfer through the plate from inside of the electric furnace to outside atmosphere. Surface temperatures were measured in real time using a thermographic camera. The particle size of SiC was varied in the range of $1.3{\sim}17.5{\mu}m$ and the insulation was found to be most excellent when SiC of $2.2{\mu}m$ was incorporated. When the size of SiC was smaller or larger than $2.2{\mu}m$, the heat insulation effect was decreased. Inorganic binders of alkali silicate and phosphate were tested and the phosphate was found to maintain the heat insulation property while increasing mechanical properties.

• Journal of the Korean Crystal Growth and Crystal Technology
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• v.29 no.2
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• pp.54-60
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• 2019

Recently, various composite materials for additive manufacturing are interested to expand the application field of 3D printing. 3D printing technique was mainly developed using polymer, and ceramic materials for 3D printing are still in the early stage of research due to the requirement of high solid content and post treatment process. In this study, silica particles with various diameters were surface treated with silane coupling agent, and synthesized as silica composite with photopolymer to apply DLP 3D printing process. DLP is an additive manufacturing technology, which has high accuracy and applicability of various composite materials. The rheological behavior of silica composite was analyzed with various solid contents. After DLP 3D printing was performed using silica composites, the printing accuracy of the 3D printed specimen was less than about 3 % to compare with digital data and he bending strength was 34.3 MPa at the solid content of 80 wt%.

• Journal of the Korean Ceramic Society
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• v.40 no.8
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• pp.784-790
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• 2003

Present investigation shows the analysis results for ceramic reinforced metal matrix composite under uniaxial transverse tensile loading. The resulting deformation, the projected damage type, and stress-strain behavior were computed depending on microstructure details such as the type of periodic reinforcement array, and the type of interface bonding. A two-dimensional finite element analysis was conducted based on the unit-cell of square, hexagonal, or diagonal periodic away For composite with strong interface bonding, the transverse stress vs. strain curve was generally increased with the increase of the ceramic volume fraction. For the composite with weakly bonded interface, however, the transverse stress vs. strain curve was reduced against the ceramic volume fraction. The decrease was caused by the interface debonding-induced stiffness reduction of the composite. For the composite of weakly bonded interface, the relative reduction rate in the final limit stress for hexagonal array was larger than that for square array. Outcome of the present study was compared favorably with the published literature data.