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A Study on the Corrosion Inhibition Effects of Sodium Heptanoate for Carbon Steel in Aqueous Solution

  • Won, D.S.;Kho, Y.T.
    • Corrosion Science and Technology
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    • v.3 no.6
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    • pp.227-232
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    • 2004
  • The carboxylates as a corrosion inhibitor has been studied by many researchers because of its environmental safety and low depletion rate. However, conventional test methods of inhibitor such as weight loss measurements, linear polarization resistance and corrosion potential monitoring etc., evaluate uniform corrosion of metals. These methods are unable to evaluate crevice-related corrosions, which are encountered in most of heat exchanging facilities. In order to choose the optimum corrosion inhibitor, the appropriate test methods are required to evaluate their performances in service environment. From this point of view, polarization technique was used to evaluate the characteristics of sodium heptanoate on corrosion behavior for carbon steel. Especially a thin film crevice sensor technique were applied to simulate the crevice corrosion in this study. From these experiments, we found that oxygen as an oxidizing agent was required to obtain stable passive film on the metal. Presence of oxygen, however, accelerated crevice corrosion. Potential shift by oxygen depletion and weakened inhibitive film inside the crevice were responsible for such accelerated feature. It is shown that film for corrosion inhibition is a mixture of sodium heptanoate and iron (II) heptanoate as reaction product of iron surface and sodium heptanoate. The iron (II) heptanoate which has been synthesized by reaction of heptanoic acid and ferrous chloride in methanol solution forms bidentate complex.

Study on Corrosion of Automotive Coil Spring Steel by Electrochemical Impedance Spectroscopy (전기화학 임피던스 분석을 통한 자동차용 코일스프링 강의 부식 평가)

  • Lee, Kyu Hyuk;Park, Jung-Hyun;Ahn, Seung Ho;Seo, Ji Won;Jang, HeeJin
    • Corrosion Science and Technology
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    • v.16 no.6
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    • pp.298-304
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    • 2017
  • Coil spring steels from the automobile suspension part after field exposure for 10 years and those after anti-corrosion validation test in proving ground of 5,000 ~ 10,000 km were examined for corrosion damages. Partial loss of paint, accumulation of corrosion product, and cracking of paint and superficial material were observed. The surface and subsurface region of spring steels had compressive residual stress and high hardness by shot peening. The surface hardness values of the specimens were 620 ~ 670 Hv. They were 60 ~ 80 Hv higher than those of the samples taken from the middle part of the spring. The maximum compressive stress was -916 ~ -1208 MPa measured at depth of about $100{\mu}m$. Electrochemical impedance spectroscopy showed that the resistances of charge transfer and the paint layer of the spring steels ranged from several tens to millions ${\Omega}{\cdot}cm^2$. The resistance of the field samples was much higher than that of the proving ground samples used in this study, implying that the proving ground test condition would be more corrosive than the field environment.

Hydrodynamic characteristics for flow around wavy wings with different wave lengths

  • Kim, Mi Jeong;Yoon, Hyun Sik;Jung, Jae Hwan;Chun, Ho Hwan;Park, Dong Woo
    • International Journal of Naval Architecture and Ocean Engineering
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    • v.4 no.4
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    • pp.447-459
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    • 2012
  • The present study numerically investigates the effect of the wavy leading edge on hydrodynamic characteristics for the flow of rectangular wings with the low aspect ratio of 1.5. Five different wave lengths at fixed wavy amplitude have been considered. Numerical simulations are performed at a wide range of the angle of attack ($0^{\circ}{\leq}{\alpha}{\leq}40^{\circ}$) at one Reynolds number of $10^6$. The wavy wings considered in this study did not experience enough lift drop to be defined as the stall, comparing with the smooth wing. However, in the pre-stall region, the wavy wings reveal the considerable loss of the lift, compared to the smooth wing. In the post-stall, the lift coefficients of the smooth wing and the wavy wings are not much different. The pressure coefficient, limiting streamlines and the iso-surface of the spanwise vorticity are also highlighted to examine the effect of the wave length on the flow structures.

Preparation and Electromagnetic Properties of an Electromagnetic Wave Absorber

  • Sun, Chang;Sun, Kangning;Pang, Laixue;Liu, Jian
    • Journal of Magnetics
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    • v.21 no.1
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    • pp.61-64
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    • 2016
  • In this study, we report the as-prepared MgO-doped $BaFe_{12}O_{19}$, which was prepared by calcination technique and high-energy ball milling process, as an electromagnetic wave absorber. The phase analysis of $BaFe_{12}O_{19}$ and the as-prepared MgO-doped $BaFe_{12}O_{19}$ was detected utilizing X-ray Diffractometer (XRD). The microstructure was characterized using Scanning Electron Microscope (SEM). By means of the transmission/reflection coaxial line method, the electromagnetic properties and microwave absorbing properties of the as-prepared electromagnetic wave absorber were studied. It is found that the electromagnetic wave absorber has a minimum reflection loss value of -41 dB at 4.27 GHz with a matching thickness of 2.6 mm. The experiment results revealed that the as-prepared electromagnetic wave absorber could find potential applications in many military as well as commercial industries.

The Study of Job Stress in Occupational Therapist (작업치료사의 직무 스트레스에 관한 연구)

  • Yang, Young-Ae;Hur, Jin-Gang;Noh, Young-Man;Lee, Gyu-Chang
    • Journal of the Ergonomics Society of Korea
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    • v.26 no.3
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    • pp.1-9
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    • 2007
  • The purpose of this study was going to research relation of job stress and society psychologic stress according to general characteristic, work characteristic, health characteristic and personality characteristic for the occupational therapist in the working domestic rehabilitation therapy with hospital and welfare center occupational therapist. The research was 91 of withdrawal questionnaire among 102 occupational therapist from 1. November 2005 to 31. December 2005. In the result of analysis the given question for the ninety one occupational therapist showed just normal group 25% 23 person, potential stress group 47% 43 person, and the rest 28% 25 person high risk group. The result shows significance different in general characteristic of job stress about age, final scholarship and marriage. Job stress was included income, working time, office form and working position etc. Health special job stress was significance different according to sleep time. So we have to know a fact of job stress of occupational therapist and prevent of loss of business services. And we have to endeavoring removals factor of stress and good office culture fixation.

Totally Laparoscopic Total Gastrectomy Using Intracorporeally Hand-Sewn Esophagojejunostomy

  • So, Kwang-Oh;Park, Jong-Min
    • Journal of Gastric Cancer
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    • v.11 no.4
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    • pp.206-211
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    • 2011
  • Purpose: Laparoscopic total gastrectomy (LTG) for gastric cancer is still uncommon because of technical difficulties, especially in esophagojejunostomy (EJ). There are many reports for various laparoscopic procedures of EJ using linear or circular staplers. On the other hands, there has been no report for hand-sewn anastomosis. We report successfully performed intracorporeally hand-sewn EJ after LTG. Materials and Methods: The clinicopathologic data and short-term surgical outcomes of 6 patients who underwent totally laparoscopic total gastrectomy for upper gastric cancer from December 2010 and July 2011 were retrospectively reviewed. Results: The mean age was 66.5 years and mean body mass index (kg/$m^2$) was 24.6. All patients had medical comorbidities. The mean patient ASA score was 2.17. Among the 6 patients, previous abdominal operation was performed for 2 patients and combined operation was performed for 3 patients. The mean blood loss, operation time, and EJ anastomosis time was 130 ml, 379.7 minutes, and 81.5 minutes, respectively. The mean time to first flatus, first oral intake, and postoperative hospital stay was 3.0, 3.0, and 12.5 days, respectively. There was no 30-day mortality case. Postoperative aspiration pneumonia and multiple periventricular lacunar infarctions developed in 1 patient. There were no anastomosis-related complications and other major surgical complications. Conclusions: When the intracorporeal anastomotic technique becomes popular in LTG the intracorporeally hand-sewn EJ may be accepted as one method among the various laparoscopic procedures of EJ.

The Architectural Analysis of the Buddy System for Qualitative Risk Analysis (정성적 위험 분석을 위한 버디 시스템의 구조 분석)

  • Jeongwon Yoon;Kim, Hong-Keun
    • Proceedings of the Korea Institutes of Information Security and Cryptology Conference
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    • 1995.11a
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    • pp.51-58
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    • 1995
  • The importance of the risk analysis tool has been recognized and its use also has been emphasized by a number of researchers recently The methodology were examined but neither algorithms nor practical applications have been implemented or practiced in Korea. In this paper, the architecture of the Buddy System, one of the automated risk assessment tools. is analyzed in depth to provide the algorithmic understanding and to promote the development of the risk analysis methodology. The Buddy System mainly uses three main factors of vulnerability, threat and countermeasures as a nucleus of the qualatative analysis with the modified loss expectancy value. These factors are identified and assessed by the separation of duties between the end user and security analyst. The Buddy System uses five axioms as its bases of assessment algorithm and the assessed vulnerability level is strictly within these axioms. Since the In-place countermeasures reduce the vulnerability level up to a certain level. the security analyst may use "what if " model to examine the impact of additional countermeasures by proposing each to reduce the vulnerability level further to within the acceptable range. The emphasis on the qualitative approach on vulnerability leveling is very well balanced with the quantitative analysis that the system performance is prominent.prominent.

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Implementation Technique of Real-time Monitoring System for High-Speed Rail Contact Wire with High Tension (고속철도 전차선로 고장력 실시간 모니터링 기술 구현)

  • Cho, Yong Hyeon;Park, Young;Jung, Hyun Jin
    • The Transactions of The Korean Institute of Electrical Engineers
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    • v.64 no.8
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    • pp.1256-1261
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    • 2015
  • Along with the increase of railway catenary system operation speed to 400 km/h, there have been growing demands for good quality current collection systems that satisfy quality standards as well as criteria for safe working. Retaining uniform elasticity tension of contact wires is essential in maintaining high quality contact between pantograph and OCL (Overhead Contact Line) of current collection systems in high speed railways. Therefore, the tension of contact wire must be kept within tight tolerance limits in both working conditions and adverse weather conditions of catenary system. In accordance with these conditions, this paper presents a real time monitoring system for the tensioning device of the newly installed catenary system on the special route of Honam high speed line for 400 km/h operation. For the verification of the true value of tension of contact wires, we have developed ring-type tensioning sensors which were installed on supporting points of mast which compose the catenary system. According to the field test performed on the Honam high speed line catenary system, variation of tension was measured accurately in real-time.

The Effects of the Tempered Materials on the Thermal Runaway Characteristics in the Resol Resin Synthesis Reaction (레졸수지 합성반응에서 온도조절 물질이 열폭주 특성에 미치는 영향)

  • Lee, Jung-Suk;Lee, Keun-Won
    • Journal of the Korean Institute of Gas
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    • v.18 no.4
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    • pp.27-34
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    • 2014
  • In this study, we evaluated an effect of the tempered materials on the thermal runaway characteristics in the resol resin synthesis reaction using the adiabatic calorimetry of vent sizing package 2(VSP2). The kinetic parameters, such as an activation energy and heat of reaction, were estimated using the test results. As the results, the instantaneous characteristics to express the intensity of runaway reaction decreased at the low solid content. However, the sudden loss of the tempered materials triggered the second runaway reaction rapidly. In this condition, the heat of reaction and the activation energy of phenol and p-formaldehyde were about 157 kJ/mol and 60 kJ/mol, respectively.

Design of Optimal Resonant Frequency for Series-Loaded Resonant DC-DC Converter in EVs On-Board Battery Charger Application (전기자동차 탑재형 충전기용 부하직렬공진형 컨버터의 최적 공진주파수 설계)

  • Oh, Chang-Yeol;Kim, Jong-Soo;Lee, Byoung-Kuk
    • The Transactions of the Korean Institute of Power Electronics
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    • v.17 no.1
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    • pp.77-84
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    • 2012
  • This paper describes the process of optimal resonant frequency design with full-bridge series-loaded resonant dc-dc converter in a high efficiency 3.3 kW on-board battery charger application for Electric Vehicles and Plug-in Hybrid Electric Vehicles. The optimal range of resonant frequency and switching frequency used for ZVS are determined by considering trade-off between loss of switching devices and resonant network with size of passive/magnetic devices. In addition, it is defined charging region of battery, the load of on-board charger, as the area of load by deliberating the characteristic of resonant. It is verified the designed frequency band by reflecting the defined area on resonant frequency.