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Synthesis of Mesostructured Conducting Polymer-Carbon Nanocomposites and Their Electrochemical Performance

  • Choi, Moon-Jung;Lim, Byung-Kwon;Jang, Jyong-Sik
    • Macromolecular Research
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    • v.16 no.3
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    • pp.200-203
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    • 2008
  • A conducting polymer layer was introduced into the pore surface of mesoporous carbon via vapor infiltration of a monomer and subsequent chemical oxidative polymerization. The polypyrrole, conducting polymer has attracted considerable attention due to the high electrical conductivity and stability under ambient conditions. The mesoporous carbon-polypyrrole nanocomposite exhibited the retained porous structure, such as mesoporous carbon with a three-dimensionally connected pore system after intercalation of the polypyrrole layer. In addition, the controllable addition of pyrrole monomer can provide the mesoporous carbon-polypyrrole nanocomposites with a tunable amount of polypyrrole and texture property. The polypyrrole layer improved the electrode performance in the electrochemical double layer capacitor. This improved electrochemical performance was attributed to the high surface area, open pore system with three-dimensionally interconnected mesopores, and reversible redox behavior of the conducting polypyrrole. Furthermore, the correlation between the amount of polypyrrole and capacitance was investigated to check the effect of the polypyrrole layer on the electrochemical performance.

Numerical Analysis of Axial-Flow Cyclone Separator for Subway Station HVAC System Pre-Filter

  • Kim, Myung-Joon;Kim, Ho-Joong;Kwon, Soon-Bark;Kim, Se-Young;Kim, Jin-Kwan;Shin, Chang-Hun;Bae, Sung-Joon;Hwang, Sun-Ho;Kim, Tae-Sung
    • International Journal of Air-Conditioning and Refrigeration
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    • v.17 no.3
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    • pp.94-99
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    • 2009
  • In the Korean subway station, three types of pre-filters, which include auto filter, electrostatic precipitator (ESP) and auto cleaning demister, are widely used. However, these devices have some problems such as the difficulty of maintenance and high operating cost. In this study, axial-flow cyclone separator was employed as a pre-filter inside a heating, ventilation, and air conditioning (HVAC) system. 3-dimensional computational fluid dynamics (CFD) analysis was performed on a single unit axial-flow cyclone and coupled unit axial-flow cyclone. Calculated and measured pressure drop of the designed axial-flow cyclone were found be comparable to other types of pre-filters and the observed cut-off diameter was less than 10 micron. Considering lower operating and maintenance cost, axial-flow cyclone was proved to be a better solution as a pre-filter.

Effect of Asymmetric Hot Rolling on the Texture Evolution of Fe-3%Si Steel

  • Na, Tae-Wook;Park, Hyung-Ki;Park, Chang-Soo;Joo, Hyung-Don;Park, Jong-Tae;Han, Heung Nam;Hwang, Nong-Moon
    • Metals and materials international
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    • v.24 no.6
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    • pp.1369-1375
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    • 2018
  • In Fe-3%Si steel, the hot rolling process affects not only the hot rolling texture but also the primary recrystallization texture. Here, the effect of asymmetric hot rolling was studied by comparing the difference in the texture evolved between asymmetric and symmetric hot rolling. The effect of asymmetric hot rolling on the texture of primary recrystallized Fe-3%Si steel was also studied. The symmetric hot rolling of Fe-3%Si steel produces a rotated cube texture at the center but Goss and copper textures near the surface. Asymmetric hot rolling tends to produce Goss and copper textures even at the center like the texture near the surface. After primary recrystallization, the dominant texture at the center changes from {001} <210> to {111} <112> and the new texture has a higher fraction of the grains which make the low energy boundary with Goss grains than that of symmetric hot rolling.

Analysis of Cavity Pressure and Dimension of Molded Part According to V/P Switchover Position in Injection Molding

  • Cho, Jung Hwan;Kwon, Soon Yong;Roh, Hyung Jin;Cho, Sung Hwan;Kim, Su Yeon;Lyu, Min-Young
    • Elastomers and Composites
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    • v.52 no.4
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    • pp.309-316
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    • 2017
  • In injection molding, the quality of an injection molded product varies greatly depending on the molding conditions. Many researche studies have been conducted on the quality analysis of molded parts according to the molding conditions such as injection pressure, injection temperature, and packing pressure. However, there have not been many studies on the V/P switchover timing. It is known that when a large pressure is applied to a cavity in the packing phase, the cavity pressure is most affected by the packing pressure. In addition, depending on the position (timing) of the packing pressure, it can have a direct influence on quality based on the shrinkage and dimensions of the molded parts. In this study, the change in pressure profile in the cavity according to the V/P switchover position is confirmed. A CAE analysis program (Moldflow) was used to simulate and analyze two models using the PC and PBT materials. In order to compare these results with the actual injection molding results, injection molding was performed for each V/P switchover position, and the correlation between simulation and experiment, especially for the shrinkage of molded parts, was evaluated.

The Characteristics and Outcomes of Abernethy Syndrome in Korean Children: A Single Center Study

  • Kim, Eun Sil;Lee, Ki Wuk;Choe, Yon Ho
    • Pediatric Gastroenterology, Hepatology & Nutrition
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    • v.22 no.1
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    • pp.80-85
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    • 2019
  • Purpose: Abernethy malformation is a rare condition, which was first described in 1793 as a congenital extrahepatic porto-systemic shunt (CEPS) directing splanchnic blood flow into the inferior vena cava. Eighty cases have been published so far that reported CEPS, while in Korea, very few cases have been reported. Through this study, we present 6 cases of patients diagnosed with CEPS at Samsung Medical Center and compare these with other such cases published in France and China. Methods: We reviewed clinical, laboratory, and imaging data of 6 children with CEPS in our pediatric clinic between 2004 and 2017. Results: A total of 6 children with CEPS was included in this study, namely, one with type 1a, two with type 1b, and three with type 2 CEPS. The most common presenting symptom was gastrointestinal bleeding (50.0%). Therapeutic interventions included shunting vessel ligation (16.7%) in type 2 CEPS and liver transplantation (16.7%) in type 2 CEPS patient with suddenly developed hepatic encephalopathy. Conclusion: There is no consensus guideline for the optimal management of patients with CEPS. Large-sample studies regarding CEPS are needed to evaluate the characteristics of patients with CEPS and determine the treatment guideline for CEPS.

Transdermal Delivery of Quercetin Using Elastic Liposomes: Preparation, Characterization and In Vitro Skin Permeation Study (탄성 리포좀을 사용한 쿼세틴의 경피 전달: 제조, 특성 그리고 In Vitro 피부 투과 연구)

  • Park, Soo Nam;Lim, Myoung Sun;Park, Min A;Kwon, Soon Sik;Han, Seat Byeol
    • Polymer(Korea)
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    • v.36 no.6
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    • pp.705-711
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    • 2012
  • In this study, the elastic liposome consisted of egg phospholipids and edge activator ($Tego^{(R)}$ care 450) was prepared in order to supplement the defect of the conventional liposome. We prepared elastic liposome containing quercetin, known as natural antioxidant, and evaluated the vesicles size, elasticity, loading efficiency, stability, and in vitro skin permeation. The mean diameter of quercetin loaded elastic liposome formulations ranged between 208.2~303.4 nm and loading efficiency was observed 64.1~87.5%. The highest loading efficiency (87.5%) and deformability (28.3) were observed at the optimal ratio of 90 : 10 (egg phospholipids : $Tego^{(R)}$ care 450) among 0.1% quercetin loaded elastic liposome formulations. The elastic liposome formulation was selected for further transdermal permeation study. The elastic liposome ($129.9{\mu}g/cm^2$) exhibited more skin permeability than general liposome ($114.8{\mu}g/cm^2$) and 1,3-butylene glycol ($75.1{\mu}g/cm^2$) solution. This results suggest that the elastic liposome formulation using $Tego^{(R)}$ care 450 as a major edge activator could be useful for the delivery of active ingredient through the skin transdermal.

Printable Time Temperature Integrator Consisting of Oxygen Indicator and Cover Film with Various Oxygen Permeability (다양한 산소 투과도를 가진 커버필름과 산소지시물질로 제작된 인쇄형 TTI)

  • Kim, Do Hyeon;Jang, Han Dong;Han, Seo Hyeon;Ahn, Myung Hyun;Lee, Seung Ju
    • KOREAN JOURNAL OF PACKAGING SCIENCE & TECHNOLOGY
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    • v.24 no.2
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    • pp.41-48
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    • 2018
  • A printable time temperature integrator (TTI) consisting of oxygen indicator and cover films with various oxygen permeability was developed. The printing ink contained methylene blue (oxygen indicator) which changed in color during storage. $TiO_2$ and glycerol for UV-activation of TTI and zein and ethanol for printing performance were also contained in the printing ink. The cover film on the ink was employed to control the color change rate and temperature dependency (Arrhenius activation energy, $E_a$) by using the different films (PE, PET, OPP, and LLDPE). The film properties were varied by annealing. TTI was produced by silk screen printing. As a result, the color change rates were different for the cover films, being the highest in TTI with LLDPE, followed by OPP, PE, and PET. The rate decreased with increase in the cover film thickness. The $E_a$ was the highest in TTI with LLDPE, followed by OPP, PE, and PET. The $E_a$ did not change with the cover film thickness. The annealed PVC and PET film were lower in oxygen permeability than the unannealed ones, indicating the lower color change rate.

The Effects of TWEAK, Fn14, and TGF-$\beta1$ on Degeneration of Human Intervertebral Disc

  • Huh, Hoon;Lee, Yong-Jik;Kim, Jung-Hee;Kong, Min-Ho;Song, Kwan-Young;Choi, Gun
    • Journal of Korean Neurosurgical Society
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    • v.47 no.1
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    • pp.30-35
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    • 2010
  • Objective: The purpose of this study is to explain the effect and reciprocal action among tumor necrosis factor (TNF) like weak inducer of apoptosis (TWEAK), fibroblast growth factor-inducible 14 (Fn14), and transforming growth factor-$\beta1$ (TGF-$\beta1$) on degeneration of human intervertebral disc (IVD). Methods: Human intervertebral disc tissues and cells were cultured with Dulbecco's Modified Eagle's Medium/Nutrient F-12 Ham (DMEM/F-12) media in $37^{\circ}C$, 5% $CO_2$ incubator. When IVD tissues were cultured with TWEAK, Fn14 that is an antagonistic receptor for TWEAK and TGF-$\beta1$, the level of sulfated glycosaminoglycan (sGAG) was estimated by dimethyl methyleneblue (DMMB) assay and sex determining region Y (SRY)-box 9 (Sox9) and versican messenger ribonucleic acid (mRNA) levels were estimated by reverse transcriptase polymerase chain reaction (RT-PCR). Results: When human IVD tissue was cultured for nine days, the sGAG content was elevated in proportion to culture duration. The sGAG was decreased significantly by TWEAK 100 ng/mL, however, Fn14 500 ng/mL did not change the sGAG production of IVD tissue. The Fn14 increased versican and Sox9 mRNA levels decreased with TWEAK in IVD tissue TGF-$\beta1$ 20 ng/mL elevated the sGAG concentration 40% more than control. The sGAG amount decreased with TWEAK was increased with Fn14 or TGF-$\beta1$ but the result was insignificant statistically. TGF-$\beta1$ increased the Sox9 mRNA expression to 180% compared to control group in IVD tissue. Sox9 and versican mRNA levels decreased by TWEAK were increased with TGF-$\beta1$ in primary cultured IVD cells, however, Fn14 did not show increasing effect on Sox9 and versican. Conclusion: This study suggests that TWEAK would act a role in intervertebral disc degeneration through decreasing sGAG and the mRNA level of versican and Sox9.

Minimizing total cost in proportionate flow shop with controllable processing times by polynomially solvable 0-1 unconstrained Quadratic Program

  • Choi, Byung-Cheon;Hong, Sung-Pil;Lee, Seung-Han
    • Proceedings of the Korean Operations and Management Science Society Conference
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    • 2007.11a
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    • pp.309-312
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    • 2007
  • We consider a proportionate flow shop problem with controllable processing times. The objective is to minimize the sum of total completion time and total compression cost, in which the cost function of compressing the processing times is non-decreasing concave. We show that the problem can be solved in polynomial time by reducing it to a polynomially solvable 0-1 unconstrained quadratic program.

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Animal Experiments Using Rotator Cuff

  • Chung, Seok Won;Kim, Sae Hoon;Oh, Joo Han
    • Clinics in Shoulder and Elbow
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    • v.17 no.2
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    • pp.84-90
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    • 2014
  • In conducting animal studies using rotator cuff, researchers should select the appropriate types of animals and experimental models. This should also be followed by complete understanding of the selected experimental animals as well as the methods for evaluating the results. Thus, researchers could minimize errors and failure in conducting animal experimental studies. Further, this will provide a basis of establishing new idea and theory about rotator cuff diseases.