• 제목/요약/키워드: cell degradation

검색결과 1,509건 처리시간 0.031초

저전류/저가습 조건에서 고분자전해질 막 열화 (Degradation of Polymer Electrolyte Membrane under Low Current/Low Humidity Conditions)

  • 김태희;이정훈;이호;임태원;박권필
    • 한국수소및신에너지학회논문집
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    • 제18권2호
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    • pp.157-163
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    • 2007
  • During PEMFC operation, low current and low humidity conditions accelerate the degradation of perfluorosulfonic acid membrane. But, there have been no studies that clearly explain why these conditions accelerate the membrane degradation. In this study, the hydrogen permeability through the membrane, I-V polarization of MEA, fluoride emission rate(FER) in effluent water were measured during cell operation under low current densities and low relative humidity(RH). The experimental results were evaluated with oxygen radical mechanism the most commonly known for membrane degradation. It seems that low RH of anode is a good condition for $H{\cdot}$ radical formation on the Pt catalyst and the low current condition accelerates the $H{\cdot}$ to form $HO_2{\cdot}$ radical attacking the polymer membrane.

태양 양성자 이벤트에 의한 삼중 접합 GAGET2-ID2 태양전지 열화 (Triple Junction GAGET2-ID2 Solar Cell Degradation by Solar Proton Events)

  • 구자춘;박정언;문건우
    • 한국항공우주학회지
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    • 제49권12호
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    • pp.1019-1025
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    • 2021
  • 거의 모든 우주 환경에서 태양전지 열화는 양성자에 의해 좌우된다. 정지궤도는 전자 방사선 벨트에 위치하지만 태양 이벤트에서 방출된 양성자는 여전히 태양전지 열화의 주된 요소이다. 2010년 6월 26일 천리안 1호가 발사된 이후로, 2012년 1월 23일에서 29일 그리고 2012년 3월 7일에서 14일에 다년 평균 관측 수준의 약 30배 이상의 플루언스를 갖는 양성자 이벤트가 관측되었다. 본 논문은 2012년 1월과 3월에 발생한 태양 양성자 이벤트에 의해 감시 셀의 개방회로 전압(Voc)과 션트 스위치에 연결된 한 섹션의 단락회로 전류(Isc)에 대한 태양전지 열화에 대해 연구한다. 태양전지의 성능을 평가하기 위해 전압과 전류의 비행 데이터는 온도, 지구-태양 거리, 태양 각도로 보정한 후 임무 초기 태양전지 특성과 비교한다. Voc 전압은 2012년 1월 양성자 이벤트 이전과 비교하여 2012년 3월 양성자 이벤트 이후에 약 23.6mV 감소되었다. 감소된 Voc 전압은 임무 초기값 2575mV에 대해 1% 미만이다. Isc 전류는 예상대로 2012년 3월 양성자 이벤트에서 무시할 정도로 감소되었다.

Afatinib Mediates Autophagic Degradation of ORAI1, STIM1, and SERCA2, Which Inhibits Proliferation of Non-Small Cell Lung Cancer Cells

  • Kim, Mi Seong;Kim, So Hui;Yang, Sei-Hoon;Kim, Min Seuk
    • Tuberculosis and Respiratory Diseases
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    • 제85권2호
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    • pp.147-154
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    • 2022
  • Background: The expression of calcium signaling pathway molecules is altered in various carcinomas, which are related to the proliferation and altered characteristics of cancer cells. However, changes in calcium signaling in anti-cancer drug-resistant cells (bearing a T790M mutation in epidermal growth factor receptor [EGFR]) remain unclear. Methods: Afatinib-mediated changes in the level of store-operated Ca2+ entry (SOCE)-related proteins and intracellular Ca2+ level in non-small cell lung cancer cells with T790M mutation in the EGFR gene were analyzed using western blot and ratiometric assays, respectively. Afatinib-mediated autophagic flux was evaluated by measuring the cleavage of LC3B-II. Flow cytometry and cell proliferation assays were conducted to assess cell apoptosis and proliferation. Results: The levels of SOCE-mediating proteins (ORAI calcium release-activated calcium modulator 1 [ORAI1], stromal interaction molecule 1 [STIM1], and sarco/endoplasmic reticulum Ca2+ ATPase [SERCA2]) decreased after afatinib treatment in non-small cell lung cancer cells, whereas the levels of SOCE-related proteins did not change in gefitinib-resistant non-small cell lung cancer cells (PC-9/GR; bearing a T790M mutation in EGFR). Notably, the expression level of SOCE-related proteins in PC-9/GR cells was reduced also responding to afatinib in the absence of extracellular Ca2+. Moreover, extracellular Ca2+ influx through the SOCE was significantly reduced in PC-9 cells pre-treated with afatinib than in the control group. Additionally, afatinib was found to decrease the level of SOCE-related proteins through autophagic degradation, and the proliferation of PC-9GR cells was significantly inhibited by a lack of extracellular Ca2+. Conclusion: Extracellular Ca2+ plays important role in afatinib-mediated autophagic degradation of SOCE-related proteins in cells with T790M mutation in the EGFR gene and extracellular Ca2+ is essential for determining anti-cancer drug efficacy.

실리콘 태양전지 열화특성 분석연구 (The characteristics research of silicon solar cell Degradation)

  • 최석준;신상욱;이세현;노재엽;권기태;이정근;서정진;이규승;황명근
    • 한국조명전기설비학회:학술대회논문집
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    • 한국조명전기설비학회 2009년도 추계학술대회 논문집
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    • pp.89-92
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    • 2009
  • In this paper, We observed degradation of general poly-cristalline silicon solar cell by light and heat. This is very important to define solar cell's characteristics. So we test eight cells that made of poly-cristalline silicon. We expect to the result of this experiment is useful for researching and measuring solar cell's characteristics.

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Remediation of Diesel-Contaminated Soil by Electrokinetically Supplied Bacterial Cells

  • 이효상;이기세
    • 한국지하수토양환경학회:학술대회논문집
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    • 한국지하수토양환경학회 2000년도 창립총회 및 춘계학술발표회
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    • pp.20-23
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    • 2000
  • The use of electrokinetic injection and transport for the distribution of an NAPLs-degrading microorganism in a sandy soil bed was studied. After the injection of the cell into cathode side of bed, an electric current was applied. The transport of cell though the sandy soil was achieved by electokinetics, mainly by electrophoresis, The pH control in electrode chamber plays un important role to achieve desirable cell transport because H$^{+}$ generated at anode is toxic or inhibits the transport of cells. Electokinetic distribution rate of bacterial cells changed depending on the applied electric current and pH. The degradation of diesel by electrokinetically transport cells were monitored.d.

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니켈 섬유 매트 촉매를 사용한 바이오가스 수증기개질 반응 (Steam Reforming of Biogas on Nickel Fiber Mat Catalysts)

  • ;김용민;윤창원;남석우
    • 에너지공학
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    • 제20권3호
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    • pp.252-258
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    • 2011
  • Nickel fiber mat was investigated as a potential structured catalyst for steam reforming of biogas in the temperature range of $600-700^{\circ}C$. The activity of as-received catalyst was very low owing to the smooth surface of fibers. Pretreatment of the catalyst by oxidation followed by reduction under methane partial oxidation condition significantly improved the catalytic activity, although degradation of the activity was found during the reaction due to oxidation and sintering. This deactivation was retarded by supplying additional hydrogen in the inlet gases or by coating $CeO_2$ over the catalyst surfaces.

TiN이 코팅된 316 스테인리스강 분리판을 이용한 고분자전해질 연료전지의 성능에 관한 연구 (A Study on the Performance of PEMFC Using the TiN-Coated 316 Stainless Steel Bipolar Plates)

  • 조은애
    • 한국수소및신에너지학회논문집
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    • 제14권4호
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    • pp.291-297
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    • 2003
  • As an alternative bipolar plate material for polymer electrolyte membrane fuel cell (PEMFC), TiN-coated 316 stainless was evaluated in terms of electrical contact resistance and water contact angle. Performance and lifetime of the TiN-coated 316 bipolar plates were measured in comparison with those of graphite and bare 316 bipolar plates. At a cell voltage of 0.6 V, current density of the single cells using graphite, AISI 316, and TiN/316 bipolar plates was 996, 796, and $896mA/cm^2$, respectively. By coating 316 stainless steel with TiN layer, performance degradation rate determined to be the voltage degradation rate at a cell voltage of 0.6 V was reduced from 2.3 to 0.43 mV/h.

플렉서블 CIGS 태양전지의 고온고습 환경 고장 기구 분석 (Evaluation of Failure Mechanism of Flexible CIGS Solar Cell Exposed to High Temperature and Humid Atmosphere)

  • 김혁수;변재원
    • 한국신뢰성학회지:신뢰성응용연구
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    • 제16권1호
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    • pp.41-47
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    • 2016
  • Purpose: The purpose of this study was to evaluate electrical and structural degradation of flexible CIGS sollar cell exposed to high temperature and humid atmosphere. Method: Accelerated degradation was performed for various time under $85^{\circ}C/85%RH$ and then electrical and structural properties were analyzed by 4-point probe method, scanning electron microscopy (SEM), energy dispersive spectroscopy (EDS), and X-ray diffraction (XRD). Results: Sheet resistance of the top ITO layer increased with exposure time to the high temperature and humid atmosphere. Blunting of the protrusion morphology of ITO layer was observed for the degraded specimen, while no phase change was detected by XRD. Oxygen was detected at the edge area after 300 hours of exposure. Conclusion: Increase in electrical resistance of the degraded CIGS solar cell under high temperature and humid environment was attribute to the oxygen or water absorption.

EFFECTS OF TRANSFORMATION CAPACITY ON COMETABOLIC DEGRADATION OF TRICHLOROETHENE

  • Lee, Seung-Bong;Kim, Geon-Ha
    • Environmental Engineering Research
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    • 제10권2호
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    • pp.79-87
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    • 2005
  • The effects of transformation capacity on cometabolic degradation of trichloroethene (TCE) were evaluated using TCE-degrading actinomycetes pure and mixed culture under various culture conditions. The TCE transformation capacity of the actinomycetes enrichment culture in a batch test with phenol addition was 1.0 mg of TCE/mg of volatile suspended solids (VSS). The resting cell TCE transformation capacity of the actinomycetes pure culture cell was 0.75 mg TCE/mg VSS, which increased to 2.0 mg TCE/mg VSS when phenol was added as an external substrate. When the pure culture had an internal substrate in the form of poly-β-hydroxybutyrate (PHB) at 19% of the cell mass, the resting cell TCE transformation capacity increased from 0.47 to 0.6 mg TCE/mg VSS. The presence of PHB increased transformation capacity by 57%, whereas, the addition of phenol caused more than two fold increase in transformation capacity. The actinomycetes culture showed the highest transformation capacity.

Improved Understanding of LeTID of Single-crystalline Silicon Solar Cell with PERC

  • Kim, Kwanghun;Baik, Sungsun;Park, Jaechang;Nam, Wooseok;Jung, Jae Hak
    • Current Photovoltaic Research
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    • 제6권4호
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    • pp.94-101
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    • 2018
  • Light elevated temperature induced degradation (LeTID) was noted as an issue in multi-crystalline silicon solar cells (MSSC) by Ram speck in 2012. In contrast to light induced degradation (LID), which has been researched in silicon solar cells for a long time, research about both LeTID and the mechanism of LeTID has been limited. In addition, research about LeTID in single-crystalline silicon solar cells (SSSC) is even more limited. In order to improve understanding of LeTID in SSSC with a passivated emitter rear contact (PERC) structure, we fabricated four group samples with boron and oxygen factors and evaluated the solar cell characteristics, such as the cell efficiency, $V_{oc}$, $I_{sc}$, fill factor (FF), LID, and LeTID. The trends of LID of the four group samples were similar to the trend of LeTID as a function of boron and oxygen.