• Title/Summary/Keyword: cationic

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Retention and Drainage Characteristics of Compozil System and Impact of Cationic Corn Starch for its Improvement (콤포질 시스템의 보류 및 탈수특성과 양성 옥수수전분을 이용한 성능 개선)

  • 이학래;김태영;윤혜정
    • Journal of Korea Technical Association of The Pulp and Paper Industry
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    • v.30 no.2
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    • pp.30-39
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    • 1998
  • Effect of cationic starches and anionic colloidal silica on retention and drainage characteristics of Compozil system was investigated. Depending upon the degree of substitution and molecular weight of cationic starches and morphological characteristics of anionic colloidal silica, retention and drainage properties of Compozil system were significantly influenced. When cationic starch addition level increased above a certain limit retention and stock freeness were decreased. To elucidate this an electrostatic coagulation mechanism occurring between unadsorbed starch molecules and anionic colloidal silica was proposed. Unstructured colloidal silica showed greater improvement in retention than structured colloidal silica. Cationic corn starches with different degree of substitution and molecular weights were prepared and their effect as a constituent of Compozil system was also evaluated. By controlling the molecular weight and degree of substitution of cationic corn starch it was possible to achieve significant improvement in fines retention. Cationic corn starch with higher degree of substitution maintained its retention efficiency even when the stock conductivity was increased. Turbidity measurement technique was found to be a simple and useful method to measure the retention characteristics.

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Influence of Conductivity and Anionic Trashes on Adsorption Behavior of Cationic Starches (전기전도도와 음이온성 트래쉬에 따른 양상전분의 흡착 거동변화)

  • 허동명;이학래
    • Journal of Korea Technical Association of The Pulp and Paper Industry
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    • v.31 no.3
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    • pp.10-18
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    • 1999
  • The influence of simple electrolyte or anionic trashes on cationic starch adsorption was examined using deinked pulp and bleached thermomechniical pulp. Adsorbed amounts of cationic starches increased slightly , then decreased abruptly as the concentration of simple electrolyte increased. This phenomenon was discussed based on the compression of electrical double layer and conformation change of starch molecules. Also, the effect of the type of simple electrolytes on starch adsorption was examined and discussed. Addition of sodium slilicate increased starch adsorption since it increased surface charge density of fibers. On the other hand, addition of kraft lignin decreased cationic demand of the pulp slurries and adsorbed amounts of cationic starches. Nonionic surfactant did not show any significant effect on the cationic demand of pulp slurries. When simple electrolytes were added to the stock , grater adsorption or cationic starches was obtained with starches of lower degree of substitution . On t도 other hand, amount of adsorbed starches decreased for lower DS starches when the concentration of anionic trashes increased.

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The Improvement of Dyeing Property of Cotton Fabric by Cationic Agent Treatment (카티온화제 처리에 의한 면직물의 염색성 개선)

  • Sung, Woo Kyung;Park, Sang Joo;Lee, Won Chul
    • Textile Coloration and Finishing
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    • v.9 no.1
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    • pp.33-43
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    • 1997
  • This study was carried out to investigate increasing the neutral substantivity of anionic dyes for cationic-modified cotton fabric treatied with cationic agent. In the present study 3-chloro-2-hydroxypropyltrimethyl ammonium chloride for reactive cationic agent was produced by reaction of epichlorohydrine with trimethylamine hydrochloride. 3-chloro-2-hydroxypropyltrimethylammonium chloride was converted in an aqueous solution of sodium hydroxide into glycidyltrimethylammonium chloride. By treating with this epoxy reagent the hydroxyl groups of cotton fabric was modified to trimethylammonium group through ether linkage. The introduction of new cationic sites into cotton fabric by pretreating with cationic agent improves the substantivity of anionic dyes with the cotton in dyebath. Dyeablity of the modified cotton fabric for direct and reactive dyes was much improved in a non-electrolytic or a little electrolytic dyebath and was proportional to the concentration of cationic agent.

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Expression of Antibacterial Cationic Peptides from Methylotrophic Yeast, Pichia pastoris

  • Lee, Gang-U;Choe, Yun-Jae
    • 한국생물공학회:학술대회논문집
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    • 2000.11a
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    • pp.669-671
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    • 2000
  • Antimicrobial cationic peptides have attracted increasing research and clinical interest as a natural antibiotics due to their broad spectrum of antimicrobial activites and the rapid development of multidrug-resistant pathogenic microorganisms. In this study, first, we synthesized artificial fusion partner and cationic peptide genes (lactoferricin, magainin, protegrin-1, and indolicidin). Second, we constructed recombinant expression vectors and then transformed Pichia pastoris. Finally, expressed cationic peptides were purified and tested for their antimicrobial activites. Antimicrobial activity has been tested upon the appearance of clearing zone on the plate with the lawn of gram negative E.coli XL- I blue and garm positive Staphylococcus aureus. Protegrin-1 and Indolicidin have apparant activity of cationic peotides. This fusion technique may lead to a general and suitable tool for production of pure antimicrobial cationic peptides in Pichia pastoris.

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Adsorption Behavior of Cationic Starches onto Deinked Pulp and Thermomechnical Pulp (탈묵펄프와 열기계펄프에 대한 양성전분 흡착 거동)

  • 허동명;이학래
    • Journal of Korea Technical Association of The Pulp and Paper Industry
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    • v.31 no.2
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    • pp.42-49
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    • 1999
  • Although many researches have been made on the adsorption of cationic starches onto chemical pulp fibers, only limited studies have been reported for deinked pulp(DIP) and thermomechanical pulpI(TMP). In this experiment, the adsorption behavior of the cationic starches onto DIP and TMP fibers investigated. Almost complete adsorption of cationic starches onto the pulp fibers were observed when the addition rate of starch was low. Adsorption ratio decreased abruptly when 3.5% and 4.0% of cationic starches were adsorbed onto deinked pulp and thermomechanical pulp, respectively. Adsorption of cationic starches increased as the degree of substitution decreased and as the pH of the pulp slurry increased. TMP fibers adsorbed more cationic starches than DIP because of its greater charge density, and this led to greater improvement in strength properties for the TMP sheets.

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Contribution of lysine-containing cationic domains to thermally-induced phase transition of elastin-like proteins and their sensitivity to different stimuli

  • Jeon, Won-Bae
    • BMB Reports
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    • v.44 no.1
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    • pp.22-27
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    • 2011
  • A series of elastin-like proteins, $SKGPG[V(VKG)_3VKVPG]_n$-(ELP1-90)WP (n = 1, 2, 3, and 4), were biosynthesized based on the hydrophobic and lysine linkage domains of tropoelastin. The formation of self-assembled hydrophobic aggregates was monitored in order to determine the influence of cationic segments on phase transition properties as well as the sensitivity to changes in salt and pH. The thermal transition profiles of the proteins fused with only one or two cationic blocks (n = 1 or 2) were similar to that of the counterpart ELP1-90. In contrast, diblock proteins that contain 3 and 4 cationic blocks displayed a triphasic profile and no transition, respectively. Upon increasing the salt concentration and pH, a stimulus-induced phase transition from a soluble conformation to an insoluble aggregate was observed. The effects of cationic segments on the stimuli sensitivity of cationic bimodal ELPs were interpreted in terms of their structural and molecular characteristics.

Dyeing of Cotton Knitted Fabrics with Volcanic Ash (II) - The Dyeability Change According to Cationic Agent Treatment - (화산재를 이용한 면 편성물의 염색(II) - 카티온화 처리에 따른 염색성 변화 -)

  • 신인수;유복선
    • Journal of the Korean Home Economics Association
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    • v.42 no.4
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    • pp.119-125
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    • 2004
  • In this paper, the effect of the volcanic ash dyed on cotton knitted fabrics was studied in various ways. A cationic agent was used to improve the depth of color of the fabric in the dyeing process. K/S values of dyed fabrics were measured to examine the dyeing properties. Cationic agent pretreatment, followed by dyeing with volcanic ash, was tested. In the dyeing experiment, the effects of a wide range of parameters such as the concentration of cationic agent, treatment time, treatment temperature and treatment pH of the dyebath were studied. Experimental results showed that the pretreatment with cationic agent improved the dyeing properties of cotton knitted fabrics with volcanic ash. At this point, concentration of cationic agent was 4%(on weight of fabric), treatment time was 40minutes, treatment temperature was 80 C and treatment pH of the dyebath was a neutral condition.

Polyethylene glycol (PEG)-modified cationic liposome mediated gene delivery

  • Kim, Jin-Ki;Choi, Sung-Hee;Ahn, Woong-Shick;Kim, Chong-Kook
    • Proceedings of the PSK Conference
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    • 2002.10a
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    • pp.426.1-426.1
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    • 2002
  • In this study. we modified the cationic liposomes by polyethylene glycol (PEG)-grafted or PEG-added methods. The PEG-grafted transfection complexes were prepared by adding the plasmid DNA to the PEG-grafted cationic liposomes, composed of PEG and cationic lipids. PEG-added transfection complexes were prepared by adding the PEG to the mixture of cationic lipids and plasmid DNA. The particle sizes of PEG-modified transfection complexes did not change during storage compared to conventional transfection complexes. (omitted)

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Cationic Emulsions with Galactosylated Chitosan as a Novel Gene Delivery System

  • Choi, Woo-Jeong;Choi, Sung-Hee;Ahn, Woong-Shick;Kim, Chong-Kook
    • Proceedings of the PSK Conference
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    • 2002.10a
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    • pp.427.1-427.1
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    • 2002
  • To improve stability and transfection efficiency, a novel combination of cationic emulsion and galactosylated chitosan was developed for targeted gene delivery. Six formulations of cationic liposome and our novel emulsion were prepared for comparison of stability and transfection efficiency. Cationic liposomes composed of 3[N-(N.N dimethylaminoethylene) carbamoyl] cholesterol (DC-Chol) and dioleyl phophatidyl ethanolamine (DOPE) were prepared by extrusion method and cationic emulsions composed of DC-Chol. DOPE. castor oil, and Tween 80 were prepared by sonication method. (omitted)

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Analysis of Cationic Surfactants in Cosmetics By Reverse phase Ion-Pair Chromatigraphy with Suressed Conductivity Detector and UV Detector

  • Jong-Keun Choi;Jae
    • Journal of the Society of Cosmetic Scientists of Korea
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    • v.23 no.3
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    • pp.161-167
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    • 1997
  • Determination of several cationic surfactants in cosmetics has been investigated. Reverse phase ion pair chromatography was used to identify and quantitate cationic surfactants. Cationic surfactants analyzed in this experiment were cetylpyridium chloride, stearyltrimetylammonium chloride, bezalkonium chloride, benzyldicethylcetylammonium chloride, and bihenyltrimethyl ammonium chloride. The separation was achieved on a reverse phase coumn with 10mM HCl-acetonitrile eluent. In this condition, the most of cationic surfactants with exception of CPC and CTAC respectively with suppressed conductivity detector and UV detector connected in series. The calibration curves obtained by plotting the peak areas of the cationic surfactants were linear at levels ranging from 0.005 to 0.1% correlation coefficient, r=0.9988. The detection limits were 1 to 5ppm in sample solution. The average recoveries of cationic surfactants added to hair treatment cream and hair rinse in three to five experiments were 96.7 105.2% and relative standard deviations were 1.1-3.8%. The case that there were CPC and CTAC in same solution was also tested. CPC and CTAC which couldn't be separated on reverse phase column were quantitated with suppressed conductivity detector and UV detector connected in series. Recovery of CPC and CTAC were 101.6 and 89.2% respectively. The proposed method was applied to the determination of cationic surfactants in commercial hair treatment cream.

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