• 제목/요약/키워드: cathodic potential

검색결과 268건 처리시간 0.022초

해양구조물 RE36강의 용접부 부식거동 및 SSRT법에 의한 기계적 특성에 관한 연구 (A Study on the Corrosion Rehavior and Mechanical Property by SSRTTest of Welding Part of RE36 Steel for Marine Structure)

  • 김종성;김진경;김종호;이명훈;김영식;문경만
    • Journal of Advanced Marine Engineering and Technology
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    • 제24권4호
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    • pp.460-469
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    • 2000
  • A study on the corrosion behavior of RE36 steel for marine structure was investigated with parameters such as micro-Vickers hardness, corrosion potential and corrosion current density measurement of weld metal(WM), base metal (BM) and heat affected zone(HAZ), Al anode generating current and Al anode weight loss quantity in case of cathodic protection. And we carried out slow strain rate test(SSRT) in order to research mechanical properties such as stress at maximum load, percent strain, time to fracture and strain to failure ratio etc and to find out limiting cathodic polarization potential for hydrogen embrittlement with applied cathodic polarization potential. Hardness of HAZ part was the highest among those three parts and also galvanic corrosion susceptibility was the highest in HAZ part among those three parts due to the lowest corrosion potential than other parts. However corrosion current density was the highest in WM part among those three parts. And the optimum cathodic polarization potential showing the best mechanical properties obtained by SSRT method with applied constant cathodic potential was from - 770mV to - 875mV(SCE). However it is suggested that limiting cathodic polarization potential indicating hydrogen embrittlement on the mechanical properties was under - 900mV(SCE).

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해양구조물용 RE36강 용접부의 부식거동 및 기계적 특성에 미치는 용접후 열처리 효과에 관한 연구 (A Study on the Post-Weld Heat Treatment Effect Affecting Corrosion Behavior and Mechanical Property of Welding Part of RE36 Steel for Marine Structure)

  • 김성종;문경만
    • Journal of Welding and Joining
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    • 제19권1호
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    • pp.65-74
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    • 2001
  • A study on the corrosion behavior in case of As-welded and PWHT temperature 55$0^{\circ}C$ of welding part of RE36 steel for marine structure was investigated with parameters such as micro-Vickers hardness, corrosion potential measurement of weld metal(WM), base metal(BM) and heat affected zone(HAZ), both Al anode generating current and Al anode weight loss quantity under sacrificial anode cathodic protection conditions. And also we carried out slow strain rate test(SSRT) in order to research both limiting cathodic polarization potential for hydrogen embrittlement and optimum cathodic protection potential as well as mechanical properties by post-weld heat treatment(PWHT) effect. Hardness of HAZ was the highest among three parts(WM, BM and HAZ) and the highest galvanic corrosion susceptibility was HAZ. And the optimum cathodic polarization potential showing the best mechanical properties by SSRT method was from -770mV to -875mV(SCE). In analysis of SEM fractography, applied cathodic potential from -770mV to -875mV(SCE) it appeared dimple pattern with ductile fracture while it showed transgranular pattern (Q. C : quasicleavage) under -900mV(SCE). However it is suggested that limiting cathodic polarization potential indicating hydrogen embrittlement was under -900mV(SCE).

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강의 음극방식에 미치는 표면상태와 유속의 영향 (The Effects of Surface Condition and Flow Rate to the Cathodic Protection Potential and Current on Steel)

  • Kyeong-soo, Chung;Seong- Jong, Kim;Myung-Hoon, Lee;Ki-Joon, Kim;Kyung-Man, Moon
    • Journal of Advanced Marine Engineering and Technology
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    • 제28권6호
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    • pp.972-980
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    • 2004
  • Cathodic protection is being widely used to protect steel structures in sea water environment, In order to protect steel structures completely, the flow condition of sea water surrounding with this structures and the surface condition of the structures must be considered for a desirable design of cathodic protection. In this study, the optimum protection potential and current density were investigated in terms of cathodic current density, surface condition and a flow condition of sea water. The optium protection potential of the cleaned specimen was -770 mV(SCE) and below. However in the case of the rusted specimen, its potential was -700 mV(SCE) and below, which was somewhat positive than the cleaned one irrespective of flow condition. The optimum cathodic protection current density for both the cleaned and rusted specimens was 100 mA/$\textrm{m}^2$, however, on the flow condition, 200 mA/$\textrm{m}^2$ to be supplied for cathodic protection of steel structures completely for both cleaned and rusted specimens.

The effect of cathodic protection system by means of zinc sacrificial anode on pier in Korea

  • Jeong, Jin-A;Jin, Chung-Kuk
    • Journal of Advanced Marine Engineering and Technology
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    • 제38권10호
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    • pp.1206-1211
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    • 2014
  • This study has been conducted to confirm the effect of sacrificial anode cathodic protection system for 90 days to protect corrosion on pier that is located in Korea. The cathodically protected structure was a slab and a pile cap. Before the construction of cathodic protection system, the macrography was carried out. As a result of the macrography, many corrosion traces were confirmed in this structure. The trace was mainly focused on joint and zones that concrete cover was eliminated. To apply the cathodic protection system, many onsite techniques have been adopted. In addition, to confirm the inner state of steel in concrete properly, a corrosion monitoring sensor (DMS-100, Conclinic Co. Ltd) has been applied. Test factors were corrosion & cathodic protection potential, 4 hour depolarization potential, resistivity and current density. After 90 days from the installation of cathodic protection system, it could confirm that proper corrosion protection effect was obtained by considering the result of tests.

Investigation of the Effective Range of Cathodic Protection for Concrete Pile Specimens Utilizing Zinc Mesh Anode

  • Duhyeong Lee;Jin-A Jeong
    • Corrosion Science and Technology
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    • 제23권3호
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    • pp.195-202
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    • 2024
  • A zinc mesh sacrificial anode cathodic protection method is recently being developed to protect the reinforced concrete structure in a marine environment. However, comprehensive information regarding the cathodic protection technology applied to reinforced concrete test specimens utilizing zinc mesh sacrificial anodes remains limited. Particularly, no research has investigated the effective range of sacrificial anode cathodic protection in a reinforced concrete structure regarding the transmission of protection current from zinc mesh sacrificial anode to the reinforced concrete structure, particularly concerning effects of temperature variations. This study examined the distribution of potential and current using a long single rebar and several segment reinforcing bars inside a horizontal beam. Vertical pile specimens were applied with a zinc mesh sacrificial anode to simulate concrete bridges or harbor structures. To check the effect of cathodic protection, cathodic protection potential and current of the reinforced concrete specimens were measured and 100 mV depolarization criterion test was performed. It was confirmed that effect of cathodic protection varied depending on resistivity and temperature. The cathodic protection test of pile specimens revealed that the maximum reachable range of cathodic protection current was 10 cm from the waterline as observed in the experiment.

아연 양극에 의한 도장강판과 나강판의 방식 연구 (A Study on the Protection of the Bare and Painted Steel Plates)

  • 문경만;김종신;김진경
    • Journal of Advanced Marine Engineering and Technology
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    • 제17권1호
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    • pp.55-65
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    • 1993
  • Galvanic protection method is one the cathodic protection methods and is mostly used for corrosion prevention of heat exchangers and ship's hull. In this paper, it was investigated that how cathodic potential distribution was varied with according to the bare and painted steel plates in case of galvanic anode protection. The results obtained above were as follows. 1. Cathodic potential distribution of a painted steel plate was smoothed than that of the bare steel plate all over the cathodic surface area. 2. It was shown that polarization potential of the bare steel plate was somewhat shifted to negative potential, on the contrary that of the painted steel plate was somewhat shifted from negative potential to positive potential as time gone by beginning of galvanic anode method. 3. The applied current density in order to maintain constant protection potential(-770mv SCE) in the painted steel plate was less than that of the bare steel plate because of the high resistance polarization of the painted steel plate. 4. It was suggested that required number and life-time of anode for galvanic anode protection could be decided easily with corrosion prevention coefficient obtained by experimental data.

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Quantitative estimation of reversibility of the discharge process undergone by nickel hydroxide film cathodically deposited on pure nickel as a positive supercapacitor electrode using cyclic voltammetry and potential drop method

  • Pyun Su-Il;Moon Sung-Mo
    • 전기화학회지
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    • 제1권1호
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    • pp.8-13
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    • 1998
  • This work presents the way how to evaluate the degree of reversibility of the discharging process undergone by the nickel hydroxide film cathodically deposited on pure nickel as a positive electrode for electrochemical capacitor using the combined cyclic voltammetry and potential drop method, supplemented by galvanostatic discharge and open-circuit potential transient methods. The time interval necessary just to establish the current reversal of anodic to cathodic direction from the moment just after applying the potential inversion of anodic to cathodic direction, was obtained on cyclic voltammogram. The cathodic charge density passed upon dropping the applied potential, was calculated on potentiostatic current density-time curve. Both the time interval and the cathodic charge density in magnitude can be regarded as being measures of the degree of reversibility of the discharging process undergone by the positive active material for supercapacitor, i.e. , the longer the time interval is, the lower is the degree of reversibility and the greater the cathodic charge density is, the higher is the degree of reversibility. From the applied potential dependences of the time interval and cathodic charge density, discharge at $0.42 V_{SCE}$ was determined to be the most reversible.

Numerical analysis results of the cathodic protection for the underground steel pipe by anode installation method

  • Jeong, Jin-A;Choo, Yeon-Gil;Jin, Chung-Kuk;Park, Kyeong-Wan
    • Journal of Advanced Marine Engineering and Technology
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    • 제38권10호
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    • pp.1212-1216
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    • 2014
  • This study aims to find out the best anode location for buried pipelines. Numerical simulation program known as CATPRO (Elsyca, Belgium) were used for confirming the best location of anodes and the effects of impressed current cathodic protection system. Applied conditions for numerical simulation were similar to on-site environmental conditions for optimal application of cathodic protection system. Used criterion of cathodic protection was NACE SP 0169, which describes that minimum requirement for cathodic protection is -850mV vs. CSE. Various layouts for anodes' installation were applied, which were distance between anodes, anode installation location, and applied current. The areas where cathodic protection potential was lower than -850mV vs. CSE was limited up to 50m from anode installation locations. It was founded numerical analysis obtain cost-effective and efficient cathodic protection methods before design and application the impressed cathodic protection system to on-site environment.

The effect of temperature and relative humidity on concrete slab specimens with impressed current cathodic protection system

  • Jeong, Jin-A;Jin, Chung-Kuk
    • Journal of Advanced Marine Engineering and Technology
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    • 제37권3호
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    • pp.260-265
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    • 2013
  • Impressed current cathodic protection (ICCP) system is one of the most promising corrosion protection methods. The Effect of ICCP system can be changed at diverse conditions. Particularly, temperature and relative humidity plays a crucial role in CP (Cathodic Protection) effect. Thus, in this study, the influence of temperature and relative humidity on concrete specimens was investigated. Specimens were concrete slab type with a base of $400mm{\times}400mm$ and height of 70mm. To enhance the effect of CP system, seawater was used as an electrolyte. Used anode for ICCP system was mixed metal oxide (MMO) titanium. Test factors were natural potential, CP potential, CP current, and 4-hour depolarization potential. From this study, it could be confirm that CP potential and current were highly influenced by temperature and relative humidity.

희생양극식 음극방식이 적용된 해안 교량 구조물의 방식거동 (Cathodic Protection Behavior of Coastal Bridge Structure with Sacrificial Anode Cathodic Protection System)

  • 하지명;진충국;정진아
    • Corrosion Science and Technology
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    • 제11권6호
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    • pp.242-246
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    • 2012
  • This measurement represents the effectiveness of sacrificial anode cathodic protection (SACP) system in a coastal bridge structure. To verify the cathodic protection (CP) effect, the monitoring sensor (DMS-100) that could measure potential, corrosion rate, current, concrete resistivity, and temperature was embedded. The measurement conducted for three years after CP system was installed. Specifically, due to the fact that fresh water and sea water was repeated in the bridge structure, this bridge structure presented special CP behavior. Measurement factors were CP potential, CP current, concrete resistivity, and depolarization potential. In addition, visual inspection was also carried out. As a result of current and depolarization measurement, CP system was well activated in most piers.