• Title/Summary/Keyword: cast film

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방전플라즈마 소결법에 의해 제조된 Cu 타겟과 스퍼터링 박막의 특성평가 (Evaluation of the Cu Target Fabricated by the SPS Technique and its Sputtered Film)

  • 현혜영;김민정;유정호;양준모;오익현;이승민;오용준
    • 대한금속재료학회지
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    • 제49권3호
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    • pp.250-255
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    • 2011
  • The basic properties and electrical characteristics of sputtering films deposited with a commercial cast target and Spark Plasma Sintering (SPS) were compared and analyzed. From the results, the Cu film prepared heating $60^{\circ}C/min$ (SPS process) showed a similar specific resistance compared to the commercial cast Cu film. Also, auording to the results of XRD, SIMS, and TEM. There was not much difference in the crystal structure and impurities between the two films. Consequently, the SPS Cu target was found to have quite similar properties with the commercial one and it is expected to be applied in futare research to the metal wiring material for semiconductor/display devices.

Ester 및 Ether형 Polyurethane Ionomer의 Emulsion 블랜드 (Emulsion Blends of Polyurethane Ionomers from Ester and Ether Type Polyols)

  • 김상준;김병규
    • 공업화학
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    • 제3권4호
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    • pp.614-619
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    • 1992
  • Soft segment가 각각 ester 및 ether형 polyol로된 2종의 polyurethane(PU) ionomer를 emulsion 블렌딩하여, 블렌드의 분산점도, 및 emulsion cast film의 접촉각, 기계적 특성을 조성의 함수로 측정하였다. 블렌드의 기계물성은 혼합법칙으로부터 심한 scattering이나, negative deviation을 보였으며, 이는 ester 및 ether형 polyol간의 상용성의 결여에 기인하는 것으로 보았다. 접촉각 측정 결과로부터 유화입경이 작은 PPG PU 입자가 주로 도막표면층을 형성하는 것을 확인할 수 있었다.

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Experimental and Theoretical Studies on Corrosion Inhibition Performance of Phenanthroline for Cast Iron in Acid Solution

  • Idir, B.;Kellou-Kerkouche, F.
    • Journal of Electrochemical Science and Technology
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    • 제9권4호
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    • pp.260-275
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    • 2018
  • The corrosion inhibition of cast iron in 1 M HCl by Phenanthroline (Phen) was investigated using potentiodynamic polarization (PDP) curves, electrochemical impedance spectroscopy (EIS), surface analysis and theoretical calculations. It is found that Phen exhibits high inhibition activity towards the corrosive action of HCl and its adsorption obeys the Langmuir adsorption isotherm model. The results showed that inhibition efficiency increases with Phen concentration up to a maximum value of 96% at 1.4 mM, and decreases slightly with the increase in temperature. The free adsorption energy value indicates that Phen adsorbs on cast iron surface in 1 M HCl via a simultaneous physisorption and chemisorption mechanism. Scanning electron microscopy (SEM) micrographs, atomic force microscopy (AFM) and FTIR analysis confirmed the formation of a protective film on cast iron surface, resulting in the improvement of its corrosion resistance in the studied aggressive solution. Quantum chemical calculations at the DFT level were achieved to correlate electronic structure parameters of Phen molecules with their adsorption mode.

InGaZnO 용액의 농도가 Drop-casting으로 제작된 산화물 박막 트랜지스터의 전기적 특성에 미치는 영향 (Effect of InGaZnO Solution Concentration on the Electrical Properties of Drop-Cast Oxide Thin-Film Transistors)

  • 노은경;유경민;김민회
    • 센서학회지
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    • 제29권5호
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    • pp.332-335
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    • 2020
  • Drop casting, a solution process, is a simple low-cost fabrication technique that does not waste material. In this study, we elucidate the effect of the concentration of a InGaZnO solution on the electrical properties of drop-cast oxide thin-film transistors. The higher the concentration the larger the amount of remnant InGaZnO solutes, which yields a thicker thin film. Accordingly, the electrical properties were strongly dependent on the concentration. At a high concentration of 0.3 M (or higher), a large current flowed but did not lead to switching characteristics. At a concentration lower than 0.01 M, switching characteristics were observed, but the mobility was small. In addition to a high mobility, sufficient switching characteristics were obtained at a concentration of 0.1 M owing to the appropriate thickness of the semiconductor layer. This study provides a technical basis for the low-cost fabrication of switching devices capable of driving a sensor array.

Nanofabrication of Microbial Polyester by Electrospinning Promotes Cell Attachment

  • Lee, Ik-Sang;Kwon, Oh-Hyeong;Wan Meng;Kang, Inn-Kyu;Yoshihiro Ito
    • Macromolecular Research
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    • 제12권4호
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    • pp.374-378
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    • 2004
  • The biodegradable and biocompatible poly(3-hydroxybutyrate-co-3-hydroxyvalerate) (PHBV), a copolymer of microbial polyester, was fabricated as nanofibrous mats by electrospinning. Image analysis of the electrospun nanofibers fabricated from a 2 wt% 2,2,2-trifluoroethanol solution revealed a unimodal distribution pattern of fiber diameters with an observed average diameter of ca. 185 nm. The fiber diameter of electrospun fabrics could be controlled by adjusting the electro spinning parameters, including the solvent composition, concentration, applied voltage, and tip-to-collector distance. Chondrocytes derived from rabbit ear were cultured on a PHBV cast film and an electrospun PHBV nano-fibrous mat. After incubation for 2 h, the percentages of attached chondrocytes on the surfaces of the flat PHBV film and the PHBV nanofibrous mat were 19.0 and 30.1 %, respectively. On the surface of the electrospun PHBV fabric, more chondrocytes were attached and appeared to have a much greater spreaded morphology than did that of the flat PHBV cast film in the early culture stage. The electro spun PHBV nanofabric provides an attractive structure for the attachment and growth of chondrocytes as cell culture surfaces for tissue engineering.

치과용 합착제의 선택 (Selection of Dental Cements)

  • 성무경
    • 대한심미치과학회지
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    • 제8권1호
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    • pp.76-82
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    • 1999
  • Zinc phosphate cement has long been the material of choice for permanent luting of cast restorations, and through many years of use has been considered effective to retain castings. However, cast restorations cemented with this material have been susceptible to secondary caries. Glass ionomer luting agents become available in the late 1970s. These material s, through release of fluoride, show considerable promise as a means of reducing secondary caries. Other favorable traits include significantly less disintegration in vivo than zinc phosphate cements, a film thickness comparable to that of zinc phosphate cement, and adhesion to tooth structure. Compomer materials were created in 1993 as a filling material for deciduous teeth, cervical lesions, and class III cavities. In the meantime, compomer have been developed as chemical hardening cements for cast gold restorations. The aim of this paper is to review the articles on luting cements to help the choice of dental cements.

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CV흑연주철(黑鉛鑄鐵)에서의 표면응고층(表面凝固層) 생성(生成)에 관(關)한 연구(硏究) (A study on the formation of surface solidification layer in compacted/vermicular graphite cast iron)

  • 박기성;이상익;김수영
    • 한국주조공학회지
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    • 제6권1호
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    • pp.20-26
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    • 1986
  • In order to investigate the solidification characteristics of CV. graphite cast iron, decantation technique and thermal analysis test were used. Solidification characteristics were studied in the specimens with various compositions and graphite shape. The results were as follows; 1. The first surface solidifcation layer is formed along the mold wall by the growth of austenite dendrites in hypoeutectic composition and thin solid film in hypereutectic composition. 2. The mushy degree of solidifcation of hypereutiectic composition is higher than that of hypoeutectic. 3. In hypoeutectic, the effect of change of the mushy degree of solidification on the graphite shape is small, however, in hypereutectic the mushy degree of solidification becomes higher in order of flake, CV, and spheroidal graphite cast iron.

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PS-PB-PS 삼블럭 공중합체 박막형판에서의 금의 자기응집에 의한 Nano-Scale 패턴형성 (Nano-Scale Patterning by Gold Self-Assembly on PS-PB-PS Triblock Copolymer Thin Film Templates)

  • Kim, G.;Libera, M.
    • Elastomers and Composites
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    • 제34권1호
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    • pp.45-52
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    • 1999
  • 본 논문에서는 미세 상분리된 블럭 공중합체 박막의 특이상에서 금 입자들이 어떻게 자기응집(self assemble) 되고 잘 배열된 패턴을 형성하는지를 살펴보았다. 본 연구에서는 원통형 모폴로지를 갖는 PS-PB-PS 삼블럭 공중합체(30wt% PS) 박막(${\sim}100nm$)을 0.1wt% 톨루엔 용액으로부터 캐스팅하여 고분자 박막 형판(template)으로 사용하였다. 각각의 상이한 용매 증발조건으로부터 PB matrix내에 수평배열 PS cylinder와 수직 PS cylinder를 함께 갖는 막이 얻어졌다. 블럭 공중합체박막의 표면 및 bulk 몰폴로지를 살펴보기 위하여 단면투과전자현미경(TEM)을 사용하였다. Nano-scale 패턴을 얻기 위하여는 소량의 금입자를 블럭 공중합체 박막상에 증발시켰다. 캐스팅된 상태 그 대로의 박막형판이 사용되어질때 금입자들은 표면 장력이 적은 PB상에 우선적으로 자기응집(self as-semble)하여 비교적 잘 배열된 nano-scale의 패턴을 형성하였다. 그러나 열처리(annealing)에 의하여 표면장력이 적은 PB-rich충이 형성된 후에는 금입자의 자기응집에 의한 패턴은 관찰되지 않았다.

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선박 엔진의 실린더 라이너용 합금주철의 부식마멸에 미치는 분위기의 영향 (Effect of Atmosphere on Corrosive Wear of Alloy Cast Iron for Cylinder Liner of Large Ship Engine)

  • 구현호;조연상;조화영;박흥식
    • Tribology and Lubricants
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    • 제28권5호
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    • pp.233-239
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    • 2012
  • The engine of a large ship operates under wet conditions using a fuel such as bunker C oil, which includes sulfur and many impurities. A cylinder liner made of cast iron is very susceptible to damage such as scuffing on the surface. This scuffing can reliably be attributed to the destruction of the oil film and the corrosion wear caused by water and sulfur included in the fuel, along with abrasion impurities and poor lubricants. In this study, a reciprocating friction and wear test was carried out with a cast iron specimen, which was used to simulate an engine cylinder in a corrosive environment. Base-oil and stirred oil containing distilled water, NaCl solution, and dilute sulfuric acid were used as lubricants. The friction surface was analyzed using a microscope and EDAX, and the friction coefficient was measured using a load-cell under each experimental condition. We then attempted to investigate the damage to the cylinder liner using the results.