• Title/Summary/Keyword: carbonation curing

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Pore Structure and Fractal Characters of Cement Mortar Containing γ-C2S (γ-C2S 혼입 시멘트 모르타르의 공극구조 및 Fractal특성)

  • Chen, Zheng-Xin;Lee, Han-Seung
    • Proceedings of the Korean Institute of Building Construction Conference
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    • 2017.11a
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    • pp.24-25
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    • 2017
  • Gamma-C2S (γ-C2S) is a substance that is difficult to react with water under normal temperature but can absorb a large amount of CO2 in the air. The addition of γ-C2S to cementitious materials through the curing of CO2 can improve the pore structure and improve the durability of the material. In this study, three kind of Ca-bearing materials : CaO, Ca(OH)2, CaCO3, were calcined 2.5h at 1450℃ to synthesize γ-C2S after mixing with SiO2 respectively. Among them, Ca(OH)2 mixed with SiO2 after calcining shows highest content. Synthesized γ-C2S was added to the cement mortar, after water curing for 1 month, accelerated carbonation test was experimented. After 28d accelerated carbonation test, pore structure will be detectived by MIP. Based on the MIP result, following the calculation method of Fractal theory, the pore structure will be quantitative described.

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Physicochemical Properties of Cement Paste Containing Mg(OH)2 Cured by CO2 curing Method (CO2 양생을 이용한 Mg(OH)2 혼입 시멘트 페이스트의 물리화학적 특성)

  • Chen, Zheng-Xin;Lee, Han-Seung
    • Journal of the Korea Institute of Building Construction
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    • v.18 no.3
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    • pp.203-210
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    • 2018
  • Corrosion of the rebar is one of the main factors affecting the durability of reinforced concrete in the world which lead to the failure of the reinforced concrete structures. In this research, a new method of fixing $CO_2$ is practiced to improve the carbonation resistance of the concrete. Brucite($Mg(OH)_2$), a kind of common $CO_2$ fixation materials, was added into ordinary Portland cement paste. Samples containing 0%, 5%, 10%, and 15% $Mg(OH)_2$ were exposed to an accelerated carbonation curing regime with 20% concentration of $CO_2$, 60% relative humidity, and a temperature of $20^{\circ}C$ until tested at 3d, 7d, 14d and 28d. After 28d of $CO_2$ accelerated curing, in the paste containing $Mg(OH)_2$, magnesian calcite was detected by SEM-EDX. Meanwhile, the paste containing $Mg(OH)_2$ exhibit the better pore distribution than ordinary Portland cement paste and the compressive strength of the cement paste containing $Mg(OH)_2$ were more than 50Mpa.

An Investigation on Estimation of the Compressive strength by P Type Schmidt Hammer (P형 슈미트햄머에 의한 압축강도 추정에 관한 검토)

  • 김기정;이용성;이백수;윤기원;최영화;한천구
    • Proceedings of the Korean Institute of Building Construction Conference
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    • 2002.11a
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    • pp.11-15
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    • 2002
  • This study is intended to analyze the relationship between the rebound value of P type schmidt hammer and the compressive strength for a quality control of concrete. According to the results, the compressive strength of standard curing specimen increases in proportion to age, but that of air curing specimen hardly increases after 28 days. The rebound value of P type schmidt hammer, however, increases due to carbonation of concrete in air curing specimen. The correlativity between the rebound value and the compressive strength is very favorable in the case of standard curing specimen, but drops remarkably in the case of air curing specimen. Thus, as application of age coefficient is required for exact estimation of the compressive strength, the age coefficient is derived from this study. The age coefficient of P type schmidt hammer is higher at the age of 3 and 7days, and drops significantly, compared with the age of 28days. And it is lower before 28days than that of N type schmidt hammer suggested in Japan, and shows the similar tendency after 28days.

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Prediction of Carbonation Progress for Concrete Structures Considering Change of Atmospheric Environment (대기환경변화를 고려한 콘크리트 구조물의 중성화 예측)

  • Lee, Chang-Soo;Yoon, In-Seok
    • Journal of the Korea Concrete Institute
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    • v.15 no.4
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    • pp.574-584
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    • 2003
  • The most common deterioration cause of concrete structures in urban environment is carbonation. Recently, the $CO_2$ concentration and temperature at atmosphere is sharply increased with time due to global warming phenomena. In this study, the climate scenario IS92a, which was suggested by the IPCC, is used to consider temperature and atmospheric $CO_2$ concentration change in the model of service life prediction. The modified mathematical solution, which was based on the Fick's 1st law of diffusion, was used to reflect concrete materials properties such as the degree of hydration of concrete with elapsed time, and important parameters, which associated with deterioration rate. The techniques of service life prediction are developed introducing the method of reliability and stochastic concept to consider microclimatic condition in Seoul, South Korea. From the result of service life prediction, concrete containing high W/C ratio is shown fast carbonation rate due to $CO_2$ concentration increase. It is concluded that the deterioration of concrete structures due to carbonation is insignificant problem on the conditions that below W/C 55%, well curing concrete.

Bond Strength and Corrosion Resistance of Coated Reinforcing Bar Using Hybrid-Type Polymer Cement Slurry (Hybrid형 폴리머 시멘트 슬러리로 도장한 철근의 부착강도와 부식저항성)

  • Jo, Young-Kug
    • Journal of the Korea Institute of Building Construction
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    • v.8 no.3
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    • pp.93-99
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    • 2008
  • The purpose of this study is to evaluate the bond strength and corrosion resistance of coated reinforcing bar using hybrid-type polymer cement slurry(PCS). PCS coated steels, which is made from two types of polymer dispersions such as St/BA and EVA are prepared, and tested for bond strength and various corrosion resistances such as autoclaved cure, carbonation and H2SO4 solution. From the test results, the bond strength of PCS coated reinforcing bar using ordinary portland cement at 1-5, 2-1 and 4-5 of mixes is higher than that of uncoated regular steel. However, bond strength of almost PCS coated reinforcing bars using ultra rapid high strength cement is higher than that of epoxy coated bar, is also in ranges of 102% to 123% compared to that of uncoated regular steel. In autoclaved accelerating test, the ratio of corrosion of uncoated regular steel is increased with the increase in NaCl content, but the corrosion of PCS coated steel was very small. In the acceleration test for carbonation, increasing the amount of NaCl the corrosion of coated steel did not produce. The corrosion of uncoated regular steel is increased with the increase in the amount of NaCl. It can be seen that the NaCl following the acceleration test for carbonation can lower the corrosion resistance of concrete. As a result, the corrosion of steel largely is affected by the acceleration curing, chloride ion penetration and carbonation and shown more severe corrosion by applying complex factors. These corrosions of steel can be suppressed by the coating of PCS.

An Experimental Study on the Durability Performance for Ternary Blended Concrete Containing Both Fly Ash and Granulated Blast Furnace Slag (플라이 애시와 고로슬래그 미분말을 복합 활용한 3성분계 혼합 콘크리트의 내구성능에 대한 실험적 연구)

  • Lee, Chang-Soo;Yoon, In-Seok
    • Journal of the Korea institute for structural maintenance and inspection
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    • v.7 no.1
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    • pp.139-145
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    • 2003
  • Ternary blended concrete, which contains both fly ash and granulated blast furnace slag, has an initial cost effective and is environment friendly. Furthermore, it has a lot of technical advantages such as the improvement of long term compressive strength, high workability, and the reduction of hydration heat. However, as the use and study on the performance of ternary blended concrete is limited, it is worthwhile studying the actual performance of this technology. This study examined the durability performance of ternary blended concrete, compared to binary blended concrete and ordinary portland concrete. It led to the conclusion that ternary blended concrete is very suitable for submerged members under marine environment. However, it should be noticed that ternary blended concrete becomes weak on carbonation, when it is situated on combined deterioration environment of carbonation and chloride. Therefore, the curing duration of ternary blended concrete should be prolonged in order to enhance the resistance of carbonation.

Properties of Matrix According to the Replacement Ratio of Portland Cement-based Carbonation Sluge (시멘트 기반 탄화슬러지 치환율에 따른 경화체의 특성)

  • Kang, Yong-Mo;Lee, Hye-Eun;Lee, Sang Soo
    • Proceedings of the Korean Institute of Building Construction Conference
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    • 2021.05a
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    • pp.189-190
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    • 2021
  • Recently, the spread of intense social distancing and untact culture due to COVID-19 has increased the time spent indoors. In addition, according to the International Cancer Institute, fine dust was classified as a first-class carcinogen, a substance found to be carcinogenic, such as asbestos and benzene. As a result, interest in indoor air quality is increasing, and many studies are underway to reduce air pollutants. This study is a basic experiment of a board made to improve indoor air quality. The basic characteristics of the board, flexural strength and compressive strength, are analyzed and the results of the test are as follows. Experiments have shown that flexural strength and compressive strength tend to decrease as the replacement rate of hydrocarbons increases. It is believed that the strength of the sludge has decreased due to the increase in internal voids due to the increase in non-surface area, volume and diameter of microfiber as it undergoes the carbonation process. In addition, it is believed that the amount of moisture needed for curing during the mixing process was reduced due to the absorption of hydrocarbons.

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Studies on Carbonation of Concrete with Low-Calcium Fly Ash and Blast Furnace Slag (플라이 애쉬 및 고로수쇄(高爐水碎)슬래그를 혼화(混和)한 콘크리트의 중성화(中性化)에 관한 연구(研究))

  • Nagataki, Shigeyoshi;Kim, Eun Kyum;Ohga, Hiroyuki
    • KSCE Journal of Civil and Environmental Engineering Research
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    • v.7 no.3
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    • pp.229-240
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    • 1987
  • Carbonation of concrete is one type of a chemical process. The reaction mechanism is very complex for the case when low-calcium fly ash and blast furnace slag is added. When fly ash and blast furnace slag is used as an admixture in concrete, they improve compressive strength in the long term, permeability and chemical resistance of concrete by a pozzolanic reaction and latent hydraulic property. On the other hand, the pozzolanic reaction of fly ash and latent hydraulic property of the blast furance slag leads to a reduction of the alkalinity of the concrete. It has been pointed out that this will accelerate the carbonation of the concrete and the corrosion of reinforcement steel embedded in the concrete. In order to clarify the effect of fly ash and blast furance slag on the carbonation of concrete, an accelerated carbonation testing of concrete was carried out by varying the conditions of concrete and the initial curing period in water. The test results of accelerated carbonation were compared to the carbonation test results of concrete stored for 15 years in open air, but protected from rain. As a result, the equation for the rate of carbonation based on compressive strength of concrete was proposed.

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Carbon-capture Performance of foam Concrete Using Stainless Steel Slag (스테인리스 스틸 AOD 슬래그를 이용한 폼 콘크리트의 탄소포집 성능)

  • Kim, Byung Jun;Yoo, Sung Won;Choi, Young Cheol
    • Journal of the Korea institute for structural maintenance and inspection
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    • v.24 no.4
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    • pp.18-25
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    • 2020
  • The purpose of this study is to investigate the mechanical and carbon-capture properties of foam concrete containing stainless steel argon oxygen decarbonization(AOD) slag. AOD slag was used as a binder, and foam concrete having a foaming ratio of 69 ± 0.5 % and a slurry density of 573.2 to 578.6 kg / ㎥ was produced. In order to examine the effect of carbonation, blended specimen was cured by two types : normal curing and CO2 curing. As a result of the experiment, the specimens incorporating AOD slag showed higher compressive strength than Plain after CO2 curing. According to the analysis of the image of foam concrete, it was confirmed that the ST30 has a lower total pore volume and average pore size than plain, resulting in high compressive strength. The SEM analysis confirmed the formation of calcite by carbonation of AOD slag. Through the thermogravimetric analysis, the increase of CO2 uptake was confirmed by the incorporation of AOD slag. Foam concrete has a higher porosity than normal concrete, so it is expected that carbon-capture performance can be improved by using a AOD slag.

Enhancement of the Strength of MgO-Based Binder by Accelerated Carbonation (촉진탄산염화에 의한 마그네슘계 고화제의 강도 향상 특성)

  • Yun, Do Youn;Ahn, Jun-Young;Kim, Cheolyong;Kim, Tae Yoo;Hwang, Inseong
    • Journal of Soil and Groundwater Environment
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    • v.21 no.6
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    • pp.135-145
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    • 2016
  • MgO recently has been regarded as the alternative material for replacement of cement. The aim of this study is to investigate the effects of accelerated carbonation on the strength development of MgO-based binder which is binary mixtures of magnesium oxide (MgO) with portland cement (PC) or ground granulated blast furnace slag (GGBS) or fly ash (FA). The compressive strengths of all binders were higher in the 20% $CO_2$ condition and for longer curing time. The strength were generally higher as the following order: MgO/PC > MgO/GGBS > MgO/FA system. The binder composed of 20% MgO and 80% PC showed highest compressive strength (38.0MPa) which was higher than PC. The correlation analysis of the porosity and compressive strength showed that compressive strength was higher when porosity was lower. The hydration and carbonation products of MgO including brucite ($Ca(OH)_2$), magnesite ($MgCO_3$) and nesquehonite ($MgCO_3{\cdot}3H_2O$) presumably filled the pores and contributed to strength development. Thermogravimetric analyses elucidated that 0.34 kg of $CO_2$ could be stored the 50% MgO/50% PC binder which performed the maximum $CO_2$ uptake at 20% $CO_2$ condition.