• 도시과학
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• 제9권2호
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• pp.45-50
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• 2020

The formation characteristics of calcium carbonates are closely related to the durability and mechanical properties of cement-based materials. In this regard, a deep understanding of the reaction pathway of calcium carbonates is critical. Recently, non-classical nucleation theory was summarized and it was presumed that prenucleation clusters are present. The formation of the prenucleation cluster at undersaturated condition (≈ 0.1 ml) in the present study was investigated via electrical characteristics of an electrolytic solution. Calcium chloride dihydrate (CaCl2·2H2O) and sodium carbonate (Na2CO3) were used as starting materials to supply calcium and carbonate sources, respectively. Furthermore, the reaction pathway of calcium carbonates was investigated by time-resolved polarization and depolarization characteristics of the electrolytic solution. The time-resolved polarization and depolarization tests were conducted by switching polarity with an interval of 20 seconds for 1 hr and by measuring the variation of electrical resistance. It can be inferred from the results obtained in the present study that the reactive constituent for the formation of calcium carbonates was mostly consumed in the period possibly associated with the prenucleation and the reaction pathways may be governed by the monomer-addition mechanism.

• 한국산업보건학회지
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• 제33권4호
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• pp.455-463
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• 2023

Objectives: The aim of this study was to develop an air sampling and analytical method for estimating worker exposure to linear carbonate solvents and to evaluate the method. Methods: The target substances were three linear carbonates: DMC, DEC, EMC. GC/FID was used for sample analysis. Laboratory experiments were conducted to determine desorption solvents and sample capacity, and to evaluate storage stability, accuracy, and precision. Results: Coconut Shell Charcoal (CSC, 100/50 mg) was used as the air sampling media, and a desorption solvent of 5% methanol/95% dichloromethane was selected. Recommended sampling capacities were 1~11 ℓ for DMC, 1~18 ℓ for DEC, and 1~24 ℓ for EMC. The stability of three linear carbonates was demonstrated over 30 days in a refrigerator (4℃). Detection limits were determined as follows: DMC 0.26 ㎍/sample, DEC 0.24 ㎍/sample, and EMC 0.25 ㎍/sample. The total coefficient of variation was calculated as DMC 0.064, DEC 0.079, and EMC 0.07. Conclusions: This sampling and analysis method is suitable for estimating personal exposure to linear carbonates in the workplace.

• 한국세라믹학회지
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• 제44권8호
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• pp.424-429
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• 2007

Novel conductive $CO_2$ membranes composed of dual phases, molten carbonates and electronic conducting ceramics, were investigated. As the microstructure control of electronic conducting ceramic supports is extremely important to keep the molten carbonates stable in the membranes by a capillary force applied by the pore structure of the supports, we have scrutinized the microstructure of the electronic conducting supports utilizing microscopic images and gas permeability measurement. From the evaluation of the electrical conductivities of the molten carbonates and the electronic conducting ceramic supports, we found that the ionic conductivity of the molten carbonates could determine $CO_2$ flux through the dual phase membranes if the surface exchange rate were relatively high enough.

• Bulletin of the Korean Chemical Society
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• 제30권11호
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• pp.2567-2573
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• 2009

Carbonation of $Mg(OH)_2$ at 300 ${^{\circ}C}$ was studied by Infrared spectroscopy. Dehydroxylation and carbonation reactions were carried out in consecutive manner via 2-step procedure. Unidentate carbonates were produced only on defective surface of MgO in situ generated by dehydroxylation of $Mg(OH)_2$$Mg(OH)_2$${^{\circ}C}$ was proposed.

• Geosciences Journal
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• 제22권6호
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• pp.975-987
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• 2018

Stable isotope ratios of $^{18}O/^{16}O$ and $^{13}C/^{12}C$ and rare earth elements geochemistry of the Upper Triassic carbonates from the Baluti Formation in Kurdistan Region of Northern Iraq were studied in two areas, Sararu and Sarki. The aim of the study is to quantify the possible diagenetic processes that postdated deposition and the paleoenvironment of the Baluti Formation. The replacement products of the skeletal grains by selective dissolution and neomorphism probably by meteoric water preserved the original marine isotopic signatures possibly due to the closed system. The petrographic study revealed the existence of foraminifers, echinoderms, gastropods, crinoids, nodosaria and ostracods as major framework constituents. The carbonates have micritic matrix with microsparite and sparry calcite filling the pores and voids. The range and average values for twelve carbonate rocks of ${\delta}^{18}O$ and ${\delta}^{13}C$ in Sararu section were -5.3‰ to -3.16‰ (-4.12‰) and -2.94‰ to -0.96‰ (-1.75‰), respectively; while the corresponding values for the Sarki section were -3.69‰ to -0.39‰ (-2.08‰) and -5.34‰ to -2.70‰ (-4.02‰), respectively. The bivariate plot of ${\delta}^{18}O$ and ${\delta}^{13}C$ suggests that most of these carbonates are warm-water skeletons and have meteoric cement. The average ${\Sigma}REE$ content and Eu-anomaly of the carbonates of Sararu sections were 44.26 ppm and 1.03, respectively, corresponding to 22.30 ppm and 0.93 for the Sarki section. The normalized patterns for the carbonate rocks exhibit: (1) non-seawater-like REE patterns, (2) positive Gd anomalies (average = 1.112 for Sararu and 1.114 for Sarki), (3) super chondritic Y/Ho ratio is 31.48 for Sararu and 31.73 for Sarki which are less than the value of seawater. The presence of sparry calcite cement, negative $^{13}C$ and $^{18}O$ isotope values, the positive Eu anomaly in the REE patterns (particularly for Sararu), eliminated Ce anomaly ($Ce/Ce^{\ast}$: 0.916-1.167, average = 0.994 and 0.950-1.010, average = 0.964, respectively), and Er/Nd values propose that these carbonates have undergone meteoric diagenesis. The REE patterns suggest that the terrigenous materials of the Baluti were derived from felsic to intermediate rocks.

• 자원환경지질
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• 제45권4호
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• pp.365-375
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• 2012

이 연구는 캐나다 Core Research Center (CRC) 시추코어 Saleski 03-34-88-20w4와 Saleski 08-01-88-20w4를 이용하여 비투멘을 함유한 캐나다 앨버타주 데본기 탄산염암의 무기 지화학적 특징을 규명하고, 탄산염 저류층에 대한 지화학적 기초자료를 구축하는데 목적이 있다. 대부분이 0.2 mm 이하 크기의 돌로마이트 입자로 구성된 탄산염암은 소량의 석영과 방해석을 포함한다. 두 CRC 코어 탄산염암의 퇴적환경과 돌로마이트화 과정이 유사하나 Saleski 03-34-88-20w4 코어 탄산염암이 Saleski 08-01-88-20w4 코어 탄산염암보다는 쇄설성 퇴적물 유입이 상대적으로 많은 환경에서 형성되었다. 동위원소 분석결과 두 CRC 코어 돌로마이트 생성온도는 약 40~$55^{\circ}C$이고, 돌로마이트 생성 속성수는 데본기 해수이다. 캐나다 앨버타 데본기 Cairn층과 비교한 결과 돌로마이트 생성온도는 같으나, Cairn층은 약간의 대륙기원 암석과 반응한 속성수가 해수에 혼합되었을 가능성이 있다.

• 한국지반공학회:학술대회논문집
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• 한국지반공학회 2009년도 춘계 학술발표회
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• pp.993-998
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• 2009

This study was conducted to propose the model that is able to predict long-term settlement of sands containing carbonates. We can observe that in addition to the initial elastic compression, a considerable additional compression occurs with long-term period in some sands. The compressibility of sands is significantly dependent on particle characteristics. Some sands have many pores and particularly has an angular shape. To predict of long-term settlement of these sands which contain carbonates, first of all a variety of tests which are to assess chemical, physical and compression characteristics of these sands were conducted. Second, in order to know settlement with time, the time parameter was determined by analyzing the measured data obtained from $\bigcirc\bigcirc$ area. The measured settlement of this area shows that in addition to the initial elastic compression, a considerable additional compression occurring with time. It was caused by the crushing, shattering, and rearrangement of particles, which were real phenomena in sandy soils under loading condition. Based on this case study, we proposed that a simple method is able to predict settlement with time of sandy soil containing carbonates.

• Journal of the korean society of oceanography
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• 제34권3호
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• pp.144-150
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• 1999

Slope sedimentation on the modern west Florida continental margin is controlled by pelagic carbonate accumulation and off-shelf sedimentation of neritic carbonates and terrigenous fines. Production and deposition of pelagic carbonates by planktonic foraminifera and coccoliths have played a significant role in the total slope sedimentation and are mainly promoted by sea-surface productivity. Organic carbon data reflect the relatively high biological productivity in surface waters, indicating high accumulation of biogenic calcareous sediments. The surface-water productivity in the study area is supported by the relation among microfossil assemblages, carbonate mineralogy and sedimentary organic carbon.

• Bulletin of the Korean Chemical Society
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• 제33권12호
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• pp.4150-4154
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• 2012

Efficient synthesis of ${\alpha}$-chloroenones bearing ${\beta}$-carbonates or ${\beta}$-carbamates was achieved by rhodium(II)-catalyzed reaction of cyclic diazodicarbonyl compounds with a variety of chloroformates or carbamyl chlorides in good yields. These reactions provided a useful and rapid route to ${\beta}$-substituted ${\alpha}$-haloenones.

• 한국지반공학회:학술대회논문집
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• 한국지반공학회 2010년도 추계 학술발표회
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• pp.790-799
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• 2010

The Upper Devonian Grossmont Formation in Alberta, Canada reserves an estimated 50 billion cubic meters of bitumen and possess about 1/6 of the total bitumen resources in northern Alberta. However, unlike the overlying Athabasca oil sands, non conventional bitumen resources has not been developed as yet. The carbonate rocks of Grosmont Formation have been subject to various stages of diagenesis, including dolomatization and karstification with a strong effect on the distribution of porosity and permeability, which resulted in highly heterogeneous reservoirs. An extensive fracture logging and mapping was performed on total of six boreholes located in the study area to explore the characteristics of fracture geometry system and the subsurface structures of carbonates reservoir that holds bitumen. Fractal dimension was used as a measure of the statistical homogeneity of the fractured rock masses. The applicability of random Cantor dust, Dc, as a fractal parameter was examined systematically. The statistical homogeneity of fractured carbonates rock masses was investigated in the study area. The structural domains of the rock masses were delineated depthwise according to estimated Dc. The major fracture orientation was dominated by horizontal beddings having dip of $0-20^{\circ}$. Also, fractures having high dip angles existed with relatively low frequency. Three dimensional fracture network modeling for each structural domain has been performed based on fracture orientation and intensity, and some representative conceptual models for carbonates reservoir in the study area has been proposed. The developed subsurface conceptual models will be used to capture the geomechanical characteristics of the carbonates reservoir.