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Geochemical Characteristics of Devonian Bitumen Carbonates in Alberta, Canada

캐나다 데본기 비투멘 탄산염암의 지화학적 특성 연구

  • Kil, Young-Woo (Department of Energy and Resources Engineering, Chonnam National University) ;
  • Kim, Ji-Hoon (Petroleum and Marine Research Division, Korea Institute of Geoscience and Mineral Resources) ;
  • Choi, Ji-Young (Petroleum and Marine Research Division, Korea Institute of Geoscience and Mineral Resources) ;
  • Park, Myong-Ho (E&P Technology Institute, Korea National Oil Corporation)
  • 길영우 (전남대학교 에너지자원공학과) ;
  • 김지훈 (한국지질자원연구원 석유해저연구본부) ;
  • 최지영 (한국지질자원연구원 석유해저연구본부) ;
  • 박명호 (한국석유공사 석유개발연구원)
  • Received : 2012.04.16
  • Accepted : 2012.08.20
  • Published : 2012.08.28

Abstract

The objective of this study is to investigate inorganic characteristics of Devonian bitumen carbonates in Alberta using two drilling cores, Saleski 03-34-88-20w4 and Saleski 08-01-88-20w4, taken from the Core Research Center (CRC) of Canada. The bitumen carbonates are mainly composed of less than 0.2 mm dolomites and some carbonate includes small amount of quartz and calcite. The bitumen carbonates from two cores are interpreted to have formed in similar sedimentary environments and dolomitization processes. Carbonates from Saleski 03-34-88-20w4 core were formed under higher inflow of clastic sediment than those from Saleski 08-01-88-20w4 core. Range of crystallization temperature of dolomites in the both bitumen carbonate cores is about 40~$55^{\circ}C$. Dolomitizing fluid of the bitumen carbonates would be Devonian seawater. Bitumen carbonates from Cairn Formation, compared with the CRC cores, have experienced a similar crystallization temperature, but dolmititizing fluid of the bitumen carbonates from Cairn Formation have been modified from the isotopic exchange with continental crust.

이 연구는 캐나다 Core Research Center (CRC) 시추코어 Saleski 03-34-88-20w4와 Saleski 08-01-88-20w4를 이용하여 비투멘을 함유한 캐나다 앨버타주 데본기 탄산염암의 무기 지화학적 특징을 규명하고, 탄산염 저류층에 대한 지화학적 기초자료를 구축하는데 목적이 있다. 대부분이 0.2 mm 이하 크기의 돌로마이트 입자로 구성된 탄산염암은 소량의 석영과 방해석을 포함한다. 두 CRC 코어 탄산염암의 퇴적환경과 돌로마이트화 과정이 유사하나 Saleski 03-34-88-20w4 코어 탄산염암이 Saleski 08-01-88-20w4 코어 탄산염암보다는 쇄설성 퇴적물 유입이 상대적으로 많은 환경에서 형성되었다. 동위원소 분석결과 두 CRC 코어 돌로마이트 생성온도는 약 40~$55^{\circ}C$이고, 돌로마이트 생성 속성수는 데본기 해수이다. 캐나다 앨버타 데본기 Cairn층과 비교한 결과 돌로마이트 생성온도는 같으나, Cairn층은 약간의 대륙기원 암석과 반응한 속성수가 해수에 혼합되었을 가능성이 있다.

Keywords

References

  1. Al-Asam, I.S., Lonnee, J. and Clarke, J. (2002) Multiple fluid flow events and the formaiton of saddle dolomite: case studies from the Middle Devonian of the Western Canada Sedimentary Basin. Marine and Petroleum Geology, v.19, p.209-217. https://doi.org/10.1016/S0264-8172(02)00013-2
  2. Bachu, S. and Underschults, X. (1993) Hydrogeology of formation waters, northeastern Alberta Basin. AAPG Bull, v.77, p.1745-1768.
  3. Briggs, P.J., Beck, P.L., Black, C.J.J. and Bissell, R. (1988) Development of Heavy-oil Reservoirs. JPT, Feb., p.206-214.
  4. Burke, W.H., Denison, R.F., Hetherington, E.A., Koepnick, R.B., Nelson, H.F. and Otto, J.B. (1982) Variation of sea water $^{87}Sr/^{86}Sr$ throughout Phanerozoic time. Geology, v.10, p.516-519. https://doi.org/10.1130/0091-7613(1982)10<516:VOSSTP>2.0.CO;2
  5. Buschkuehle, B.E., Hein, F.J. and Grobe, M. (2007) An overview of the geology of the Upper Devonian Grosmont carbonate bitumen deposit, northern Alberta. Canada Nat. Resour. Res., v.16, p.3-15. https://doi.org/10.1007/s11053-007-9032-y
  6. Carpenter, S.J., Lohmann, K.C., Holden, P., Walter, L.M., Huston, T.J. and Halliday, A.N. (1991) ${\delta}^{18}O$ values, $^{87}Sr/^{86}Sr$ and Sr/Mg ratios of Late Devonian abiotic marine calcite: implications for the composition of ancient seawater. Geochim. Cosmochim. Acta., v.55, p.1991-2010. https://doi.org/10.1016/0016-7037(91)90038-7
  7. Choi, J., Kim, J.-H., Kil, Y., Lee, S.-D. and Park, M.-H. (2011) Inorganic and Organic Geochemical Characteristics of Devonian Bitumen Carbonate in Alberta, Canada. Econ. Environ. Geol., v.44, p.21-35. https://doi.org/10.9719/EEG.2011.44.1.021
  8. Dembicki, E.A. (1994) The Upper Devonian Grosmont Formation: Well-log evaluation and regional mapping of a heavy oil carbonate reservoir in northeastern, Alberta. MS Thesis, Univ. Alberta, Edmonton, 221p.
  9. Dembicki, E.A. and Machel, H.G. (1996) Recognition and delineation of paleokarst zones by the use of wireline logs in the bitumen-saturated Upper Devonian Grosmont Formation of northeastern Alberta, Canada. AAPG Bull., v.80, p.695-712.
  10. Gunter, W.D., Bachu, S., Buschkuehle, M., Michael, K., Ordorica-Garcia, G. and Hauck, T. (2009) Reduction of GHG emissions by geological storage of $CO_{2}$: Anatomy of the Heartland Aquifer Red water Carbon Capture and Geological Storage Project (HARP), Alberta. Canada. Intern. J. Climate Change Strat. Manage., v.1, p.160-178. https://doi.org/10.1108/17568690910955621
  11. Harrison, R.S. (1982) Geology and production history of the Grosmont carbonate platform pilot project, Alberta: Proc. 2nd Intern. Conf. Heavy Crude and Tar Sands, UNITAR (Caracas, Venezuela), p.12.
  12. Harrison, R.S. and McIntyre, B.G. (1981) The geologic setting of the Grosmont thermal recovery project, northeastern Alberta: Alberta Oil Sands and Technology Research Authority (AOSTRA). Seminar on Advances in Petroleum Recovery and Upgrading Technology, Proc. (Calgary), p.11.
  13. Hein, F.J. (2006) Oil sands and heavy oil in North America: An overview and summary. Nat. Resour. Res., v.15, p.67-84. https://doi.org/10.1007/s11053-006-9016-3
  14. Huebscher, H. (1996) Regional controls on the stratigraphic and diagenetic evolution of the Woodbend group carbonates, north-central Alberta. Ph. D Thesis, Univ. Alberta, Edmonton, p.231.
  15. Hudson, J.D. (1977) Stable isotopes and limestone lithification. Journal of the Geol. Soci. of Lond., v.133, p.637-660. https://doi.org/10.1144/gsjgs.133.6.0637
  16. Hudson, J.D. and Anderson, T.F. (1989) Ocean temperatures and isotopic compositions through time. Transactions of the Royal Society of Edingburgh: Earth Sciences, v.80, p.183-192. https://doi.org/10.1017/S0263593300028625
  17. Kim, J.-H. and Kil, Y. (2009) Bitumen carbonate in the Canada. KIGAM report, p.97.
  18. Kil, Y. and Kim, J.-H. (2010) Bitumen carbonate of CRC core in the Canada. KIGAM report, p.109.
  19. Koster, J., Littke, L. and Machel, H.G. (2008) Devonian carbonates of the Nigel Peak Area, Rocky mountains, Canada: a fossil petroleum system? J. Petro. Geol., v.31, p.283-302. https://doi.org/10.1111/j.1747-5457.2008.00421.x
  20. Land, L.S (1985) The origin of massive dolomite. J. Geol. Education, v.33, p.112-125. https://doi.org/10.5408/0022-1368-33.2.112
  21. Luo, P., Machel, H.G. and Shaw, J. (1994) Petrophysical properties of matrix blocks of a heterogeneous dolostone reservoir-the Upper Devonian Grosmont Formation, Alberta, Canada. Can. Petrol. Geol. Bull., v.42, p.465-481.
  22. Machel, H.G. and Huebscher, H. (2001) The Devonian Grosmont heavy oil reservoir in Alberta, Canada. Zentra. Geol. Paleont. Teil 1, v.1/2, p.5-84.
  23. McKenzie, J. (1981) Holocene dolomitization of calcium carbonate sediments from the coastal sabkhas of Abudhabi, U.A.E.: A stable isotopic study. J. Geol., v.89, p.185-198. https://doi.org/10.1086/628579
  24. Miller, H. and Vandermeer, J. (1980) Grosmont-another energy giant for the future. Can. Soc. Petrol. Geol. Reser., v.7, p.1.
  25. Park, M.-H., Kim, J.-H., Lee, S.-D., Choi, J. and Kil, Y. (2010) Geochemical Characteristics of Devonian Cairn Formation in Alberta, Canada. Econ. Environ. Geol., v.43, p.85-100
  26. Potter, I.J. (2007) Alberta Carbonates: Prime candidate for the 3rd Trillion and beyond. SPE 2007 Research & Development Conference, San Antonio, Texas, USA.
  27. Saller, A.H. (1984) Petrologic and geochemical constrains on the origin of subsurface dolomite, Emewetak Atoll: an example of dolomitization by normal seawater. Geology, v.12, p.217-220. https://doi.org/10.1130/0091-7613(1984)12<217:PAGCOT>2.0.CO;2
  28. Vandeginste, V., Swennen, R., Gleeson, S.A., Ellam, R.M., Osadetz, K., and Roure, F. (2006) Development of secondary porosity in the Fairholme carbonate complex (southwest Alberta, Canada). J. Geochem. Explo., v.89, p.394-397. https://doi.org/10.1016/j.gexplo.2005.11.088
  29. Vandeginste, V., Swennen, R., Gleeson, S.A., Ellam, R.M., Osadetz, K. and Roure, F. (2009) Thermochemical sulphate reduction in the Upper Devonian Cairn Formation of the Fairholme carbonate complex (South-West Alberta, Canadian Rockies): evidence from fluid inclusions and isotopic data. Sedimentology, v.56, p.439-460. https://doi.org/10.1111/j.1365-3091.2008.00978.x
  30. Verma, S.P., Quiroz-Ruiz, A. and Diaz-Gonzalez, L. (2008) Critical values for 33 discordancy test variants for outliers in normal samples up to sizes 1000, and applications in quality control in Earth Sciences: Revista Mexicana de Ciencias Geologica, v.25, p.82-96.

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