• Title/Summary/Keyword: carbonate content

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Calcium Ionization Characteristics and In vitro Bioavailability Derived from Natural Calcium Sources (천연칼슘소재의 이온화 특성 및 In vitro 칼슘 이용률)

  • Jang, Se-Young;Jeong, Yong-Jin
    • Journal of the Korean Society of Food Science and Nutrition
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    • v.42 no.4
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    • pp.497-504
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    • 2013
  • This study examined the characteristics of ionized calcium and in vitro calcium bioavailability rate of calcium from four natural sources: shellfish shell, oyster shell, starfish, egg shell. The levels of dissolved calcium and calcium ions increased at different concentrations of natural calcium (up to 8.0% (w/v)). However, there were insignificant differences in the levels of dissolved calcium and calcium ions between samples at calcium concentrations above 8.0% (w/v). In addition, no significant differences were observed (depending on the calcium source and concentration) with an ionization yield of about 90%. The temperature of the solutions also had little influence on the ionization of calcium. The highest calcium ion content was observed when solutions were left to dissolve calcium for 18 hours. The highest in vitro calcium bioavailability rate achieved among the different calcium solutions was BS (67.3%), with overall bioavailability rates about two times higher than the rates observed in commercially sold calcium supplements and natural calcium. In addition, the in vitro calcium bioavailability rate for ionized calcium in market milk, soy milk, and orange juice was more than twice as high as calcium carbonate. Overall, we expect a high and diverse bioavailability of ionized calcium from natural resources.

Geochemical Characteristics of Surface Sediments in the Eastern Part of the Yellow Sea and the Korean West Coast (황해 동부 대륙붕과 한반도 서해안 표층퇴적물의 지구화학적 특성)

  • 조영길;이창복;박용안;김대철;강효진
    • The Korean Journal of Quaternary Research
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    • v.7 no.1
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    • pp.69-91
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    • 1993
  • A total of 76 surface sediment samples, collected from the Korean west coast and the eastern Yellow Sea areas, were analyzed for their elemental composition in order to understand the geochemical characteristics of these deposits. The analyzed elements included 9 major elements (Al, Fe, Na, K, Mg, Ca, Ti, P, Mn), 8 minor elements (Sr, Ba, V, Cr, Co, Ni, Cu, Zn), organic carbon and calcium carbonate. Contents of most analyzed elements, excluding K and Ba, were generally low compared to those of average crust. Contents of most elements, except K and Ca, also correlated with sediment grain size, though the degree of relationship varied widely from one element to another. For fine-grained sediments, a distinction could be made between those in the central Yellow Sea and those in the Keum Estuary based on their characteristic elemental composition: the former were rich in Fe, Na, K, Mg, Ca and V, and the latter in Mn, Co and Ni. The element/aluminium ratios, on the other hand, showed that the central Yellow Sea muds were enriched in Fe, Mg, V, Ni, Cu and Zn and depleted in K, Mn, Ba and Sr relative to the mud located near the Korean Peninsula. Based on the analysis of these results, as well as of the influences of particular mineral phases or pollution effects, we could suggest geochemical criteria which can be used in distinguishing muds from the two different sources, the Keum River and the Yellow River: the former by the higher Mn content and the latter by the higher Mg and V contents, relative to each other.

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A study on the Mineral Contents of Korea Common Foods and Analytical Methods. 2. Potassium (한국인의 상용식품 중 무기질 함량과 분석방법 비교 연구 2. 칼륨)

  • 송범호;황성희;이주돈;김희재;정해랑;문현경
    • Journal of Food Hygiene and Safety
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    • v.7 no.1
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    • pp.37-44
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    • 1992
  • In order to observe the K contents, Korean common foods, especially processed foods were analyzed by Atomic Absorption Spectrophotometer. The results obtained were summarized as followed; (I) The K contents of instant noodle(ramyon) was 105-180 mg/100g and K ontents of their soup powder was 500-1000 mg/100g. (2) The K contents of potato products and bean products were less than those of original foods. So it was recongnized that the K contents might reduced during the food process. (3) The K contents of meats was 130-475 mg/I00g and those of meats products was relatively low, 80-260 mg/100g. (4) The K contents of carbonate beverage was very low but that of instant coffed was very high, 2400-2600 mg/100g. (5) There was no Statistical difference between the results of wet ash method and dry ash method in the K contents of all food groups.

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A Study on the Waste Treatment from a Nuclear Fuel Powder Conversion Plant (핵연료 분말제조 공정에서 발생하는 폐액의 처리에 관한 연구)

  • Jeong, Kyung-Chai;Kim, Tae-Joon;Choi, Jong-Hyun;Park, Jin-Ho;Hwang, Seong-Tae
    • Applied Chemistry for Engineering
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    • v.7 no.6
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    • pp.1164-1173
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    • 1996
  • Treating methods and characteristics of waste from a nuclear fuel powder conversion plant were studied. To recovery or treat a trace uranium in liquid waste, the ammonium uranyl carbonate(AUC) filtrate must be heated for $CO_2$ expelling, essentially. Uranium content of final treated waste solution from fuel powder processes for a heavy water reactor(HWR) could be lowered to 1 ppm by the lime treatment after the ammonium di-uranate(ADU) precipitation by simple heating. Otherwise, in case of the waste from fuel powder processes for a pressurized light water reactor(PWR), it is result in 0.8 ppm as a form of uranium peroxide such as $UO_4{\cdot}2NH_4F$ compounds. Optimum condition was found at $101^{\circ}C$ by the simple heating method in case of HWR powder process waste. And in case of PWR powder process waste, optimum condition could be obtained by precipitating with adding hydrogen peroxide and adjusting at pH 9.5 with ammonia gas at $60^{\circ}C$ after heating the waste In order to expelling $CO_2$. As the characteristics of recovered uranium compounds, median particle size of ADU was increased with pH increasing in case of HWP waste. Also, in case of uranium proxide compound recovered from PWR waste, the property of $U_3O_8$ power obtained after thermal treatment in air atmosphere was similar to that of the powder prepared from AUC conversion plant.

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Sedimentary Facies and Environmental Changes of the Nakdong River Estuary and Adjacent Coastal Area (낙동강 하구와 주변 연안역의 표층 퇴적상 및 퇴적환경 변화)

  • KIM Seok-Yun;HA Jeong-Su
    • Korean Journal of Fisheries and Aquatic Sciences
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    • v.34 no.3
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    • pp.268-278
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    • 2001
  • To investigate sedimentary facies and environmental changes of the Nakdong River Estuary and its adjacent coastal area, the grain size analysis and measurement of organic matter, calcium carbonate, clay mineral and metallic elements were carried out for forty surface sediment samples. Based on regional distribution pattern and characteristics of the surface sediments, sedimentary facies in the study area can be divided into sand facies (TYPE I), mud facies (TYPE II) and sand-mud mixed facies (TYPE III). TYPE III is the transition of TYPE I and TYPE II in every aspects of sediment characteristics. It suggests that TYPE III may have been formed by the mixture of two different source of sediment : one derived from Nakdong River and the other resuspended fine-grained sediments from the Jinhae Bay by winnowing action during floods or storms. Among many aspects of environmental change after the construction of the Nakdong Barrage, the most significant is the increase of sand content off the sand barrier region. It could be explained by several reasons including decreased input of fine-grained sediment from river, increased hydrodynamic energy level off the sand barrier region and artificial effects such as dredging and dumping.

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Physical and Mechanical Properties of Polymer Concrete Using Recycled Aggregate (재생골재를 사용한 폴리머 콘크리트의 물리·역학적 특성)

  • Sung, Chan-Yong;Baek, Seung-Chul
    • Korean Journal of Agricultural Science
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    • v.32 no.1
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    • pp.19-27
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    • 2005
  • This study was performed to evaluate the physical and mechanical properties of polymer concrete using unsaturated polyester resin, initiator, heavy calcium carbonate, crushed gravel, recycled coarse aggregate, silica sand and recycled fine aggregate. The unit weight, compressive strength, flexural strength and dynamic modulus of elasticity were decreased with increasing the content of recycled aggregate. The unit weight, compressive strength, flexural strength and dynamic modulus of elasticity were showed in $2,127{\sim}2,239kg/m^3$, 80.5~88.3MPa, 19.2~21.5MPa and $254{\times}10^2{\sim}288{\times}10^2MPa$ at the curing age 7 days, respectively. Therefore, these recycled aggregate can be used for polymer concrete.

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Mineralogy of Cu-Co Ores from Democratic Republic of Congo (콩고민주공화국 동-코발트 광석의 광물학적 특정)

  • Cho, Hyen-Goo;Seo, Hye-Min;Kim, Soon-Oh;Kim, Young-Ho;Kim, Sang-Bae
    • Journal of the Mineralogical Society of Korea
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    • v.23 no.4
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    • pp.305-313
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    • 2010
  • Mineralogical characteristics of Cu-Co ores from the Central African Copperbelt in the Democratic Repblic of Congo are studied using powder X-ray diffractometer, general area detector X-ray diffractometer, and electron proble microanalyzer. Black ores are mainly composed of heterogenite (cobalt oxide/hydroxide mineral) and malachite (copper carbonate mineral), whereas green ores are only composed of malachite. Heterogenite shows very bright white color under the reflected microscope, and belongs to 3R polytype, because it has d-spacings at $4.39{\AA}$ and $2.316{\AA}$. Since NiO and $Fe_20_3$ content of heterogenite are lower than those of 3R polytype from other localities, it cannot completely exclude the presence of 2H polytype in heterogenite from this study. Malachite is light grey color under the reflected microscope with approximate chemical formula of $Cu_{1.97}Co_{0.02}Fe^{2+}{_{0.01}}CO_3(OH)_2$. Heterogenite and malachite were probably formed at the supergene emichment stage, the last mineralization stage in the Central African Copperbelt. Cobalt seems to be much more emiched in the black supergene (oxy)hydroxide ore than those in the primary sulfide ore.

The Base Catalyzed Synthesis of Sucrose Ester Containing Omega-3 Fatty Acids (오메가 3 지방산을 함유한 Sucrose Ester의 합성)

  • Shin, Jung-Ah;Jang, Ji-Sun;Hong, Jang-Hwan;Lee, Ki-Teak
    • Journal of the Korean Society of Food Science and Nutrition
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    • v.35 no.9
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    • pp.1224-1231
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    • 2006
  • Sucrose esters were synthesized by transesterification of sucrose with docosahexaenoic acid ethylester mixture (DHAEE). Potassium carbonate as a base catalyst was used in the presence of dimethylsulfoxide (DMSO) for the reactions. The reactions were performed with the different reaction times and molar ratios of substrates in the presence of surfactant in vacuum. Among the reaction conditions in this study, SE#4~7 showed the relatively high conversion rate (>96%) of DHAEE, leading to the high yield of sucrose esters. In addition, the product composition was changed from sucrose mono ester to di/tri/polyesters after the prolonged reaction time while the increased molar ratio of DHAEE also resulted in the composition changes of sucrose mono ester to the sucrose di/tri/polyesters. From the reaction (SE#7), conversion ratio was 98.5% in which 87.3% mono ester and 13.7% di/tri/polyester were found, resulting in the highest content of mono ester. Therefore, the sucrose ester containing various rates of mono and di/tri/polyesters, which effects on hydrophilic lipophilic balance (HLB) values, can be manipulatively synthesized using the reaction conditions reported in this study.

A Study on Synthesis of CaCO3 & MgO/Mg(OH)2 from Dolomite Using the Strong Acidic Cation Exchange Resin (강산성 양이온 교환수지를 통한 백운석으로부터 CaCO3 및 MgO/Mg(OH)2 합성에 관한 연구)

  • Hwang, Dae Ju;Yu, Young Hwan
    • Korean Chemical Engineering Research
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    • v.57 no.6
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    • pp.812-825
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    • 2019
  • Two dolomite samples mined from the different mines were calcined using a batch-type microwave kiln ($950/60min^{\circ}C$) to produce $CaO{\cdot}MgO$. The hydration of the $CaO{\cdot}MgO$ samples shows different reactivity. MgO was separated by reacting with a strong acid cation exchange resin using the reactivity of the hydration properties of light dolomite ($CaO{\cdot}MgO$). Calcium ($Ca-(R-SO_3)_2$) was separated from the prepared $CaO{\cdot}MgO$ by the cation exchange resin ($CaO{\cdot}MgO:R-SO_3H=1:12mass%$). High purity MgO (higher than 94 mass %) with unburned $CaCO_3$ (1~2 mass %) was obtained by the separation process. The separated MgO was heated at $950^{\circ}C$ for 60 minutes to afford high purity MgO with MgO content higher than 96%. And High-grade $CaCO_3$ was prepared from the reaction with calcium adsorbed resin ($Ca-(R-SO_3)_2$) and NaOH, $CO_2$ gas.

Biochemical and cultural characteristics of mineral-solubilizing Acinetobacter sp. DDP346 (미네랄 가용화능을 갖는 Acinetobacter sp. DDP346의 생화학적 및 배양학적 특성)

  • Kim, Hee Sook;Lee, Song Min;Oh, Ka-Yoon;Kim, Ji-Youn;Lee, Kwang Hui;Lee, Sang-Hyeon;Jang, Jeong Su
    • Journal of Applied Biological Chemistry
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    • v.64 no.4
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    • pp.333-341
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    • 2021
  • In this study, to select strains suitable as microbial agent from among rhizosphere microorganisms present in rhizosphere soil and roots, the mineral solubilization ability, antifungal activity against 10 types of plant pathogenic fungi, and plant growth-promoting activity of rhizosphere microorganisms were evaluated. As a result, DDP346 was selected because it has solubilization ability of phosphoric acid, calcium carbonate, silicon, and zinc; nitrogen fixing ability; production ability of siderophore, indole-3-acetic acid, and aminocyclopropane-1-carboxylate deaminase; and antifungal activity against seven types of plant pathogenic fungi. DDP346 showed a 99.9% homology with Acinetobacter pittii DSM 21653 (NR_117621.1); phylogenetic analysis also revealed a close relationship with Acinetobacter pittii based on the 16S rRNA base sequence. The growth conditions of DDP346 were identified as temperatures in the range of 10-40 ℃, pH in the range of 5-11, and salt concentrations in the range of 0-5%. In addition, a negative correlation coefficient (r2 = -0.913, p <0.01) was shown between pH change and the solubilized phosphoric acid content of Acinetobacter sp. DDP346, and this is assumed to be due to the organic acid generated during culture. Consequently, through the evaluation of its mineral solubilization ability, antifungal activity against plant pathogenic fungi, and plant growth-promoting activity, the potential for the utilization of Acinetobacter sp. DDP346 as a multi-purpose microbial agent is presented.