• 동력기계공학회지
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• 제10권3호
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• pp.5-10
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• 2006

In a conventional and lean operating engine, the state of mixture is very important in the combustion and emission characteristics. Lean operation is known to decrease the formation while maintaining a good fuel economy, but the unstable operation due to misfire and erratic combustion prevents engines from being operated at very lean mixtures, so both combustion rates and exhaust emission formation need to be satisfied comparably. In this study, it is designed and experimented the modified engine, and analyzed the combustion and exhaust emission according to the change of engine speed and with adding ozone. The conclusions were drawn out and enumerated as follows. 1. At the experimental result of automobile diesel engine, it has been verified that the formation of particulate matter(PM) gas is able to be lower with the addition of optimum quantities of ozone. 2. Carbon monoxide(CO) was formed by the lack of oxygen and the thermal dissociation in the combustion process. Therefore, with the change of swirl valve's position and addition of oxygen and ozone, CO formation was decreased by the increasing of excessive O2, but it was increased by the temperature of combustion gas growing higher. As a result of the two effects, CO formation was decreased in this study. 3. Hydrocarbon(HC) was formed by the lack of O2, and the flow of mixture in cylinder. According to opening of the swirl valve and adding the oxygen and ozone, hydrocarbon gas was decreased by 20%, 9%, and 27.5%, respectively. 4. Nitric oxides($NO_x$) was strongly affected by the combustion gas temperature. As a result of respectively experimental conditions, $NO_x$ formation was increased about 20% due to (be the) high(er) combustion gas temperature.

• 상하수도학회지
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• 제32권1호
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• pp.55-65
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• 2018

It is necessary to develop a mobile water production system in order to provide stable water supply in case of disasters such as floods or earthquakes. In this study, we developed a modular mobile water production system capable of producing water for various uses such as domestic water and drinking water while improving applicability in various raw water sources. The water production system consists of three stages of filtration (sand filtration - activated carbon filtration - pressure filtration) to produce domestic water and an additional reverse osmosis process to produce drinking water. In laboratory and field experiments, the domestic water production system showed excellent treatment efficiency for particulate matter, but showed limitations in the treatment of dissolved substances such as dissolved organic matter. In addition, ultraviolet irradiation was considered as additional disinfection step, because it does not form precipitates of manganese oxides after disinfection. Reverse osmosis process was added to increase the removal efficiency of dissolved substances and the treated water satisfied drinking water quality standards. Fluorescence analysis of dissolved organic matter showed that the fulvic acid-like substances in raw water was successfully removed in the reverse osmosis process. The mobile water production system developed in this study is expected to be used not only in water supply in case of disaster, but also widely used in islands and rural area.

• 한국세라믹학회지
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• 제47권6호
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• pp.583-589
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• 2010

In this paper, the properties of reclaimed ash(RA) from various domestic thermal power plants(S, D and H) were analyzed, and the possibility of fabricating the artificial lightweight aggregate(ALA) using RA was studied. The chemical compositions of RA are similar to the clay, but it had higher concentrations of alkali earth metal oxides(CaO, MgO) and unburned-carbon. The TCLP(Toxicity Characteristic Leaching Procedure) results showed that the dissolution concentrations of heavy metal ions of RA were below the limitation defined by the enforcement regulation of wastes management law in Korea. The results of IC analysis showed that leaching concentration of $Cl^-$ ion was 124 ppm for RA of HN and ${SO_4}^{2-}$ ion was leached a few hundreds ppm for all RA in this study. The ALAs with various mass ratio of clay to reclaimed ash(RA:Clay = 7:3, 6:4, 5:5, 4:6, 3:7) were sintered with a electric muffle furnace at the temperature of $1050{\sim}1200^{\circ}C$. The specific gravity and water absorption(%) of the sintered ALAs were 1.1~1.8 and 10~30% respectively. The ALA sintered in the rotary kiln at $1125^{\circ}C$ showed a bulk density of 1.7 and water absorption of 15.2%.

• Journal of Electrochemical Science and Technology
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• 제8권3호
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• pp.183-196
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• 2017

The research efforts directed at advancing water electrolysis technology continue to intensify together with the increasing interest in hydrogen as an alternative source of energy to fossil fuels. Among the various water electrolysis systems reported to date, systems employing a solid polymer electrolyte membrane are known to display both improved safety and efficiency as a result of enhanced separation of products: hydrogen and oxygen. Conducting water electrolysis in an alkaline medium lowers the system cost by allowing non-platinum group metals to be used as catalysts for the complex multi-electron transfer reactions involved in water electrolysis, namely the hydrogen and oxygen evolution reactions (HER and OER, respectively). We briefly review the anion exchange membranes (AEMs) and electrocatalysts developed and applied thus far in alkaline AEM water electrolysis (AEMWE) devices. Testing the developed components in AEMWE cells is a key step in maximizing the device performance since cell performance depends strongly on the structure of the electrodes containing the HER and OER catalysts and the polymer membrane under specific cell operating conditions. In this review, we discuss the properties of reported AEMs that have been used to fabricate membrane-electrode assemblies for AEMWE cells, including membranes based on polysulfone, poly(2,6-dimethyl-p-phylene) oxide, polybenzimidazole, and inorganic composite materials. The activities and stabilities of tertiary metal oxides, metal carbon composites, and ultra-low Pt-loading electrodes toward OER and HER in AEMWE cells are also described.

• Journal of Electrochemical Science and Technology
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• 제11권4호
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• pp.384-391
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• 2020

Due to its characteristics of light weight, high energy density, good safety, long service life, no memory effect, and environmental friendliness, lithium-ion batteries (LIBs) are widely used in various portable electronic products. The capacity and performance of LIBs largely depend on the performance of electrode materials. Therefore, the development of better positive and negative materials is the focus of current research. The application of metal organic framework materials (MOFs) derivatives in energy storage has attracted much attention and research. Using MOFs as precursors, porous metal oxides and porous carbon materials with controllable structure can be obtained. In this paper, rod-shaped Co-MOF-74 was grown on Ni Foam (NF) by hydrothermal method, and then Co-MOF-74/NF precursor was heat-treated to obtain rodshaped Co₃O₄/NF. Ni Foam was skeleton structured, which effectively relieved. The change of internal stress changes and destroys the structural volume of the electrode material and reduces the capacity attenuation. Co₃O₄/NF composite material has a specific discharge capacity of up to 1858 mA h/g for the first time, and a reversible capacity of up to 902.4 mA h/g at a current density of 200 mA/g, and has excellent rate and impedance performance. The synthesis strategy reported in this article opens the way to design high-performance electrodes for energy storage and electrochemical catalysis.

• 대한기계학회논문집B
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• 제39권7호
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• pp.609-615
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• 2015

본 연구는 직접분사식 가솔린엔진에서 공기 과잉률 및 바이오에탄올-가솔린 혼합연료의 혼합비에 따른 연소특성과 배기배출물 특성을 실험적으로 규명한 것이다. 다양한 공기 과잉률 및 혼합비 조건에서 실험을 수행하였으며, 연소실 압력, 열발생률, 연료소비율 등을 통해 연소특성을 분석하였으며, 배기배출물 특성은 미연탄화수소(HC), 일산화탄소(CO), 질소산화물($NO_x$) 분석을 통해 확인하였다. 혼합연료의 실험결과는 100% 가솔린 및 바이오에탄올 실험결과와 비교하였다. 실험결과 최고연소압력과 열발생률, 제동연료소비율은 혼합비의 증가에 따라 증가하였으며, CO, HC, $NO_x$와 같은 배기배출물은 바이오 에탄올 혼합비율이 증가함에 따라 감소하였다. 혼합연료의 배기배출물 수준은 가솔린 보다 낮게 나타났다.

• 대한기계학회논문집B
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• 제36권5호
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• pp.539-543
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• 2012

셀룰로오스 EAPap 작동기는 생체 모방형 작동기의 하나로 생체적합하고 가볍고 비교적 낮은 전압에서도 큰 변위를 발생시킨다는 장점을 가지고 있다. 셀룰로오스를 재생하면서 셀룰로오스 파이버를 배열함으로써 압전 종이를 만들었다. 한편 셀룰로오스에 탄소나노튜브, 산화금속 나노분말, 전도성 고분자, 이온성 유체등을 물리적, 화학적으로 결합시켜 다양한 하이브리드 나노복합재를 만들었다. 본 논문에서는 셀룰로오스 EAPap 의 제조공정 및 이를 응용한 바이오센서, 화학센서, 유연트랜지스터, 그리고 작동기의 응용 디바이스에 대해 소개한다. 또한 셀룰로오스 EAPap 을 무선으로 구동하는 기술에 대해 소개한다. 이는 생체모방로봇, 정찰 등에 활용될 수 있다.

• 해양환경안전학회:학술대회논문집
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• 해양환경안전학회 2007년도 추계학술발표회
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• pp.133-137
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• 2007

An experimental study is conducted to evaluate and compare the use of BiodieseDI Fuel supplements at blend ratio of 10/90(BDF10) and 20/80(BDF20), in four stroke, direct injection diesel engine located at the authors' laboratory. especially this Biodiesel is produced from Rape oil at the authors' laboratory. The tests are conducted using each of the above fuel blends, in the engine working at a speed of 1800rpm and at a various loads. In each test, specific fuel consumption, exhaust emissions such as nitrogen oxides(NOx), carbon monoxide(CO) and Soot are measured. The results of investigation at various operating conditions are as follows (1) Specific fuel consumption is increased average 1.52%, maximum 1.84% at load 25% in case of BDF10, and average 1.98%, maximum 2.80% at load 25% in case of BDF20. (2) CO emission is decreased average 5.14%, maximum 6.09% at load 0% in case of BDF10, and average 7.75%, maximum 9.13% at load 0% in case of BDF 20. (3) NOx emission is increased average 2.97%, maximum 3.74% at load 0% in case of BDF10, and average 3.84%, maximum 4.67% at load 0% in case of BDF20. (4) Soot emission is decreased average 9.36%, maximum 10.85% at load 75% in case of BDF10, and average 11.99%, maximum 13.95% at load 75% in case of BDF20.

• 대한화학회지
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• 제22권5호
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• pp.289-294
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• 1978

흑연과 산화알루미늄(Alucer) 표면에 흡착된 벤젠이나 p-크실렌분자가 submonolayer 영역에서 어떤 흡착상태를 이루고 있는가를 이론적으로 살펴보기 위하여, 이들 흡착질 분자를 2차원 기체와 조화진동자의 두가지 모형으로 가정하고 통계열역학적으로 흡착엔트로피를 계산하여 실험치와 비교하였다. 그 결과 벤젠은 흑연표면에서 조화진동 운동을 하며, 산화알루미늄 표면에서는 비편재된 상태에 있다는 것을 알게 되었다. 흡착제 표면에서 흡착된 분자가 조화진동 운동을 한다고 가정할 경우 조절가능한 파라미터로 도입된 분자진동수는 $10^{11}\;sec^{-1}$로서 대단히 합리적인 값을 얻었다. p-크실렌분자가 흑연이나 산화알루미늄 표면에 흡착될 때는 단분자층이 이루어지기 훨씬 전에 비정상적인 값들이 나타난다.

• 대한전자공학회:학술대회논문집
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• 대한전자공학회 2001년도 The 6th International Symposium of East Asian Resources Recycling Technology
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• pp.409-412
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• 2001

The high purity manganese oxides were made from the dust, generated in AOD process that produces a medium-low carbon ferromanganese and collected in the bag filter. Manganese oxide content in the dust was about 90%, and its phase was confirmed as Mn₃O₄. In the extraction of manganese, because of remaining amorphous MnO₂, the dust was reduced to MnO by roasting with charcoal. The pulp density of the reduced dust can control pH of the solution more than 4 and then Fe ion is precipitated to a ferric hydroxide. Because a ferric hydroxide co precipitates with Si ion etc, Fe, Si ion was removed f개m the solution. Heating made water to be volatized and nitrates was left in reactor Then nitrates were a liquid state and stirring was possible. Among the nitrates in reactor, only the manganese nitrate which have the lowest pyrolysis temperature pyrolyzed into β-MnO₂powder and NO₂(g) at the temperature less than 200℃. When the pyrolysis of manganese nitrate has been completed about 90%, injection of water stopped the pyrolysis. Nitrates of impurity dissolved and the spherical high purity β-MnO₂powders were obtained by filtering and washing. Mn₂O₃or Mn₃O₄ powder could be manufactured from β-MnO₂powder by controlling the heating temperature. Lastly, a manufactured manganese oxide particle has 99.97% purity.