• Carbon letters
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• v.11 no.4
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• pp.325-331
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• 2010

This study investigates the effect of filler content (wt%), presence of interphase and agglomerates on the effective Young's modulus of polypropylene (PP) based nanocomposites reinforced with exfoliated graphite nanoplatelets ($xGnP^{TM}$) and carbon nanotubes (CNTs). The Young's modulus of the composites is determined using tensile testing based on ASTM D638. The reinforcement/polymer interphase is characterized in terms of width and mechanical properties using atomic force microscopy which is also used to investigate the presence and size of agglomerates. It is found that the interphase has an average width of ~30 nm and modulus in the range of 5 to 12 GPa. The Halpin-Tsai micromechanical model is modified to account for the effect of interphase and filler agglomerates and the model predictions for the effective modulus of the composites are compared to the experimental data. The presented results highlight the need of considering various experimentally observed filler characteristics such as agglomerate size and aspect ratio and presence and properties of interphase in the micromechanical models in order to develop better design tools to fabricate multifunctional polymer nanocomposites with engineered properties.

• Transactions on Electrical and Electronic Materials
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• v.10 no.6
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• pp.217-221
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• 2009

The use of the carbon nanotube (CNT) is superior to the general powder state materials in their thermal and chemical properties. Because its ratio of diameter to length (aspect ratio) is very large, it is known to be a type of ideal nano-reinforcement material. Based on this advantage, the existing carbon black of the semiconductive shield materials used in power cables can acquire excellent properties by the use of a small amount of CNTs. Therefore, we fabricated specimens using a solution mixing method. We investigated the thermal properties of the CNT, such as its storage modulus, loss modulus, and its tan delta using a dynamic mechanical analysis 2980. We found that a high thermal resistance level is demonstrated by using a small amount of CNTs. We also investigated the chemical properties of the CNT, such as the oxidation reaction by using Fourier transform infrared spectroscopy (FT-IR) made by Travel IR. In the case of the FT-IR tests, we searched for some degree of oxidation by detecting the carboxyl group (C=O). The results confirm a tendency for a high cross-linking density in a new network in which the CNTs situated between the carbon black constituent molecules show a bond using similar constructive properties.

• Advances in nano research
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• v.16 no.5
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• pp.445-458
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• 2024

The objective of this paper is to present free vibration and static stability analyses of rotating composite beams reinforced with carbon nanotubes (CNTs) under uniform thermal loads. Beam structural equations and CNT-reinforced composite (CNTRC) beam formulations are derived based on Timoshenko beam theory (TBT). The temperature-dependent properties of the beam material, such as the elastic modulus, shear modulus, and material density, are assumed to vary over the thickness according to the rule of mixture. The beam material is modeled as a mixture of single-walled carbon nanotubes (SWCNTs) in an isotropic matrix. The SWCNTs are aligned and distributed in the isotropic matrix with different patterns of reinforcement, namely the UD (uniform), FG-O, FG-V, FG- Λ and FG-X distributions, where FG-V and FG- Λ are asymmetric patterns. Numerical examples are presented to illustrate the effects of several essential parameters, including the rotational speed, hub radius, effective material properties, slenderness ratio, boundary conditions, thermal force, and moments due to temperature variation. To the best of the authors' knowledge, this study represents the first attempt at the finite element modeling of rotating CNTRC Timoshenko beams under a thermal environment. The results are presented in tables and figures for both symmetric and asymmetric distribution patterns, and can be used as benchmarks for further validation.

• Fibers and Polymers
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• v.3 no.4
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• pp.134-139
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• 2002

Carbon nanotubes are graphene sheets rolled up in cylinders with diameter as small as 1nm. Extensive work carried out in recent years has revealed the intriguing properties of this novel material. Exceptional property combined with low density of nanotubes makes them suitable for use as reinforcements in composites. Low volume of production and high cost is the main limitations towards their growth and application. Nanofibres bridge the gap between the conventional carbon fibre and the carbon nanotubes. With their low cost & comparatively higher volume of production along with their exceptional properties, the nanofibres are considered attractive material as nanoscale reinforcement. In this article a concise review of structure, property. production and application of carbon nanotubes and nanofibres have been discussed.

• Journal of Powder Materials
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• v.23 no.3
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• pp.213-220
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• 2016

In this study, bulk nickel-carbon nanotube (CNT) nanocomposites are synthesized by a novel method which includes a combination of ultrasonication, electrical explosion of wire in liquid and spark plasma sintering. The mechanical characteristics of the bulk Ni-CNT composites synthesized with CNT contents of 0.7, 1, 3 and 5 wt.% are investigated. X-ray diffraction, optical microscopy and field emission scanning electron microscopy techniques are used to observe the different phases, morphologies and structures of the composite powders as well as the sintered samples. The obtained results reveal that the as-synthesized composite exhibits substantial enhancement in the microhardness and values more than 140 HV are observed. However an empirical reinforcement limit of 3 wt.% is determined for the CNT content, beyond which, there is no significant improvement in the mechanical properties.

• Journal of Welding and Joining
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• v.35 no.3
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• pp.15-20
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• 2017

In this paper, two types of assemblies using CNT-filled SACAs (with 0.03 wt% CNTs and without CNT) were prepared to investigate the influence of carbon nanotubes (CNTs) on the reliability properties of solderable anisotropic conductive adhesives (SACAs) with a low-melting-point alloy (LMPA). Two types of reliability test including thermal shock (TS: -55 to $125^{\circ}C$, 1000 cycles) and high-temperature and high-humidity (HTHH: $85^{\circ}C$, 85% RH, 1000 h) tests were conducted. The SACA assemblies with and without CNTs showed stable electrical reliability properties due to the formation of wide and stable metallurgical interconnection between corresponding metallizations by the molten LMPA fillers. Although the mechanical pull strength of CNT-filled SACA assemblies was decreased after thermal aging (because of the excessive layer growth and planarization of the IMCs), the CNT-filled SACA with 0.03wt% CNTs showed enhanced mechanical reliability properties compared with the SACA assemblies no CNTs. This enhancement in mechanical performance was due to the reinforcement effect of the CNTs. These results demonstrate that CNTs within the CNT-filled SACAs can improve the reliability properties of CNT-filled SACAs joints due to their superior physical properties.

• Structural Engineering and Mechanics
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• v.67 no.2
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• pp.125-130
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• 2018

This study deals with buckling analysis with stretching effect of functionally graded carbon nanotube-reinforced composite beams resting on an elastic foundation. The single-walled carbon nanotubes (SWCNTs) are aligned and distributed in polymeric matrix with different patterns of reinforcement. The material properties of the CNTRC beams are estimated by using the rule of mixture. The significant feature of this model is that, in addition to including the shear deformation effect and stretching effect it deals with only 4 unknowns without including a shear correction factor. The equilibrium equations have been obtained using the principle of virtual displacements. The mathematical models provided in this paper are numerically validated by comparison with some available results. New results of buckling analyses of CNTRC beams based on the present theory with stretching effect is presented and discussed in details. the effects of different parameters of the beam on the buckling responses of CNTRC beam are discussed.

• Steel and Composite Structures
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• v.29 no.3
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• pp.405-422
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• 2018

In this research, experimental tensile test and manufacturing of carbon nanotube reinforced composite beam (CNTRC) is presented. Also, bending, buckling, and vibration analysis of CNTRC based on various beam theories such as Euler-Bernoulli, Timoshenko and Reddy beams are considered. At first, the experimental tensile tests are carried out for CNTRC and composite beams in order to obtain mechanical properties and then using Hamilton's principle the governing equations of motion are derived for Euler Bernoulli, Timoshenko and Reddy theories. The results have a good agreement with the obtained results by similar researches and it is shown that adding just two percent of carbon nanotubes increases dimensionless fundamental frequency and critical buckling load as well as decreases transverse deflection of composite beams. Also, the influences of different manufacturing processes such as hand layup and industrial methods using vacuum pump on composite properties are investigated. In these composite beams, glass fibers used in an epoxy matrix and for producing CNTRC, CNTs are applied as reinforcement particles. Applying two percent of CNTs leads to increase the mechanical properties and increases natural frequencies and critical buckling load and decreases deflection. The obtained natural frequencies and critical buckling load by theoretical method are higher than other methods, because there are some inevitable errors in industrial and hand layup method. Also, the minimum deflection occurs for theoretical methods, in bending analysis. In this study, Young's and shear modulli as well as density are obtained by experimental test and have not been used from the results of other researches. Then the theoretical analysis such as bending, buckling and vibration are considered by using the obtained mechanical properties of this research.

• Computers and Concrete
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• v.34 no.2
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• pp.179-193
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• 2024

The bending and buckling effect for carbon nanotube-reinforced composite (CNTRC) beams can be evaluated by developing the theory of third shear deformation (TSDT). This study examines beams supported by viscoelastic foundations, where single-walled carbon nanotubes (SWCNTs) are dispersed and oriented within a polymer matrix. Four patterns of reinforcement are used for the CNTRC beams. The rule of mixtures is assessed for the material properties of CNTRC beams. The effective functionally graded materials (FGM) properties are studied by considering three different uneven distribution types of porosity. The damping coefficient is considered to investigate the viscosity effect on the foundation in addition to Winkler's and Pasternak's parameters. The accuracy of the current theory is inspected with multiple comparison works. Moreover, the effects of different beam parameters on the CNTRC beam bending and buckling over a viscoelastic foundation are discussed. The results demonstrated that the O-beam is the weakest type of CNTRC beam to resist buckling and flexure loads, whereas the X-beam is the strongest. Moreover, it is indicated that the presence of porosity in the beams decreases the stiffness and increases deflection. In comparison, the deflection was reduced in the presence of a viscoelastic foundation.

• Computers and Concrete
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• v.26 no.3
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• pp.213-226
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• 2020

The present study covenants with the static and free vibration behavior of nanocomposite sandwich plates reinforced by carbon nanotubes resting on Pasternak elastic foundation. Uniformly distributed (UD-CNT) and functionally graded (FG-CNT) distributions of aligned carbon nanotube are considered for two types of sandwich plates such as, the face sheet reinforced and homogeneous core and the homogeneous face sheet and reinforced core. Based on the first shear deformation theory (FSDT), the Hamilton's principle is employed to derive the mathematical models. The obtained solutions are numerically validated by comparison with some available cases in the literature. The elastic foundation model is assumed as one parameter Winkler - Pasternak foundation. A parametric study is conducted to study the effects of aspect ratios, foundation parameters, carbon nanotube volume fraction, types of reinforcement, core-to-face sheet thickness ratio and types of loads acting on the bending and free vibration analyses. It is explicitly shown that the (FG-CNT) face sheet reinforced sandwich plate has a high resistance against deflections compared to other types of reinforcement. It is also revealed that the reduction in the dimensionless natural frequency is most pronounced in core reinforced sandwich plate.