• Applied Chemistry for Engineering
• /
• v.29 no.3
• /
• pp.264-269
• /
• 2018

PSf/D2EHPA/TBP/CNTs beads were prepared by immobilizing carbon nanotubes (CNTs) and two extractants, di-(2-ethylhexyl)-phosphoric acid (D2EHPA) and tributyl phosphate (TBP) on polysulfone (PSf). The prepared PSf/D2EHPA/TBP/CNTs beads were characterized by SEM, TGA, and FTIR. The removal rate of Sr(II) by PSf/D2EHPA/TBP/CNTs beads was well described by the pseudo-second-order kinetic model. The maximum removal capacity of Sr(II) obtained from Langmuir isotherm was found to be 5.52 mg/g. The results showed that the removal efficiency of Sr(II) by PSf/D2EHPA/CNTs beads prepared in this study was significantly improved compared to that of using PSf/D2EHPA/CNTs beads without TBP.

• 한국신재생에너지학회:학술대회논문집
• /
• 2011.05a
• /
• pp.74.1-74.1
• /
• 2011

탄소나노튜브는 높은 전기 전도성과 열 전도성을 가지며, 이러한 특성 때문에 21세기를 주도해 나갈 수 있는 차세대 첨단 소재로서 각광을 받고 있다. 또한 최근에는 나노공학기술의 발달로 인하여 획기적으로 높은 열전도도를 나타내는 다중벽 탄소나노튜브(Multi-walled Carbon Nanotubes, MWCNTs)의 대량 생산이 가능하게 되면서 다중벽 탄소나노튜브의 높은 열전도도 특성을 이용하여 탄소나노튜브를 기본 유체 및 기능성 유체에 안정하게 분산 시킨 후 이를 이용하고자 하는 연구가 활발히 진행되고 있으며, 탄소나노튜브를 유체에 안정하게 분산시키기 위한 방법으로는 기계적 분산법, 물리적 흡착에 의한 분산법, 화학적 개질에 의한 분산법이 있다. 따라서 본 연구에서는 이들 분산 방법과 탄소나노튜브 입자의 물성치에 따른 나노유체의 특성을 알아보기 위하여 나노유체의 열전도도와 점도 특성을 비교 분석하였다. 모든 물성치는 같지만 탄소나노튜브의 길이만 다른 두 종류의 다중벽 탄소나노튜브에 각각 계면 활성제(Sodium Dodecyl Sulfate, SDS) 100 wt%와 고분자 화합물(Polyvinyl Pyrrolidone, PVP) 300 wt%를 첨가하여 나노유체를 제조하였으며, 산화처리 된 다중벽 탄소나노튜브(Oxidized Multi-Walled Carbon Nanotubes, OMWCNTs)를 증류수에 초음파 분산하여 산화나노유체를 제조하였다. 나노유체의 열전도도는 전기 전도성 유체의 비정상 열선법(Transient Hot-wire Method)을 이용하여 측정하였고, 나노유체의 점도는 회전형 디지털 점도계를 이용하여 측정하였다. 실험 결과, 상온에서 동일 혼합비의 나노유체를 비교했을 때, 산화나노유체가 SDS 100 wt%, PVP 300 wt%를 혼합한 다른 나노유체보다 높은 열전도도 특성을 보였으며 점도 특성 또한 가장 낮은 것으로 측정되었다. 특히 상온에서 0.1vol%의 산화 CM-100 나노유체는 증류수보다 열전도도가 8.34%가 증가하였고, $10^{\circ}C$의 저온에서는 상온에서 증류수와 비교하여 측정된 열전도도 값보다 0.36%가 감소한 7.98%가 증가함을 보였다. 본 연구를 통하여 얻어진 결과는 높은 열전도도를 필요로 하는 열교환기의 작동유체나 기타 활용 분야에 대한 기초 자료로써 유용한 정보를 제공할 것이라 판단된다.

• Journal of the Korean Solar Energy Society
• /
• v.29 no.5
• /
• pp.35-44
• /
• 2009

In this study, boiling heat transfer coefficients(HTCs) and critical heat flux(CHF) are measured on a smooth square flat copper heater in a pool of pure water with and without carbon nano tubes(CNTs) dispersed at $60^{\circ}C$. Tested aqueous nanofluids are prepared using multi-walled CNTs whose volume concentrations are 0.0001, 0.001, 0.01, and 0.05%. For dispersion of CNTs, polyvinyl pyrrolidone(PVP) is used in distilled water. Pool boiling HTCs are taken from $10kW/m^2$ to critical heat flux for all nanofluids. Test results show that the pool boiling HTCs of the nanofluids are lower than those of pure water in entire nucleate boiling regime. On the other hand, critical heat flux is enhanced greatly showing up to 200% increase at volume concentration of 0.001% CNTs as compared to that of pure water. This is related to the change of surface characteristics by the deposition of CNTs. This deposition makes a thin CNT layer on the surface and the active nucleation sites of heat transfer surface are decreased due to this layer. The thin layer acts as the thermal resistance and also decreases the bubble generation rate resulting in a decrease in pool boiling HTCs. The same layer, however, maintains the nucleate boiling even at very high heat fluxes and reduces the formation of large vapor canopy at near CHF resulting in a significant increase in CHF.

• Journal of Institute of Control, Robotics and Systems
• /
• v.21 no.6
• /
• pp.583-588
• /
• 2015

Flexible tactile sensors can provide valuable feedback to intelligent robots regarding the environment around them. This is especially important when robots such as, service robots share a workspace with humans. This paper presents a contact force measurement algorithm of a flexible tactile sensor. This sensor is manufactured by a direct-writing technique, which is one 3D printing method, using multi-walled carbon nano-tubes. An analog signal processing circuit has been designed and implemented to reduce noise contained in the sensor output. In addition, a digital version of the Butterworth filter was implemented by software running on a microcontroller. Through various experiments, characteristics of the sensor system have been identified. Based on three traits, an algorithm to detect the contact and measure the contact force has been developed. The entire system showed a promising prospect to detect the contact over a large and curved area.

• Journal of the Korean Ceramic Society
• /
• v.51 no.1
• /
• pp.1-6
• /
• 2014

Here we report improved photo-catalytic effect of $Ag_2S$ under visible light using carbon nano-tubes (CNT) modified with $Ag_2S$ nanoparticles. The optical properties, structural properties and compositional analysis, as well as the photo-electrochemical properties of the prepared composites were investigated. It was found that the photocurrent density, and the photo-catalytic effect, was increased by modification of CNT in this way. Compared with the separate effects of $Ag_2S$ and CNT nanoparticles, the photocatalytic effect of CNT-modified-with-$Ag_2S$ composites, increased significantly due to a synergistic effect between the CNT and the $Ag_2S$ nanoparticles.

• Journal of the Korean Society for Precision Engineering
• /
• v.31 no.2
• /
• pp.149-156
• /
• 2014

Flexible tactile sensors can provide valuable feedback to intelligent robots about the environment. This is especially important when the robots, e.g., service robots, are sharing the workspace with human. This paper presents a flexible tactile sensor that was manufactured by direct writing technique, which is one of 3D printing method with multi-walled carbon nano-tubes. The signal processing system consists of two parts: analog circuits to amplify and filter the sensor output and digital signal processing algorithms to reduce undesired noise. Finally, experimental setup is implemented and evaluated to identify the characteristics of the flexible tactile sensor system. This paper showed that this type of sensors can detect the initiation and termination of contacts with appropriate signal processing.

• Advances in nano research
• /
• v.11 no.6
• /
• pp.581-593
• /
• 2021

This model is proposed to describe the buckling behavior of Carbon Nanotubes (CNTs) embedded in an elastic medium taking into account the combined effects of the magnetic field, the temperature, the nonlocal parameter, the number of walls. Using Eringen's nonlocal elasticity theory, thin cylindrical shell theory and Van der Waal force (VdW) interactions, we develop a system of partial differential equations governing the buckling response of CNTs embedded on Winkler, Pasternak, and Kerr foundations in a thermal-magnetic environment. The pre-buckling stresses are obtained by applying airy's stress function and an adjacent equilibrium criterion. To estimate the nonlocal critical buckling load of CNTs under the simultaneous effects of the magnetic field, the temperature change, and the number of walls, an optimization technique is proposed. Furthermore, analytical formulas are developed to obtain the buckling behavior of SWCNTs embedded in an elastic medium without taking into account the effects of the nonlocal parameter. These formulas take into account VdW interactions between adjacent tubes and the effect of terms involving differences in tube radii generally neglected in the derived expressions of the critical buckling load published in the literature. Most scientific research on modeling the effects of magnetic fields is based on beam theories, this motivation pushes me to develop a cylindrical shell model for studying the effect of the magnetic field on the static behavior of CNTs. The results show that the magnetic field has significant effects on the static behavior of CNTs and can lead to slow buckling. On the other hand, thermal effects reduce the critical buckling load. The findings in this work can help us design of CNTs for various applications (e.g. structural, electrical, mechanical and biological applications) in a thermal and magnetic environment.

• Journal of IKEEE
• /
• v.28 no.3
• /
• pp.337-341
• /
• 2024

As the production process for silicon-based integrated circuits approaches physical limits, a lot of attention is focused on the new semiconductor materials to overcome these problems. Carbon NanoTubes(CNTs) are attracting a lot of interest as one of the most competitive materials with excellent electrical transport and scaling properties, and CNTFETs using CNTs are gaining popularity as next-generation semiconductor devices. However, since the technology to place CNTs in a certain direction and interval on the wafer is not yet mature enough, it is difficult to construct all necessary circuits with CNTFET only. So, there is increasing interest in a hybrid configuration using MOSFET and CNTFET together. Because SRAM plays a role as a cache in microprocessors and is a critical circuit block influencing microprocessor performance, research to implement existing SRAM in a hybrid form is steadily progressing. Therefore, in this paper, we will explain the design method of hybrid 8T SRAM based on the existing hybrid 6T SRAM and discuss the performance difference between the two circuits.

• Korean Chemical Engineering Research
• /
• v.55 no.1
• /
• pp.40-47
• /
• 2017

Dust explosion hazards are always present when combustible dusts are manufactured or handled in the process. However, industries is experiencing difficulty in establishing chemical accident prevention measures because of insufficiency of information on dust explosion characteristics of combustible dust handled in industry. In this study, we investigated experimentally dust explosion characteristics of two kinds of multi-walled carbon nano tubes (MWCNT) different in particle size distribution and examined classification of dust explosion hazardous area for MWCNT manufacturing or handling process by applying the NFPA 499 code. As a result, $P_{max}$, $K_{st}$, LEL, MIE and MIT of MWCNT 1 having $124.2{\mu}m$ median diameter are obtained 6.3 bar, $56bar{\cdot}m/s$, $125g/m^3$, over 1000 mJ, and over $650^{\circ}C$. $P_{max}$, $K_{st}$, LEL, MIE and MIT of MWCNT 2 having $293.5{\mu}m$ median diameter are 6.2 bar, $42bar{\cdot}m/s$, $100g/m^3$, over 1000 mJ, and over $650^{\circ}C$, respectively. MWCNT 1, 2 are not categorized as combustible dust listed in the NFPA 499 Code for classification of dust explosion hazardous area because explosion severity and ignition sensitivity of MWCNT 1, 2 are below 0.35 and 0.01, respectively.

• Journal of IKEEE
• /
• v.25 no.2
• /
• pp.381-387
• /
• 2021

As Head-Mounted Displays(HMDs), which are mainly used to maximize realism in games and videos, have experienced increased demand and expanded scope of use in education and training, there is growing interest in methods to enhance the performance of conventional HMDs. In this study, a methodology to utilize Carbon NanoTubes(CNTs) to improve the performance of gate drivers that send control signals to each pixel circuit of the HMD is discussed. This paper proposes a new circuit design method that replaces the transistors constituting the buffer part of the conventional gate driver with transistors incorporating CNTs and compare the performance of the suggested gate drive with that of a gate driver comprising only conventional transistors via simulations. According to the simulation results, by including CNTs in the gate driver, the output voltage can be increased by approximately 0.3V compared to the conventional gate driver high voltage(1.1V) at a speed of 12.5 GHz and the gate width also can be reduced by up to 20 times.