• 제목/요약/키워드: carbon chain

검색결과 406건 처리시간 0.032초

Transcriptome analysis of a transgenic Arabidopsis plant overexpressing CsBCAT7 reveals the relationship between CsBCAT7 and branched-chain amino acid catabolism

  • Kim, Young-Cheon;Lee, Dong Sook;Jung, Youjin;Choi, Eun Bin;An, Jungeun;Lee, Sanghyeob;Lee, Jeong Hwan
    • Journal of Plant Biotechnology
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    • 제48권4호
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    • pp.228-235
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    • 2021
  • The amino acids found in plants play important roles in protein biosynthesis, signaling processes, and stress responses, and as components in other biosynthesis pathways. Amino acid degradation helps maintain plant cells' energy states under certain carbon starvation conditions. Branched-chain amino acid transferases (BCATs) play an essential role in the metabolism of branched-chain amino acids (BCAAs) such as isoleucine, leucine and valine. In this paper, we performed genome-wide RNA-seq analysis using CsBCAT7-overexpressing Arabidopsis plants. We observed significant changes in genes related to flowering time and genes that are germination-responsive in transgenic plants. RNA-seq and RT-qPCR analyses revealed that the expression levels of some BCAA catabolic genes were upregulated in these same transgenic plants, and that this correlated with a delay in their senescence phenotype when the plants were placed in extended darkness conditions. These results suggest a connection between BCAT and the genes implicated in BCAA catabolism.

지속가능공급사슬관리에 관한 연구동향 분석 (An Analysis of Research Trends on Sustainable Supply Chain Management)

  • 김준석
    • 무역학회지
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    • 제46권3호
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    • pp.203-226
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    • 2021
  • Sustainability is considered to be one of the most important social and environmental requirements of modern companies located in global supply chains, since the strong worldwide regulation on carbon emission due to global warming has been emphasized. Sustainable Supply Chain Management(SSCM) could be one of the great alternatives for global companies to maintain a pleasant business environment while fulfilling their social and environmental responsibilities. This paper aims to provide research trends and future directions on SSCM through a systematic literature review. From January of 2004 to May of 2021, 185 English-written and peer-reviewed articles published in eminent journals were selected for the review. The all reviewed papers have been published in SSCI, SCI and SCIE indexed journals and should have accredited by WOS and JCR. A descriptive analysis was followed by a content analysis with regard to research design and methods, and data analysis techniques. We found that the number of research in the field of SSCM have been recently increasing and researchers and their affiliation have been expanding to all over the world, especially to emerging countries. We also found that the rate of the empirical studies and relevant research methodologies applied to the selected papers were relatively high. In the future, it is desirable to be increased the number of the specific industry-oriented research and the quantitative research pursuing the optimality.

A review of elemental mercury removal processing

  • Bae, Kyong-Min;Kim, Byung-Joo;Park, Soo-Jin
    • Carbon letters
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    • 제12권3호
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    • pp.121-130
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    • 2011
  • Public concern has recently increased over the potential risk of toxic elements emitted from anthropogenic sources. Among these, mercury has drawn special attention owing to its increasing level of bioaccumulation in the environment and in the food chain, with potential risks for human health. This paper presents an overview of research related to mercury control technology and identifies areas requiring additional research and development. It critically reviews measured mercury emissions progress in the development of promising control technologies, including catalytic oxidation, sorbent injection, photochemistry oxidation, and air pollution control devices.

Telomerization 에 關한 硏究 (I) Vinyl Acetate 와 Chlorinated Hydrocarbons 과의 Telomerization 에 關하여 (Studies on Telomerization (I) Telomerization of Vinyl Acetate with Chlorinated Hydrocarbons)

  • 심정섭;홍석주
    • 대한화학회지
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    • 제6권1호
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    • pp.88-93
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    • 1962
  • The telomerization of vinyl acetate with carbon tetrachloride, chloroform and monochlorobenzene were investigated with respect to the synthesis of those telomers, properties and molecular weights of the formed telomers, and reaction mechanisms. Vinyl acetate reacted with carbon tetrachloride and chloroform to form telomers at 70-90$^{\circ}C$ and 60-70$^{\circ}C$, respectively and it formed polymer with monochlorobenzene. As a chain transfer agent, carbon tetrachloride was more effective than chloroform. In the telomerization of vinyl acetate and carbon tetrachloride: 1) The average molecular weight of the telomer decreased as the mole ratio of carbon tetrachloride to vinyl acetate increased. The optimum conditions for the highest yield of the telomer were as follows: Mole ratio of carbon tetrachloride to vinyl acetate : 2.5 Reaction time : 20 hours. 2) As the reaction proceeded, the refractive index and average molecular weight of the telomer increased rapidly in the first 10 hours but the increase was slow through the next 10 hours, so that, the average recurring number(n) of taxogen in the final product reached an almost definite value, i.e., 3. The telomer formed in the telomerization of vinyl acetate with carbon tetrachloride and chloroform turned to brown color in the air due to decomposition or polymerization. The suggested telomerization mechanism was supported by the hexachloroethane detected in the course of reaction.

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Metabolism of Very Long-Chain Fatty Acids: Genes and Pathophysiology

  • Sassa, Takayuki;Kihara, Akio
    • Biomolecules & Therapeutics
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    • 제22권2호
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    • pp.83-92
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    • 2014
  • Fatty acids (FAs) are highly diverse in terms of carbon (C) chain-length and number of double bonds. FAs with C>20 are called very long-chain fatty acids (VLCFAs). VLCFAs are found not only as constituents of cellular lipids such as sphingolipids and glycerophospholipids but also as precursors of lipid mediators. Our understanding on the function of VLCFAs is growing in parallel with the identification of enzymes involved in VLCFA synthesis or degradation. A variety of inherited diseases, such as ichthyosis, macular degeneration, myopathy, mental retardation, and demyelination, are caused by mutations in the genes encoding VLCFA metabolizing enzymes. In this review, we describe mammalian VLCFAs by highlighting their tissue distribution and metabolic pathways, and we discuss responsible genes and enzymes with reference to their roles in pathophysiology.

실증규모 체인스토커식 RDF전용보일러 개발 (Development of a Commercial-scale RDF Boiler with Chain type Stoker)

  • 최연석;김병길;노남선
    • 한국신재생에너지학회:학술대회논문집
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    • 한국신재생에너지학회 2009년도 춘계학술대회 논문집
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    • pp.813-816
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    • 2009
  • A commercial-scale RDF boiler that its burning capacity is 400 kg-RDF/hr and steam production capacity is 2 ton/hr. It has a chain type stoker and waste heat recovery system. Heat exchanger is vertical water-pipe so that soot blowing and removal is convenient during operation. Dry scrubber, bag filter and activated carbon tower have been installed for the reduction of air pollutant gases and dust. Analysing data of pollutants from stack such as $SO_x$. $NO_x$ and dioxin shows so good results that the boiler system could comply the regulated emission limits.

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Short-chain fatty acids, including acetate, propionate, and butyrate, elicit differential regulation of intracellular Ca2+ mobilization, expression of IL-6 and IL-8, and cell viability in gingival fibroblast cells

  • Kim, So Hui;Kim, Min Seuk
    • International Journal of Oral Biology
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    • 제45권2호
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    • pp.64-69
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    • 2020
  • Short-chain fatty acids (SCFAs) such as acetate, propionate, and butyrate are secondary metabolites produced by anaerobic fermentation of dietary fibers in the intestine. Intestinal SCFAs exert various beneficial effects on intestinal homeostasis, including energy metabolism, autophagy, cell proliferation, immune reaction, and inflammation, whereas contradictory roles of SCFAs in the oral cavity have been reported. Herein, we found that low and high concentrations of SCFAs induce differential regulation of intracellular Ca2+ mobilization and expression of pro-inflammatory cytokines, such as interleukin (IL)-6 and IL-8, respectively, in gingival fibroblast cells. Additionally, cell viability was found to be differentially regulated in response to low and high concentrations of SCFAs. These findings demonstrate that the physiological functions of SCFAs in various cellular responses are more likely dependent on their local concentration.

$^{13}C$ Spin-Lattice Relaxation Study of Segmental Motions in n-alkanes: n-Undecane and n-Dodecane

  • Min, Buem-Chan;Lee, Jo-Woong
    • 한국자기공명학회논문지
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    • 제2권1호
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    • pp.1-23
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    • 1998
  • The motions of carbon-chain backbone in n-undecance and n-dodecane dissolved in CDCl3 are investigated by 13C NMR relaxation study. For this purpose a model of C - C backbone motions for these molecules is introduced that takes into account the cooperativities between rotations about two $\beta$-coupled C - C bonds. In this model it is assumed that the major conformational interconversions occurring in the inner part of the chain involve the type II jumps only, although at terminal part of the chain both type II and type III motions are assumed to take place. Information of the rate constants of these conformational transitions could be extracted by comparing the T1's calculated on the basis of the assumed model with those observed over the temperature range of 248 - 308 K. The calculations were performed according to the method proposed by Wittebort and Szabo. The activation energies, ranging from ca 12 to 20 kJ/mol, could be obtained from the Arrhenius plots of these calculated rate constants.

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Length- and parity-dependent electronic states in one-dimensional carbon atomic chains on C(111)

  • Kim, Hyun-Jung;Oh, Sang-Chul;Kim, Ki-Seok;Zhang, Zhenyu;Cho, Jun-Hyung
    • 한국진공학회:학술대회논문집
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    • 한국진공학회 2010년도 제39회 하계학술대회 초록집
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    • pp.56-56
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    • 2010
  • Using first-principles density-functional theory calculations, we find dramatically different electronic states in the C chains generated on the H-terminated C(111) surface, depending on their length and parity. The infinitely long chain has $\pi$ electrons completely delocalized over the chain, yielding an equal C-C bond length. As the chain length becomes finite, such delocalized $\pi$ electrons are transformed into localized ones. As a result, even-numbered chains exhibit a strong charge-lattice coupling, leading to a bond-alternated structure, while odd-numbered chains show a ferrimagnetic spin ordering with a solitonlike structure. These geometric and electronic features of infinitely and finitely long chains are analogous to those of the closed (benzene) and open (polyacetylene) chains of hydrocarbons, respectively.

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포도주 효모에 의한 중간크기의 지방산 생성 (Formation of Medium Chain Fatty Acid by Wine Yeasts)

  • 이수오
    • 한국식품과학회지
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    • 제21권6호
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    • pp.832-837
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    • 1989
  • 포도주 발효에 사용되는 호모균주 12종을 Murphy배지에 배양하여 중간크기의 지방산(MCFA)의 생성을 분석하였고 발효조건에 따라 그 생성량을 관찰하였다. 특히 발효력이 강한 Saccharomyces cerevisiae에 속하는 균주들은 발효초기에 decanoic acid를 약 21-26mg/1 생성하였고 발효 후기에는 약 5-10mg/1로 감소하였다. 발효조건에서 볼 때 MCFA의 생성은 온도가 높을수록 감소하였고 당함량이 클수록 증가하였으며 또한 탄산가스의 존재 하에서도 증가하였다.

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