• 제목/요약/키워드: candidate materials

검색결과 807건 처리시간 0.03초

리튬 이차 전지로의 응용을 위한 LiNiO_2$ 양극 물질의 전자상태 연구 (Electronic state of LiNiO_2$ cathode materials for Li ion barriers)

  • 전영아;김양수;노광수
    • 한국재료학회:학술대회논문집
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    • 한국재료학회 2003년도 추계학술발표강연 및 논문개요집
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    • pp.216-216
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    • 2003
  • The layered nickel oxides (LiNiO$_2$) have been studied for possible use as cathode materials i3l 4V lithium batteries. Although LiCoO$_2$ has been known as the best candidate material for Li-ion batteries, which produces the best performance LiNiO$_2$ is generally accepted as an attractive cathode material, because of its various advantages such as lower cost higher discharge capacity and better reversibility. In this investigation, we calculated the electric state of LiNiO$_2$ using DV-X$\alpha$ molecular orbital method in order to obtain the information of chemical bonding among the Li, Ni and O. In LiNiO$_2$, alternate layers of Li and Ni occupy the octahedral sites of a cubic close packing of oxide ions, making up a rhombohedral structure with an R-3m space group, Li in 3a, Ni in 3b, and O in 6c sites. On the basis of this, we made the cluster model and studied ionization of each atoms and interaction between atoms according to Mullilcen population analysis.

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Two-Dimensional Electron Gas (2DEG) at $Ta_2O_5/SrTiO_3$ Heterointerface

  • Joung, Jin Gwan;Yoo, Kwang Soo;Kim, Jin Sang;Baek, Seung-Hyub
    • 한국진공학회:학술대회논문집
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    • 한국진공학회 2013년도 제44회 동계 정기학술대회 초록집
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    • pp.161-161
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    • 2013
  • Two-dimensional electron gas (2DEG) has been investigated at the heterointerface between two insulating dielectric perovskite oxides, $LaAlO_3$ (LAO)/$SrTiO_3$ (STO). Properties of the 2DEG have attracted an enormous interest in condensed matter physics due to multifunctional properties such as the coexistence of ferromagnetism and superconductivity, as well as the high electron mobility. Here, we have grown $Ta_2O_5$ thin films using pulsed laser deposition on $SrTiO_3$ substrate to investigate the electric properties of the $Ta_2O_5$/STO heterointerface. Our research reveal that the non-polar $Ta_2O_5$/$TiO_2$ heterointerface favors the formation of 2DEG similar to that at the LAO/STO heterointerface. The metallic behavior was found in this heterointerface with the current about $10{\sim}100{\mu}A$ at 5 V by using conventional I-V measurements, when the $Ta_20_5$ film thickness reaches over critical thickness, $d_c{\simeq}2uc$. The finding that electrons was localized at $Ta_2O_5$/STO heterointerface have attracted to be strong and new candidate for nanoscale oxide device applications.

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Fully Room Temperature fabricated $TaO_x$ Thin Film for Non-volatile Memory

  • Choi, Sun-Young;Kim, Sang-Sig;Lee, Jeon-Kook
    • 한국재료학회:학술대회논문집
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    • 한국재료학회 2011년도 춘계학술발표대회
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    • pp.28.2-28.2
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    • 2011
  • Resistance random access memory (ReRAM) is a promising candidate for next-generation nonvolatile memory because of its advantageous qualities such as simple structure, superior scalability, fast switching speed, low-power operation, and nondestructive readout. We investigated the resistive switching behavior of tantalum oxide that has been widely used in dynamic random access memories (DRAM) in the present semiconductor industry. As a result, it possesses full compatibility with the entrenched complementary metal-oxide-semiconductor processes. According to previous studies, TiN is a good oxygen reservoir. The TiN top electrode possesses the specific properties to control and modulate oxygen ion reproductively, which results in excellent resistive switching characteristics. This study presents fully room temperature fabricated the TiN/$TaO_x$/Pt devices and their electrical properties for nonvolatile memory application. In addition, we investigated the TiN electrode dependence of the electrical properties in $TaO_x$ memory devices. The devices exhibited a low operation voltage of 0.6 V as well as good endurance up to $10^5$ cycles. Moreover, the benefits of high devise yield multilevel storage possibility make them promising in the next generation nonvolatile memory applications.

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과공정 Al-25Si-X 내마모 합금의 분무 성형 및 특성 평가 (Spray forming the wear resistant hypereutectic Al-25Si-X alloy and property evaluation)

  • 이재철;석현광;신돈수;이호인
    • 한국소성가공학회:학술대회논문집
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    • 한국소성가공학회 1999년도 압출 및 인발 심포지엄
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    • pp.24-37
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    • 1999
  • A comprehensive methodology to consolidate the hypereutectic Al-27Si-X alloy via spray forming was investigated in an attempt to judge the feasiblilty of this alloy in applying wear resistant components. Billets having desired shape and microstructures were fabricated using forming parameters obtained from numerical calculations. Prior to tube extrusion of the spray formed billets, effects of various extrusion conditions, such as extrusion ratio, die temperature, and die configuration, on microstructures of the billet were studied. Based on results obtained from the preliminary extrusion tests, the formed billets were then hot extruded into a tubular shape. Various material properties of the extruded billet were measured and compared with the other candidate materials for anti-wear applications.

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진동절삭기 구성을 위한 자기변형 재료의 진동 특성 규명 (Vibrational Characteristics of Magnetostrictive Materials for a Vibration Assisted Cutting Device)

  • 이호철;김기대
    • 한국정밀공학회지
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    • 제29권11호
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    • pp.1214-1220
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    • 2012
  • Vibration assisted cutting (VAC) is one of the promising methods for precision machining, which has been normally equipped with piezoelectric materials. In this paper, a feasibility of applying magnetostrictive materials to VAC as a cutting device instead of piezoelectric materials was studied. For this, the vibrational characteristics of a magnetostrictive material was investigated with respect to a coil design, a preload, and the effects of a biasing and an exciting magnetic fields. The output strain of a magnetostrictive material is restricted due to an increasing inductive impedance as the exciting frequency increases and the heat of coil, etc. Through the experimental results, it was found that the biasing and the exciting magnetic field affected the output performance significantly but not the preload. In conclusion, the magnetostrictive material could be used only in the low frequency range but not a good candidate for high frequency actuating application.

화학적으로 변형된 전구용액을 이용한 YBCO 박막 제조 (Fabrication of YBCO films in MOD processing via chemically modified precursor solution)

  • 김영국;유재무;정국채;고재웅;김영준;한봉수
    • Progress in Superconductivity
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    • 제7권2호
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    • pp.158-161
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    • 2006
  • Superconducting YBCO films were successfully fabricated by MOD process using chemically modified precursor solution. In this study, a chemically modified precursor solution for MOD processing was synthesized using metal-organic salts and organic additives. It was shown that crack-free and uniform precursor films were formed after calcination in humidified Oxygen atmosphere. Less than 3 hours are required to finish the calcination process. XRD measurement shows that $BaF_2,\;CuO,\;Y_2O_3$ are major constituent of precursor films. Furthermore, YBCO films without any secondary phases were successfully fabricated after annealing in wet $Ar/O_2$ atmosphere. The YBCO film prepared on a $LaAlO_3$ single crystal substrate ($10mm{\times}10mm$) gives transport $I_c$ of 10A at 77K. This chemical modification approach is a possible candidate for improving MOD-processing of YBCO coated conductor.

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디젤엔진에서 수소 환원제 공급 조건에 따른 LNT 촉매 성능 (Performance of LNT Catalyst according to the Supply Condition of Hydrogen Reductants for Diesel Engine)

  • 박철웅;김창기;최영;강건용
    • 한국자동차공학회논문집
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    • 제17권3호
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    • pp.142-148
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    • 2009
  • The direct injection(DI) diesel engine has become a prime candidate for future transportation needs because of its high thermal efficiency. However, nitrogen oxides(NOx) increase in the local high temperature regions and particulate matter (PM) increases in the diffusion flame region within diesel combustion. Therefore, the demand for developing a suitable after treatment device has been increased. NOx absorbing catalysts are based on the concept of NOx storage and release making it possible to reduce NOx emission in net oxidizing gas conditions. This De-NOx system, called the LNT(Lean NOx Trap) catalyst, absorbs NOx in lean exhaust gas conditions and release it in rich conditions. This technology can give high NOx conversion efficiency, but the right amount of reducing agent should be supplied into the catalytic converter at the right time. In this research, a performance characteristics of LNT with a hydrogen enriched gas as a reductant was examined and strategies of controlling the injection and rich exhaust gas condition were studied. The NOx reduction efficiency is closely connected to the injection timing and duration of reductant. LNT can reduce NOx efficiently with only 1 % fuel penalty.

The ferroelectric and fatigue properties in Gd-modified bismuth titanate (BGT) thin films deposited by liquid delivery MOCVD

  • Kang Dong-Kyun;Park Won-Tae;Kim Byong-Ho
    • 한국반도체및디스플레이장비학회:학술대회논문집
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    • 한국반도체및디스플레이장비학회 2006년도 춘계학술대회
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    • pp.190-193
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    • 2006
  • Gadolinium-substituted bismuth titanate, $Bi_{3.3}Gd_{0.7}Ti_{3}O_{12}$, thin films were successfully fabricated on Pt(111)/Ti/$SiO_2$/Si(100) substrates by a MOCVD process. Fabricated BGT thin films were found to be random oriental ions, which were confirmed by X-ray diffraction and scanning electron microscope analysis. The remanent polarization value ($2P_r$) of the BGT thin film annealed at $720^{\circ}C$ was $45.13{\mu}C/cm^2$, at an applied voltage of 5 V. The BGT thin film exhibits a good fatigue resistance up to $1{\times}10^{11}$ switching cycles at a frequency of 1 MHz with applied voltage of 5 V. These results indicate that the randomly oriented BGT thin film is a promising candidate among ferroelectric materials useful in lead-free nonvolatile ferroelectric random access memory applications.

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제동디스크 소재의 내열성 비교시험방법 연구 (A study of comparative experiment process for heat resistance of brake disk materials)

  • 임충환;구병춘
    • 한국철도학회:학술대회논문집
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    • 한국철도학회 2008년도 춘계학술대회 논문집
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    • pp.941-947
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    • 2008
  • 철도차량의 제동에는 전기의 회생, 발전을 이용하는 전기적 제동장치와 함께 차륜 답면 및 디스크를 사용하는 기계식 제동장치가 적용된다. 특히 브레이크 디스크의 제동작용에 있어서, 디스크와 마찰패드와의 마찰을 통해 차량의 운동에너지가 열에너지로 변환되며 이때 디스크 표면에는 매우 높은 온도가 집중하게 된다. 이러한 고온 집중의 반복에 의해 디스크 표면에는 열피로에 기인한 열균열이 발생하게 된다. 발생된 열균열은 차량 유지보수성능을 저하시키고 최악의 경우 대규모의 사고를 유발할 수도 있다. 본 연구에서는 보다 높은 내열성을 갖는 브레이크 디스크 소재를 개발하기 위한 과정의 일환으로 재료의 내열성 비교시험절차를 구축하였다. 또한 현재 새마을호 및 무궁화호 열차에서 사용되는 브레이크 디스크 재질을 이용한 시험을 통해 시험 절차의 효용성을 확인하였다.

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전형적인 열처리와 마이크로웨이브 열처리에 따른 PDP용 전극과 투명 유전체의 동시 소성 (Co-firing of Dielectric and Electrode with Conventional and Microwave Heating in Plasma Display Panel)

  • 황성진;;;김형순
    • 한국전기전자재료학회:학술대회논문집
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    • 한국전기전자재료학회 2008년도 하계학술대회 논문집 Vol.9
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    • pp.463-463
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    • 2008
  • The glass frit has been used in transparent dielectric, barrier rib and electrode of PDP (Plasma display panel). In PDP fabrication, the firing temperature of glass frit is normally 550~$580^{\circ}C$ with conventional heating. However, there are a problem that silver in electrode is diffused throughout the transparent dielectric. For inhibiting the Ag diffusion we considered use of the microwave heating. We investigated firing of glass frit compared between conventional and microwave heating. After firing by two types of heating, the diffusion of silver is determined using a optical microscope and UV-spectrometer. Based on the our results, the microwave heating should be a candidate to heating source for high efficacy in PDP.

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