• Title/Summary/Keyword: c/c composite

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A Characterization Study on Nafion$^{(R)}$/$ZrO_2-TiO_2$ Composite Membranes for PEMFC Operation at High Temperature and Low Humidity (고온/저가습 PEMFC 운전을 위한 Nafion$^{(R)}$/$ZrO_2-TiO_2$ 복합 전해질 막의 특성 연구)

  • Park, Ki-Tae;Chun, Jeong-Hwan;Choi, Dong-Woong;Kim, Sung-Hyun
    • Journal of Hydrogen and New Energy
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    • v.22 no.1
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    • pp.60-68
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    • 2011
  • [ $ZrO_2-TiO_2$ ]binary oxides with various Zr:Ti molar ratios were prepared by sol-gel method and Nafion$^{(R)}$/$ZrO_2-TiO_2$ composite membranes were fabricated for proton exchange membrane fuel cells (PEMFCs) at high temperature and low humidity. Water uptake, Ion exchange capacity (IEC), and proton conductivity of Nafion$^{(R)}$/$ZrO_2-TiO_2$ composite membranes were characterized and these composite membranes were tested in a single cell at $120^{\circ}C$ with various relative humidity (R.H.) conditions. The obtained results were compared with the unmodified membranes (Nafion$^{(R)}$ 112 and Recast Nafion$^{(R)}$). A Nafion$^{(R)}$/$ZrO_2-TiO_2$ composite membrane with 1:3 of Zr:Ti molar ratio showed the highest performance. The performance showed 500 mW/$cm^2$ (0.499V) at $120^{\circ}C$, 50% R. H., and 2 atm.

A study on the forming condition of a bone plate made of a glass/polypropylene composite (Twintex) (유리섬유/폴리프로필렌 복합재료 (Twintex)를 이용한 고정판 성형조건에 관한 연구)

  • Park, Seok-Won;Yoo, Seong-Hwan;Lee, Jae-Eung;Chang, Seung-Hwan
    • Composites Research
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    • v.23 no.6
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    • pp.55-60
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    • 2010
  • In this paper, tensile and bending tests of glass/polypropylene composite (Twintex) specimens fabricated by various forming conditions were carried out and the results were compared according to the forming conditions to find the appropriate condition for the forming composite bone plates. From the tests it was found that the most appropriate forming conditions were $230^{\circ}C$, 3MPa. Composite bone plates were formed using this condition by two different fabricating methods for screw holes: one was a net shape molding and the other was drilling. The forming and bending tests revealed that the drilling process provided much better bending stiffness of bone plates. This paper provided the most appropriate condition for forming composite bone plates and this result was also expected to offer informative data on forming of other Twintex structures.

An Experimental Study on Flexural Performance Evaluation of C-Shaped Steel-Timber Composite Beams (C형 강재-목재 합성보의 휨성능 평가에 관한 실험 연구)

  • Oh, Keunyeong;Lee, Sang-Sup;Park, Keum-Sung;Boo, Yoon-Seob
    • Journal of the Korea Institute of Building Construction
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    • v.24 no.3
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    • pp.331-341
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    • 2024
  • In this study, the flexural strength and ductility of steel-timber composite beams were evaluated to enhance the structural performance of glued-laminated timber beams. Three specimens were fabricated, including one reference glulam beam and two composite beams. The composite beams were constructed by attaching steel sections to the glulam beam using either liquid adhesive or screws. The experimental results showed that the structural performance of the steel-timber composite beams was approximately 2-3 times higher than the reference glulam beam, indicating that both flexural strength and ductility were sufficiently ensured. Notably, the specimen constructed with liquid adhesive demonstrated superior structural performance compared to the screw-attached specimen.

Formation of Ti3SiC2 Interphase of SiC Fiber by Electrophoretic Deposition Method

  • Lee, Hyeon-Geun;Kim, Daejong;Jeong, Yeon Su;Park, Ji Yeon;Kim, Weon-Ju
    • Journal of the Korean Ceramic Society
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    • v.53 no.1
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    • pp.87-92
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    • 2016
  • Due to its stability at high temperature and its layered structure, $Ti_3SiC_2$ MAX phase was considered to the interphase of $SiC_f/SiC$ composite. In this study, $Ti_3SiC_2$ MAX phase powder was deposited on SiC fiber via the electrophoretic deposition (EPD) method. The Zeta potential of the $Ti_3SiC_2$ suspension with and without polyethyleneimine as a dispersant was measured to determine the conditions of the EPD experiments. Using a suspension with 0.03 wt.% ball milled $Ti_3SiC_2$ powder and 0.3 wt.% PEI, $Ti_3SiC_2$ MAX phase was successfully coated on SiC fiber with an EPD voltage of 10 V for 2 h. Most of the coated $Ti_3SiC_2$ powders are composed of spherical particles. Part of the $Ti_3SiC_2$ powders that are platelet shaped are oriented parallel to the SiC fiber surface. From these results we expect that $Ti_3SiC_2$ can be applied to the interphase of $SiC_f/SiC$ composites.

Property Studies of PAN/PVdF Composite Nanofiber Manufactured from Electrospinning (전기방사법으로 제조된 PAN/PVdF 복합나노섬유의 특성연구)

  • Yun, Jung-Hyun;Choi, Dong-You
    • 전자공학회논문지 IE
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    • v.46 no.3
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    • pp.6-11
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    • 2009
  • In this paper, manufactured composite nanofiber by electrospinning that make spinning solvent according to weight of PAN/PVdF. PVdF content of composite nanofiber decreases, diameter of fiber decreased. Result that measure contact angle to confirm hydrophile property of PAN/PVdF composite nanofiber, PVdF content increases, could confirm that contact angle with water increases. After leave filter measurement sample for 25 hours in temperature of $40^{\circ}C$, humidity of 85%, result PAN/PVdF composite nanofiber that estimate efficiency could confirm that display performance of HEPA more than 99.95% and ULPA more than 99.999%. And fiber diameter is small, could confirm that filter performance increases. Tensile strength of bulk of PAN/PVdF composite nanofiber was 5-8MPa, expansion 100-300%. And strength and expansion could know that increase according as PVdF's content increases. Tensile strength was 3-8MPa degree after annealing PAN/PVdF composite nanofiber during 2 hours in 120t. Tensile strength was no change almost by annealing, and expansion could know that decrease.

A STUDY ON MICROLEAKAGE OF COMPOSITE RESIN AFTER SURFACE TREATMENT (표면 처리방법에 따른 복합레진의 미세누출에 관한 실험적 연구)

  • Lee, Chang-Woo;Kim, Jung-Wook;Lee, Sang-Hoon
    • Journal of the korean academy of Pediatric Dentistry
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    • v.25 no.1
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    • pp.103-115
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    • 1998
  • Adhesion of composite resin to tooth structure has been of tremendous signgicance in clinical dentistry. Due to the lack of adhesion between composite restorative resins and enamel and dentin, microleakage occurs at the tooth/restoration interface. This may lead to discoloration, secondary caries, marginal breakdown, postoperative sensitivity, and even pulpal pathology. According to extensive use of composite resin, every effort on improving bonding strength and reducing microleakage between a tooth and composite resin has been continued. This study was conducted to determine the difference in microleakage in enamel and dentin treated with air-abrasion, acid etching and combination when restored with composite resin. Class V cavities were prepared on 30 premolars. The specimens were divided into following groups. group 1:air-abrasion+Scotchbond Multi-purpose group 4 :air-abrasion+All-Bond 2 group 2:acid etching+Scotchbond Multi-purpose group 5 :acid etching+All-Bond 2 group 3:combination+Scotchbond Multi-purpose group 6 :combination+All-Bond 2 #combination:air-abrasion + acid etching The specimens were filled with Z-100 after application of Scotchbond Multi-purpose and All-Bond 2. Thermocycling was conducted by alternately dipping the specimens in $5^{\circ}C$ and $55^{\circ}C$ water for 30 seconds 500 times. 1% methylene blue was applied and the specimens were left for 24 hours at $37^{\circ}C$. After washing out the dye, the tooth was sectioned buccolingually along the axis. The sectioned surface was observed with stereoscope for dye penetration. The author has measured the microleakage in teeth prepared with air-abrasion, acid ethching and combination to study the difference in microleakage following different methods of tooth surface treatment and has come to following results. 1. In comparing microleakage between groups, group 1 and 4 showed statistically significant difference from group 2, 3, 5 and 6(p<0.05). There was no significant difference among group 2, 3, 5, 6(p>0.05) nor between group 1 and 4(p>0.05). 2. In comparing microleakage among tooth surface treatment methods, Air-abrasion group showed significantly more microleakage than acid etching group and combination(airabrasion + acid etching) group(p<0.05). Combination(acid etching+air-abrasion)group tended to show lesser microleakage than acid etching group, but this was not statistically significant(p>0.05). 3. In comparing microleakage between bonding agents, there was no statistically significant difference between Scotch bond Multi-purpose and All-Bond 2(p>0.05).

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Experimental investigation of longitudinal shear behavior for composite floor slab

  • Kataoka, Marcela N.;Friedrich, Juliana T.;El Debs, Ana Lucia H.C.
    • Steel and Composite Structures
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    • v.23 no.3
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    • pp.351-362
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    • 2017
  • This paper presents an experimental study on the behavior of composite floor slab comprised by a new steel sheet and concrete slab. The strength of composite slabs depends mainly on the strength of the connection between the steel sheet and concrete, which is denoted by longitudinal shear strength. The composite slabs have three main failures modes, failure by bending, vertical shear failure and longitudinal shear failure. These modes are based on the load versus deflection curves that are obtained in bending tests. The longitudinal shear failure is brittle due to the mechanical connection was not capable of transferring the shear force until the failure by bending occurs. The vertical shear failure is observed in slabs with short span, large heights and high concentrated loads subjected near the supports. In order to analyze the behavior of the composite slab with a new steel sheet, six bending tests were undertaken aiming to provide information on their longitudinal shear strength, and to assess the failure mechanisms of the proposed connections. Two groups of slabs were tested, one with 3000 mm in length and other with 1500 mm in length. The tested composite slabs showed satisfactory composite behavior and longitudinal shear resistance, as good as well, the analysis confirmed that the developed sheet is suitable for use in composite structures without damage to the global behavior.

Application of a Composite Skin Equivalent using Collagen and Acellular Dermal Matrix as the Scaffold in a Mouse Model of Full-thickness Wound (콜라겐과 무세포진피를 이용한 혼합형 인공피부 개발 및 쥐 모델에서 창상치료 적용)

  • Lee, Dong Hyuck;Youn, Jin Chul;Lee, Jung Hee;Kim, In Seop
    • KSBB Journal
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    • v.29 no.1
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    • pp.42-49
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    • 2014
  • The aim of this study was to develop a composite human skin equivalent for wound healing. Collagen type1 and acellular dermal matrix powder were utilized as the scaffold with dermal fibroblasts and keratinocytes for the development of a composite human skin equivalent. Fibroblast maintained the volume of composite skin equivalent and also induced keratinocytes to attach and proliferate on the surface of composite skin equivalent. The composite human skin equivalent had a structure and curvature similar to those of real skin. Balb-C nu/nu mice were used for the evaluation of full-thickness wound healing effect of the composite human skin equivalent. Graft of composite skin equivalent on full-thickness wound promoted re-epithelialization and granulation tissue formation at 9 days. Given the average wound-healing time (14 days), the wound in the developed composite skin equivalent healed quickly. The overall results indicated that this three-dimensional composite human skin equivalent can be used to effectively enhance wound healing.

Degradation analysis of SiC fiber at elevated temperature for dust filtering applications (분진필터링 적용을 위한 SiC 섬유의 고온 열화분석)

  • Joo, Young Jun;Park, Cheong Ho;Khishigbayar, Khos-Erdene;Kim, Cheol Jin
    • Journal of the Korean Crystal Growth and Crystal Technology
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    • v.27 no.1
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    • pp.28-33
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    • 2017
  • SiC fiber can be used up to $1800^{\circ}C$ in both inert and air atmosphere without any problems such as melting and oxidation. SiC fibers can be applied to dust filtering processes as a bag filter at a high temperature above $700^{\circ}C$, which is far beyond the temperature range of currently available industrial bag filter. However the studies for the degradation of SiC fibers were still lacked in the harsh environment of steel industries and thermoelectric power plants. In this study, SiC fibers were reacted with steel dust and thermal power plant dust at a high temperature of $500^{\circ}C$ or higher, and the degraded shape of the fiber surface was observed by SEM. Also the degree of oxygen diffusion on the surface and inside of SiC fiber was analyzed by EDS.

고온가압소결한 SiCf/SiC 복합체에서 보호층으로써의 SiC 층이 기계적 물성에 미치는 영향

  • Jeong, Myeong-Hun;Kim, Dae-Jong;Kim, Won-Ju;Yun, Sun-Gil;Park, Ji-Yeon
    • Proceedings of the Materials Research Society of Korea Conference
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    • 2012.05a
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    • pp.105.1-105.1
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    • 2012
  • 고온가압소결으로 제조된 SiCf/SiC 복합체는 부식과 침식에 강하고 우수한 열적 성질과 고온에서의 높은 기계적 강도를 유지하는 장점을 가진 복합체다. 복합체의 파괴인성은 섬유와 기지 사이에 존재하는 열분해탄소 (PyC) 계면층에 의해 큰 영향을 받는데, 고온가압소결중 첨가되는 소결조제 ($Y_2O_3$, MgO, $Al_2O_3$)와 반응하여 계면이 손상되어 복합체의 기계적 특성치가 낮아지는 결과를 보였다. 본 연구에서는 계면의 손상을 보호하고자 PyC 계면상 위에 SiC 층을 증착하였는데 계면층과 SiC 층의 증착은 화학기상 증착법(CVD)을, 기지채움 공정은 전기영동법(EPD)과 고온가압소결방법(Hot Pressing)을 이용하여 복합체를 제조하였다. Tyranno-SA 섬유에 소스가스인 메탄을 열분해 하여 200nm 두께로 PyC 계면상을 증착하고, 두께를 달리하여 보호층으로써의 SiC 층을 single 과 double layer로 증착하였다. SiC 나노분말과 소결 첨가제인 $Y_2O_3$, $Al_2O_3$, MgO를 첨가한 슬러리를 전기영동법(EPD)을 이용하여 섬유내부에 슬러리를 함침시켰고, 이러한 프리폼을 $1750^{\circ}C$/20MPa의 조건으로 고온 가압소결 하여 $SiC_f$/SiC 복합체를 제조하였다. 이렇게 single layer와 double layer로 제조된 $SiC_f$/SiC 복합체에 대해 밀도와 미세구조를 관찰하였고, 기계적 특성을 비교하여 보호층으로써의 SiC 증착효과를 고찰하고자 하였다.

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