• Journal of the Korean Society for Nondestructive Testing
• /
• v.19 no.5
• /
• pp.347-355
• /
• 1999

A feasibility investigation on vibration-based nondestructive evaluation of thermal stress-induced micro-failure in the free edge region of thin composite laminates(1mm thick) has been carried out. The failure occurrence and damage zone, which were predicted by the three-dimensional finite-element thermal stress analysis, were observed using the ultrasonic C-scan and optical microscopy. Analysis of the vibration spectrum measured from the laminate beam specimens by the vibration sweep test exhibited that the obvious decrease in resonancy frequency and some considerable increase in damping factor were associated with the micro-failure formation. The vibration technique utilizing short beam and high resonant frequency was found to be very sensitive to the thermal stress-induced damage in the thin laminates.

• Journal of the Korea Academia-Industrial cooperation Society
• /
• v.6 no.3
• /
• pp.273-277
• /
• 2005

We prepared $0.25\~l.5um$ poly silicon gate array test group with $SiO_2$ spacers in order to employ NiCo composite salicide process from 15nm Ni/15nm Co/poly structure. We investigate the residual metal shape evolution by varying the rapid thermal silicide anneal temperature from $700^{\circ}C\;to\;1100^{\circ}C$. We observed the residual metals agglomerated into maze type and line type on $SiO_2$ field and silicide gate, respectively as temperature increased. We propose that lower silicide temperature would be favorable in newly proposed NiCo salicide in order to lessen the agglomeration causing the leakage and scum formation.

• Journal of the Korean institute of surface engineering
• /
• v.28 no.4
• /
• pp.207-218
• /
• 1995

Tungsten(W) metal has excellent properties in heat-resistance, corrison-resistance and impact-resistance but W-Metal is hard to sinter because higher than $2,000^{\circ}C$ is required to sinter W-powder. Con-sequently, a deposit technique of Nikel Phosphorus(NiP) on W-powber by the liquid reduction precipitation method was performed. Sintering temperature of the resulting W-NiP composite was lowered around to $1,000^{\circ}C$, and the mechanical properties of the sintered body was studied. The most suitable conditions for NiP thin film deposit on W-Powder by the liquid reduction precipitation method, which are composition, concentration, pH and temperature of the liquid reduction solution, were considered. The activated sintering was carried out in a reducing condition furnace. Components and properties of the sintered body were investigated by the density and the hardness measurements, X- ray diffraction analysis, and microscopic photographs of the surface. Quantity of NiP thin film on W-powder could be varied by the change of the liquid reduction solution composition. The sintering temperature of W-NiP composite powder is lowered to $950^{\circ}C$ from $2,000^{\circ}C$ and the hardness is increased (ca. 720 Hv). Large shrinkage could be observed since density was increased from 5.5 to 11.0 g/$cm^2$ which 86.2% of theoretical density. W metal and $Ni_3P$ crystal were detected through X-ray diffraction on the sintered body. Perfectly activated sintering was observed by microscopic photographs.

• Membrane Journal
• /
• v.24 no.4
• /
• pp.311-316
• /
• 2014

The polyacrylonitrile (PAN) hollow fiber composite membranes were prepared and their pervaporation performance was tested to concentrate the acetic acid aqueous solution. The coating of the composite membranes were confirmed by SEM images and the coating thickness was averagely $3.85{\mu}m$. As the crosslinking agent and the crosslinking temperature increase, the permeability decreases while the separation factor increases. Typically, the permeability $250g/m^2{\cdot}hr$ and the separation factor 13 were obtained for glutaraldehyde 13 wt% as the crosslinking agent and crosslinking temperature $140^{\circ}C$. And for the use of another crosslinking agent, poly (acrylic acid) 9 wt% and crosslinking temperature $140^{\circ}C$, the permeability $330g/m^2{\cdot}hr$ and separation factor 9 were obtained.

• The Journal of Advanced Prosthodontics
• /
• v.8 no.6
• /
• pp.417-422
• /
• 2016

PURPOSE. The purposes of this study were to evaluate the staining resistance of CAD/CAM resin-ceramics polished with different techniques and to determine the effectiveness of the polishing techniques on resin-ceramics, comparing it with that of a glazed glass-ceramic. MATERIALS AND METHODS. Four different CAD/CAM ceramics (feldspathic ceramic: C-CEREC Blocs, (SIRONA) and three resin-ceramics: L-Lava Ultimate, (3M ESPE), E-Enamic, (VITA) and CS-CeraSmart, (GC)) and one light cure composite resin: ME-Clearfil Majesty Esthetic (Kuraray) were used. Only C samples were glazed (gl). Other restorations were divided into four groups according to the polishing technique: nonpolished control group (c), a group polished with light cure liquid polish (Biscover LV BISCO) (bb), a group polished with ceramic polishing kit (Diapol, EVE) (cd), and a group polished with composite polishing kit (Clearfil Twist Dia, Kuraray) (kc). Glazed C samples and the polished samples were further divided into four subgroups and immersed into different solutions: distilled water, tea, coffee, and fermented black carrot juice. Eight samples ($8{\times}8{\times}1mm$) were prepared for each subgroup. According to CIELab system, four color measurements were made: before immersion, immersion after 1 day, after 1 week, and after 1 month. Data were analyzed with repeated measures of ANOVA (${\alpha}=.05$). RESULTS. The highest staining resistance was found in gl samples. There was no difference among gl, kc and cd (P>.05). Staining resistance of gl was significantly higher than that of bb (P<.05). Staining resistances of E and CS were significantly higher than those of L and ME (P<.05). CONCLUSION. Ceramic and composite polishing kits can be used for resin ceramics as a counterpart of glazing procedure used for full ceramic materials. Liquid polish has limited indications for resin ceramics.

• Korean Journal of Materials Research
• /
• v.20 no.10
• /
• pp.508-512
• /
• 2010

The optimum route to fabricate nano-sized Fe-50 wt% Co and hydrogen-reduction behavior of calcined Fe-/Conitrate was investigated. The powder mixture of metal oxides was prepared by solution mixing and calcination of Fe-/Co-nitrate. A DTA-TG and microstructural analysis revealed that the nitrates mixture by the calcination at $300^{\circ}C$ for 2 h was changed to Fe-oxide/$Co_3O_4$ composite powders with an average particle size of 100 nm. The reduction behavior of the calcined powders was analyzed by DTA-TG in a hydrogen atmosphere. The composite powders of Fe-oxide and Co3O4 changed to a Fe-Co phase with an average particle size of 40 nm in the temperature range of $260-420^{\circ}C$. In the TG analysis, a two-step reduction process relating to the presence of Fe3O4 and a CoO phase as the intermediate phase was observed. The hydrogen-reduction kinetics of the Fe-oxide/Co3O4 composite powders was evaluated by the amount of peak shift with heating rates in TG. The activation energies for the reduction, estimated by the slope of the Kissinger plot, were 96 kJ/mol in the peak temperature range of $231-297^{\circ}C$ and 83 kJ/mol of $290-390^{\circ}C$, respectively. The reported activation energy of 70.4-94.4 kJ/mol for the reduction of Fe- and Co-oxides is in reasonable agreement with the measured value in this study.

• Membrane Journal
• /
• v.24 no.6
• /
• pp.438-447
• /
• 2014

The amorphous and porous borosilicate without any cracks was obtained under the following condition : 0.01~ 0.10 mole ratio of trimethylborate (TMB)/ tetraethylorthosilicate (TEOS) and the temperature of $700{\sim}800^{\circ}C$. According to the BET and SEM measurements, borosilicate heat-treated in between 700 and $800^{\circ}C$ showed the surface area of $251.12{\sim}355.62m^2/g$, the pore diameter of 3.5~4.9 nm, and the particle size of 30~60 nm. According to the TGA measurements, the thermal stability of poly[1-(trimethylsilyl)propyne](PTMSP) membrane was enhanced by inserting borosilicate. SEM observation showed that the size of dispersed borosilicate in the composite membrane was $1{\mu}m$. The results showed that the permeability of $H_2$ and $N_2$ increased and the selectivity of $H_2/N_2$ decreased upon the addition of borosilicate into PTMSP membranes. Addition of borosilicate may possibly increase the free volume, cavity and porosity of membranes indicating that permeation occurred by molecular sieving, surface and Knudsen diffusion rather than solution diffusion of gases.

• Fire Science and Engineering
• /
• v.23 no.6
• /
• pp.135-141
• /
• 2009

The composite truss has been widely used for tall buildings and long-span structures in North America. As compared with other similar structures, it has merits such as reduction of construction period, low span/depth ratio, low dead weight and so on. It has the most effective trait for structures with long span of 12~18m. After collapse of WTC, the fire resistance behaviors of structures have been actively conducted under various fire conditions in several country. This study showed that the surface temperature of steel member in the composit truss beam was reached to $700^{\circ}C$ under the fire condition of a short time. Under the same condition, the temperature in concrete was within $200^{\circ}C$. The composit truss beam with 20mm bracing was collapsed by rapid deflection after about 3minutes. However, the beams with 25mm, 35mm, and 45mm bracing were not collapsed, even though those were reached to deflection standard of L/20 within 15minutes.

• Journal of the Korean institute of surface engineering
• /
• v.53 no.6
• /
• pp.293-299
• /
• 2020

The characteristics of the polycarbosilane (PCS)-based composite ceramic layer was studied by controlling the curing temperature. The stress at the interface of the graphite and SiOC composite layer was evaluated v ia finite element analysis. As a result, the tensile stress was released as the carbon ratio of the SiC decreases. In experiment, the SiOC layers were coated on the VDR graphite block by dip-coating process. It was revealed that the composition of Si and C was effectively adjusted depending on the curing temperature. As the solution-based process is employed, the surface roughness was reduced for the appropriate PCS curing temperature. Hence, it is expected that the cured SiOC layer can be utilized to reduce cracking and peeling of SiC ceramic composites on graphite mold by improving the interfacial stress and surface roughness.

• Composites Research
• /
• v.22 no.6
• /
• pp.32-38
• /
• 2009

In this study, the energy absorption capabilities and failure modes of four different kinds of circular tubes made of carbon, Kevlar and carbon-Kevlar hybrid composites with epoxy resin have been evaluated. In order to achieve these goals, these tubes were fabricated with unidirectional prepregs and compressive tests were conducted for the tubes under 10mm/min loading speed. From the test results, carbon/epoxy tubes were collapsed by brittle fracturing mode and showed the best energy absorption capabilities, while Kevlar/epoxy tubes were crushed by local buckling mode and worst. The hybrid [$90_C/0_K$] tubes were failed in a local bucking mode and showed good post crushing integrity, whereas [$90_K/0_C$] tubes were failed in a lamina bending mode and bad post crushing integrity.