• Journal of Powder Materials
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• v.9 no.2
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• pp.110-115
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• 2002

In order to obtain the nano size $10wt%Cu-TiO_2$composite powders by mechanical alloying method for useful composite catalysis, the effects of mechanical alloying time on the formationof $10wt%Cu-TiO_2$ composite powders were analyzed. The phase transformation behaviors were experimented as the heat treating temperature increased. Homogeneous 10wt% Cu-rutile type $TiO_2$composite powders were synthesized in 40 hours by mechanical alloying. After 60 hours mechanical alloying 50 nm size $TiO_2$powders were obtained. Both the phase of mechanically alloyed 10 wt% $Cu-TiO_2$ and pure $TiO_2$ powders were not transformed to anatase after annealing at the temperature range between 350 to 500 $^{\circ}C$. The intermetallic compound of $Cu_2Ti_4$O was formed after 10 hours mechanical alloying, however it could be considered that this intemetallic phase dose not prevent the transformation of rutile $TiO_2$ to the anatase phase after heat treatment at the temperature between 350 and $550^{\circ}C$.

• Journal of Korea Foundry Society
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• v.23 no.5
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• pp.244-250
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• 2003

The aim of this study is fabricating of composite filler metal (CFM) by a combination of selective laser sintering (SLS) of stainless steel powders (RapidSteel $2.0^{TM}$ and liquid phase infiltration of Ag-28 wt.%Cu alloy. Porous stainless steel body with inter-connected pore channels was fabricated by SLS, binder decomposing and densification processes. By the direct contact infiltration, the narrow inter-particle channels of the porous body were completely filled with the Ag-28 wt.%Cu alloy infiltrant. During infiltration, the dissolved elements of Fe, Ni and Cr from the porous body were solved into copper solid solution phases, which consist of eutectic structure of composite metal matrix. The S10C/CFM/S10C joints, which have narrow clearance gaps between them up to 10 micrometers, were joined successfully by self-feeding of filler metal from the matrix of CFM. The CFM kept its original thickness and microstructure after brazing. The tensile strength of brazed specimen was higher than 30 kgf/$mm^2$ and showed a typical ductile fracture mode in the CFM.

• Elastomers and Composites
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• v.50 no.4
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• pp.297-303
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• 2015

Ammonium polyphosphate-polyurethane foam composite (APP-PUF) was prepared from poly(adipate)diol/ammonium polyphosphate composite (f = 2), polyether polyol (f = 4.6), and PMDI (f = 2.5). As a blowing agent, $H_2O$ was used at various concentrations. The thermal decomposition behavior, morphology, closed-cell content, and density of APP-PUF were characterized. At the $H_2O$ concentrations lower than 3.5 php, the cell size of pure polyurethane foams (PUF) and APP-PUFs were close each other. As the $H_2O$ concentration became greater than 5.0 php, the cell size of the PUFs greatly increased compared to that of APP-PUFs. Addition of 1.5~1.9 wt% ammonium polyphosphate to the PUFs greatly enhanced the thermal stability of the PUFs, so 50 wt% residual temperature of APP-PUFs increased to $380{\sim}488^{\circ}C$, which were $30{\sim}70^{\circ}C$ higher than those of the PUFs. Thermal stability of the PUFs and APP-PUFs increased with $H_2O$ content and then decreased once $H_2O$ content exceeded 5 php.

• Korean Journal of Materials Research
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• v.16 no.10
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• pp.656-662
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• 2006

We fabricated thermal evaporated 10 nm-$Ni_xCo_{1-x}$ (x=0.2, 0.5 and 0.8) /(poly)Si films to form nanothick cobalt nickel composite silicides by a rapid thermal annealing at $700{\sim}1100^{\circ}C$ for 40 seconds. A field emission scanning electron microscope and a micro-Raman spectrometer were employed for microstructure and silicon residual stress characterization, respectively. We observed self-aligned micro-pinholes on single crystal silicon substrates silicidized at $1100^{\circ}C$. Raman silicon peak shift indicates that the residual tensile strain of $10^{-3}$ in single crystal silicon substrates existed after the silicide process. We propose thermal stress from silicide exothermic reaction and high temperature silicidation annealing may cause the pinholes. Those pinholes are expected to be avoided by lowering the silicidation temperature. Our results imply that we may use our newly proposed composite silicides to induce the appropriate strained layer in silicion substrates.

• Journal of the Korean Society of Propulsion Engineers
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• v.9 no.2
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• pp.46-53
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• 2005

We have analyzed the temperature and humidity aging test results of a composite solid propellant. The temperature aging test was performed to evaluate the storage life of a propellant, while the humidity aging test could provide the hygroscopicity of Ammonium Perchlorate(AP) exposed to .elative humidity (RH) 10, 30, $50\%$ environment. A specimen was used in the temperature test, and a block of propellant from the actual motor was used in the humidity test. We report that the 4-month storing at 60 degree is equivalent to the 10-year 60 degree condition. The composite solid propellant with HTPB binder showed signs of hardening with time lapse but the effect of humidity up to RH $50\%$ was not noticeable.

• Composites Research
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• v.30 no.5
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• pp.273-279
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• 2017

This paper describes the fabrication techniques and analysis of hybrid composite plates with an active frequency selective surface (FSS). For fabricating hybrid composite plate with active FSS, an active FSS with a resonance frequency located in the C band can obtained using varactor diodes. The hybrid composite plate was first designed and simulated to determine its electromagnetic properties using the commercial software HFSS. After simulation, active FSSs and hybrid composite plates were fabricated by mounting with varactor diodes. After fabrication, free space measurement was used to determine the electromagnetic properties of active FSS and the hybrid composite plates. The simulation and experimental results were in good agreement.

• Steel and Composite Structures
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• v.8 no.1
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• pp.35-52
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• 2008

The paper investigates the seismic performance of a Partially-Restrained (PR) steel-concrete composite frame using the probabilistic approach. The analysed frame was tested at the ELSA laboratory of the Joint Research Centre of Ispra (Italy), while the representative beam-to-column composite connections were tested at the Universities of Pisa, Milan and Trento (Italy). The component modelling of both interior and exterior composite joints is described first, including the experimental-numerical validation. The Latin Hypercube method has been used to draw the probabilistic distribution curves of joints, and then the whole PR composite frame has been analysed. Pushover and incremental dynamic analyses have been carried out using the non-linear FE code SAP2000 version 9.1. The fragility and performance curves of the PR composite frame have been determined for four damage limit states.

• Journal of the Korean Society for Nondestructive Testing
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• v.18 no.2
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• pp.112-120
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• 1998

A nondestructive evaluation technique was developed for the quantitative determination of the reinforcement volume fractions in particulate reinforced metal matrix composites. The proposed technique employed a composite micromechanics which accounts for the microstructure of the composite medium together with the measurement of anisotropic electrical conductivity. When the measured conductivity was coupled with the theoretically predicted conductivity, the unknown reinforcement volume fraction was calculated. An analytical model based on the Mori-Tanaka method was described which relates the NDE signatures to the composite microstructure. The volume fractions were calculated using eddy current measurements made on a wide range of silicon carbide particulate ($SiC_p$) reinforced aluminum (Al) matrix composites. The calculated $SiC_p$ volume fractions were in good agreement with the measured volume fractions in the range of 0-30%. The technique was also found to be effective in estimating the total volume percentage of reinforcement and intermetallic compound formed during the processing stage.

• The Journal of Advanced Prosthodontics
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• v.3 no.4
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• pp.186-189
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• 2011

PURPOSE. Porcelain fused to metal (PFM) crowns provide the best treatment option for teeth that have a large or defective restoration. More than 20% of teeth with PFM crowns or bridges require non-surgical root canal treatment (NSRCT). This may be due to the effect of restorative procedures and the possible leakage of bacteria and or their by-products, which leads to the demise of the tooth pulp. Thus, this study was planned to compare the ability of the restorative materials to seal perforated PFM specimens. MATERIALS AND METHODS. The study evaluates the ability of amalgam, composite or compomer restorative materials to close perforated PFM specimen's in-vitro. Ninety PFM specimens were constructed using Ni-Cr alloys and feldspathic porcelain, and then they were divided into 3 groups: amalgam (A), composite + Exite adhesive bond (B) and compomer + Syntac adhesive bond (C). All the PFM samples were embedded in an acrylic block to provide complete sealing of the hole from the bottom side. After the aging period, each group was further divided into 3 equal subgroups according to the thermocycling period (one week for 70 cycles, one month for 300 cycles and three months for 900 cycles). Each subgroup was put into containers containing dye (Pelikan INK), one maintained at $5^{\circ}C$ and the other at $55^{\circ}C$, each cycle for 30 sec time. The data obtained was analyzed by SPSS, 2006 using one way ANOVA test and student t-test and significant difference level at (P<.01). RESULTS. The depth of dye penetration was measured at the interfaces of PFM and filling materials using Co-ordinate Vernier Microscope. The lowest levels of the dye penetration for the three groups, as well as subgroups were during the first week. The values of dye leakage had significantly increased by time intervals in subgroups A and C. CONCLUSION. It was seen that amalgam showed higher leakage than composite while compomer showed the lowest level of leakage.

• Transactions of the Korean Society of Mechanical Engineers A
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• v.31 no.1 s.256
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• pp.121-128
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• 2007

Enhanced lower order shear deformation theory is developed in this study. Generally, lower order theories are not adequate to predict accurate deformation and stress distribution through the thickness of laminated plate. For the accurate prediction of detailed stress and deformation distributions through the thickness, higher order zigzag theories have been proposed. However, in most cases, simplified zigzag higher order theory requires $C_1$, shape functions in finite element implementation. In commercial FE softwares, $C_1$, shape functions are not so common in plate and shell analysis. Thus zigzag theories are useful for the highly accurate prediction of thick composite behaviors but they are not practical in the sense that they cannot be used conveniently in the commercial package. In practice, iso-parametric $C_0$ plate model is the standard model for the analysis and design of composite laminated plates and shells. Thus in the present study, an enhanced lower order shear deformation theory is developed. The proposed theory requires only $C_0$ shape function in FE implementation. The least-squared energy error between the lower order theory and higher order theory is minimized. An enhanced lower order shear deformation theory(ELSDT) in this paper is proposed for smart structure under complex loadings. The ELSDT is constructed by the strain energy transformation and fully coupled mechanical, electric loading cases are studied. In order to obtain accurate prediction, zigzag in-plane displacement and transverse normal deformation are considered in the deformation Held. In the electric behavior, open-circuit condition as well as closed-circuit condition is considered. Through the numerous examples, the accuracy and robustness of present theory are demonstrated.