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Phase Transformation Properties of Cu/TiO2 Photocatalyst Powders Fabricated by Mechanical Alloying

기계적 합금화법으로 제조된 Cu/TiO2 촉매용 분말의 상변화 특성

  • 안인섭 (경상대학교 재료공학부 및 공학연구원) ;
  • 배승열 (경상대학교 재료공학부 및 공학연구원) ;
  • 이영란 (경상대학교 재료공학부 및 공학연구원) ;
  • 고봉석 (경상대학교 재료공학부 및 공학연구원)
  • Published : 2002.04.01

Abstract

In order to obtain the nano size $10wt%Cu-TiO_2$composite powders by mechanical alloying method for useful composite catalysis, the effects of mechanical alloying time on the formationof $10wt%Cu-TiO_2$ composite powders were analyzed. The phase transformation behaviors were experimented as the heat treating temperature increased. Homogeneous 10wt% Cu-rutile type $TiO_2$composite powders were synthesized in 40 hours by mechanical alloying. After 60 hours mechanical alloying 50 nm size $TiO_2$powders were obtained. Both the phase of mechanically alloyed 10 wt% $Cu-TiO_2$ and pure $TiO_2$ powders were not transformed to anatase after annealing at the temperature range between 350 to 500 $^{\circ}C$. The intermetallic compound of $Cu_2Ti_4$O was formed after 10 hours mechanical alloying, however it could be considered that this intemetallic phase dose not prevent the transformation of rutile $TiO_2$ to the anatase phase after heat treatment at the temperature between 350 and $550^{\circ}C$.

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