• Title/Summary/Keyword: c/c composite

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A STUDY ON THE SHEAR BOND STRENGTH OF RESIN CEMENTS (수종 레진시멘트의 전단결합강도에 관한 연구)

  • Yang, Mi-Young;Park, Sang-Jin
    • Restorative Dentistry and Endodontics
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    • v.22 no.1
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    • pp.132-143
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    • 1997
  • Recently composite resin luting cement have been widely used according as esthetic requirement was increased. The purpose of this study was to evaluate of shear bond strength of four resin cements to bovine dentin. The materials used in this study were All-Bond 2(dentin bonding agent), Duolink cement, Bistite resin cement, Twinlook cement, Clearfil CR inlay cement. A total 40 acrylic cylinders with bovine dentin were divided into four groups. Four experimental groups were as follows; Group l(AB) : Specimens bonded with All-Bond 2 and Duolink Cement Group 2(BT) : Specimens bonded with Bistite Resin Cement Group 3(TL) : Specimens bonded with Twinlook Cement Group 4(CR) : Specimens bonded with Clearfil CR Inlay Cement Mter 1 hour of bonding, all specimens were stored for 24 hours in water at $37^{\circ}C$ and tested with Instron universal testing machine between bovine dentin and resin cements. The data were evaluated statistically at the 95% confidence level with a one-way analysis of variance and Tukey's range statistics. The following results obtained; 1. The group l(AB) was highest shear bond strength and the group 3(TL) was 10west(p>0.05). 2. Group 2(BT), 4(CR) were similar shear bond strength and there was no significant difference(p<0.05). 3. Group 1(AB), 4(CR) with acid etching were showed resin tags on the opened dentinal tubules, but Group 2(BT), 3(TL) without acid etching were not showed resin tags. 4. Group l(AB) was showed intimate adaptation than other groups.

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Modeling and Characteristics of Ethanol Fermentation Process Combined with Pervaporation (투과증발과 결합된 에탄올 발효 공정의 모델링 및 특성)

  • 최은수;김진현;유영제
    • Microbiology and Biotechnology Letters
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    • v.20 no.4
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    • pp.451-458
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    • 1992
  • Pervaporation which is capable of removing ethanol selectively was adopted to reduce the ethanol inhibition and in situ recovery of ethanol in ethanol fermentation, The composite membrane made of silicone and polysulfone was used to separate the ethanol selectively. The ethanol selectivity of the membrane was about 4 and the total flux was 300 g/m2 h at 301:: and 10 mmHg for 25 g/l of feed concentration. Saccharomyces cerevisiae entrapped within Ca-alginate gels was employed for ethanol fermentations in a fluidized-bed bioreactor. The pervaporation membrane unit and fluidized-bed bioreactor were combined into one system. The proposed model equations for the combined system showed good accordances with the experimental results. It was found from the simulation results that the ethanol concentration in the broth for the combined system was lower than that for the continuous fermentation system without a membrane unit. Ethanol productivity can be thus increased by employing the combined system.

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Prediction of Genes Related to Positive Selection Using Whole-Genome Resequencing in Three Commercial Pig Breeds

  • Kim, HyoYoung;Caetano-Anolles, Kelsey;Seo, Minseok;Kwon, Young-jun;Cho, Seoae;Seo, Kangseok;Kim, Heebal
    • Genomics & Informatics
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    • v.13 no.4
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    • pp.137-145
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    • 2015
  • Selective sweep can cause genetic differentiation across populations, which allows for the identification of possible causative regions/genes underlying important traits. The pig has experienced a long history of allele frequency changes through artificial selection in the domestication process. We obtained an average of 329,482,871 sequence reads for 24 pigs from three pig breeds: Yorkshire (n = 5), Landrace (n = 13), and Duroc (n = 6). An average read depth of 11.7 was obtained using whole-genome resequencing on an Illumina HiSeq2000 platform. In this study, cross-population extended haplotype homozygosity and cross-population composite likelihood ratio tests were implemented to detect genes experiencing positive selection for the genome-wide resequencing data generated from three commercial pig breeds. In our results, 26, 7, and 14 genes from Yorkshire, Landrace, and Duroc, respectively were detected by two kinds of statistical tests. Significant evidence for positive selection was identified on genes ST6GALNAC2 and EPHX1 in Yorkshire, PARK2 in Landrace, and BMP6, SLA-DQA1, and PRKG1 in Duroc. These genes are reportedly relevant to lactation, reproduction, meat quality, and growth traits. To understand how these single nucleotide polymorphisms (SNPs) related positive selection affect protein function, we analyzed the effect of non-synonymous SNPs. Three SNPs (rs324509622, rs80931851, and rs80937718) in the SLA-DQA1 gene were significant in the enrichment tests, indicating strong evidence for positive selection in Duroc. Our analyses identified genes under positive selection for lactation, reproduction, and meat-quality and growth traits in Yorkshire, Landrace, and Duroc, respectively.

Preparation of Pt Catalysts Supported on ACF with CNF via Catalytic Growth

  • Park, Sang-Sun;Rhee, Jun-Ki;Jeon, Yu-Kwon;Choi, Sung-Won;Shul, Yong-Gun
    • Carbon letters
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    • v.11 no.1
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    • pp.38-40
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    • 2010
  • Carbon supported electrocatalysts are commonly used as electrode materials for polymer electrolyte membrane fuel cells(PEMFCs). These kinds of electrocatalysts provide large surface area and sufficient electrical conductivity. The support of typical PEM fuel cell catalysts has been a traditional conductive type of carbon black. However, even though the carbon particles conduct electrons, there is still significant portion of Pt that is isolated from the external circuit and the PEM, resulting in a low Pt utilization. Herein, new types of carbon materials to effectively utilize the Pt catalyst are being evaluated. Carbon nanofiber/activated carbon fiber (CNF/ACF) composite with multifunctional surfaces were prepared through catalytic growth of CNFs on ACFs. Nickel nitrate was used as a precursor of the catalyst to synthesize carbon nanofibers(CNFs). CNFs were synthesized by pyrolysising $CH_4$ using catalysts dispersed in acetone and ACF(activated carbon fiber). The as-prepared samples were characterized with transmission electron microscopy(TEM), scanning electron microscopy(SEM). In TEM image, carbon nanofibers were synthesized on the ACF to form a three-dimensional network. Pt/CNF/ACF was employed as a catalyst for PEMFC. As the ratio of prepared catalyst to commercial catalyst was changed from 0 to 50%, the performance of the mixture of 30 wt% of Pt/CNF/ACF and 70wt% of Pt/C commercial catalyst showed better perfromance than that of 100% commercial catalyst. The unique structure of CNF can supply the significant site for the stabilization of Pt particles. CNF/ACF is expected to be promising support to improve the performance in PEMFC.

Magnetic Properties of $\alpha$-Fe Based Nd-Fe-B Nanocrystalline with High Remanence (고잔류자화 $\alpha$-Fe기 Nd-Fe-B 초미세결정립 합금의 자기특성)

  • 조용수;김윤배;박우식;김창석;김택기
    • Journal of the Korean Magnetics Society
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    • v.5 no.1
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    • pp.38-41
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    • 1995
  • The effects of Nb and Cu additives as will as substitutional Co into $Nd_{4}Fe_{85.5}B_{10.5}$ melt-spun alloy were studied aiming for finding a $\alpha$-Fe based Nd-Fe-B composite alloys with high energy product. The addition of Nb and Cu to $Nd_{4}Fe_{85.5}B_{10.5}$ decreased the average grain size and increased the coercivity up to 207kA/m(2.6kOe), Further-more, the substitution of Co for Fe in $Nd_{4}Fe_{82}B_{10}Nb_{3}Cu_{1}$ alloy resulted in the decrease of the average grain size (<20nm) and improved the hard magnetic properties. The remanence, coercivity and energy product of optimally annealed $Nd_{4}Fe_{74}Co_{8}B_{10}Nb_{3}Cu_{1}$ alloy were 1.345, 219kA/m(2.75kOe) and $95.5kJ/m^{3}$(12MGOe), respectively.

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Investigation of stiffening scheme effectiveness towards buckling stability enhancement in tubular steel wind turbine towers

  • Stavridou, Nafsika;Efthymiou, Evangelos;Gerasimidis, Simos;Baniotopoulos, Charalampos C.
    • Steel and Composite Structures
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    • v.19 no.5
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    • pp.1115-1144
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    • 2015
  • Current climate conditions along with advances in technology make further design and verification methods for structural strength and reliability of wind turbine towers imperative. Along with the growing interest for "green" energy, the wind energy sector has been developed tremendously the past decades. To this end, the improvement of wind turbine towers in terms of structural detailing and performance result in more efficient, durable and robust structures that facilitate their wider application, thus leading to energy harvesting increase. The wind tower industry is set to expand to greater heights than before and tapered steel towers with a circular cross-section are widely used as more capable of carrying heavier loads. The present study focuses on the improvement of the structural response of steel wind turbine towers, by means of internal stiffening. A thorough investigation of the contribution of stiffening rings to the overall structural behavior of the tower is being carried out. These stiffening rings are placed along the tower height to reduce local buckling phenomena, thus increasing the buckling strength of steel wind energy towers and leading the structure to a behavior closer to the one provided by the beam theory. Additionally to ring stiffeners, vertical stiffening schemes are studied to eliminate the presence of short wavelength buckles due to bending. For the purposes of this research, finite element analysis is applied in order to describe and predict in an accurate way the structural response of a model tower stiffened by internal stiffeners. Moreover, a parametric study is being performed in order to investigate the effect of the stiffeners' number to the functionality of the aforementioned stiffening systems and the improved structural behavior of the overall wind converter.

TiO2 Combining Spherical Activated Carbon Photocatalysts and Their Physicochemical and Photocatalytic Activity

  • Oh, Won-Chun;Kim, Jong-Gyu;Kim, Hyuk;Chen, Ming-Liang;Zhang, Feng-Jun;Zhang, Kan;Choi, Jong-Geun;Meng, Ze-Da
    • Korean Journal of Materials Research
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    • v.20 no.10
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    • pp.535-542
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    • 2010
  • In this study, we used coal-based activated carbons and charcoal as startingmaterials, phenolic resin (PR) as a binder, and TOS as a titanium source to prepare $TiO_2$ combining spherical shaped activated carbon photocatalysts. The textural properties of the activated carbon photocatalysts (SACP) were characterized by specific surface area (BET), energy dispersive X-ray spectroscopy (XRD), scanning electron microscopy (SEM), iodine adsorption, strength intensity, and pressure drop. The photocatalytic activities of the SACPs were characterized by degradation of the organic dyes Methylene Blue (MB), Methylene Orange (MO), and Rhodamine B (Rh. B) and a chemical oxygen demand (COD) experiment. The surface properties are shown by SEM. The XRD patterns of the composites showed that the SACP composite contained a typical single, clear anatase phase. The EDX spectro for the elemental indentification showed the presence of C and O with Ti peaks. According to the results, the spherical activated carbon photocatalysts sample of AOP prepared with activated carbon formed the best spherical shape, a high BET surface area, iodine adsorption capability and strength value, and the lowest pressure drop, and the photocatalytic activity was better than samples prepared with charcoal. We compared the degradation effects among three kinds of dyes. MB solution degraded with the SACP is better than any other dye solutions.

A study on Manufacture of EMI Composite Powder by the Electroless Ni Plating Method (무전해 니켈도금방법을 이용한 EMI 복합분말제조에 관한 연구)

  • Joung, I.;Yoon, S.R.;Han, S.N.;Na, J.H.;Kim, C.W.
    • Korean Journal of Materials Research
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    • v.8 no.5
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    • pp.444-449
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    • 1998
  • There are various shielding materials that have been considered; the use of a metallic plate or the layering of a conductive material on a plastic surface and the insertion of filler in plastics. All of these methods have shown their merits and weakness. Therefore, many studies have concentrated on developing materials that effectively cut down EMI without increase in weights of housing materials. In these respects, this study has focused on investigations of the shielding effect of materials that have electroless nickel plating on the lamella structured micro particles surface with low specific gravity. When a film of electroless nickel were plated on a micro particle surfaces and then mixed with paint, the electromagnetic shielding effects were measured as 63dB. Although these effects were less than that 90dB of the copper plate, trials in a series of 6 times increased the shielding effect by IOdB and is applicable to wide range of EMI shielding.

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Electrospun Non-Directional Zinc Oxide Nanofibers as Nitrogen Monoxide Gas Sensor (전기방사법에 의해 합성된 무방향성 산화아연 나노섬유의 일산화질소 가스 감지 특성)

  • Kim, Ok-Kil;Kim, Hyojin;Kim, Dojin
    • Korean Journal of Materials Research
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    • v.22 no.11
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    • pp.609-614
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    • 2012
  • We report on the NO gas sensing properties of non-directional ZnO nanofibers synthesized using a typical electrospinning technique. These non-directional ZnO nanofibers were electrospun on an $SiO_2$/Si substrate from a solution containing poly vinyl alcohol (PVA) and zinc nitrate hexahydrate dissolved in distilled water. Calcination processing of the ZnO/PVA composite nanofibers resulted in a random network of polycrystalline ZnO nanofibers of 50 nm to 100 nm in diameter. The diameter of the nanofibers was found to depend primarily on the solution viscosity; a proper viscosity was maintained by adding PVA to fabricate uniform ZnO nanofibers. Microstructural measurements using scanning electron microscopy revealed that our synthesized ZnO nanofibers after calcination had coarser surface morphology than those before calcination, indicating that the calcination processing was sufficient to remove organic contents. From the gas sensing response measurements for various NO gas concentrations in dry air at several working temperatures, it was found that gas sensors based on electrospun ZnO nanofibers showed quite good responses, exhibiting a maximum sensitivity to NO gas in dry air at an operating temperature of $200^{\circ}C$. In particular, the non-directional electrospun ZnO nanofiber gas sensors were found to have a good NO gas detection limit of sub-ppm levels in dry air. These results illustrate that non-directional electrospun ZnO nanofibers are promising for use in low-cost, high-performance practical NO gas sensors.

Fabrication of Zn-treated ACF/TiO2 Composites and Their Photocataytic Activity for Degradation of Methylene Blue

  • Go, Yu-Gyoung;Zhang, Feng-Jun;Chen, Ming-Liang;Oh, Won-Chun
    • Korean Journal of Materials Research
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    • v.19 no.3
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    • pp.142-150
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    • 2009
  • In this paper, non-treated ACF (Activated Carbon Fiber) /$TiO_2$ and Zn-treated ACF/$TiO_2$ were prepared. The prepared composites were characterized in terms of their structural crystallinity, elemental identification and photocatalytic activity. XRD patterns of the composites showed that the non-treated ACF/$TiO_2$ composite contained only typical single and clear anatase forms while the Zn-treated ACF/$TiO_2$ contained a mixed anatase and rutile phase with a unique ZnO peak. SEM results show that the titanium complex particles are uniformly distributed on and around the fiber and that the titanium complex particles are more regularly distributed on and around the ACF surfaces upon an increase of the $ZnCl_2$ concentration. These EDX spectra show the presence of peaks from the C, O and Ti elements. Moreover, peaks of the Zn element were observed in the Zn-treated ACF/$TiO_2$ composites. The prominent photocatalytic activity of the Zn-treated ACF/$TiO_2$ can be attributed to the three different effects of photo-degradation: doping, absorptivity by an electron transfer, and adsorptivity of porous ACFs between the Zn-$TiO_2$ and Zn-ACF.