• Title/Summary/Keyword: c/c composite

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Preparation of novel NF membrane via interfacial cross-linking polymerization

  • Lehi, Arash Yunessnia;Akbari, Ahmad;Soleimani, Hosna
    • Membrane and Water Treatment
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    • v.6 no.3
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    • pp.173-187
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    • 2015
  • The goal of present work is the preparation of a novel positively charged nanofiltration (NF) membrane and its development for the cation removal of aqueous solutions. This NF membrane was fabricated by the surface modification of polysulfone (PSf) ultrafiltration support. The active top-layer was formed by interfacial cross-linking polymerization of poly(ethyleneimine) (PEI) with p-xylylene dichloride (XDC) and then quaternized with methyl iodide to form a perpetually positively charged layer. In order to improve the efficiency of nanofiltration membrane, the concentration of PEI, XDC and methyl iodide solutions, PEI coating and cross-linking time have been optimized. As a result, a high water flux and high $CaCl_2$ rejection (1,000 ppm) was obtained for the composite membrane with values of $18.29L/m^2.h$ and 93.62% at 4 bar and $25^{\circ}C$, respectively. The rejections of NF membrane for different salt solutions followed the order of $Na_2SO_4$ < $MgSO_4$ < NaCl < $CaCl_2$. Molecular weight of cut off (MWCO) was calculated via retaining of PEG solutions with different molecular weights that finally, it revealed the Stokes and hydrodynamic radius of 1.457 and 2.507 nm on the membrane selective layer, respectively. The most efficient positively charged nanofiltration membrane exhibited a $Ni^{2+}$ rejection of 96.26% for industrial wastewater from Shamse Hadaf Co. (Kashan, Iran).

Behaviour of axially loaded RC columns strengthened by steel angles and strips

  • Adam, J.M.;Ivorra, S.;Gimenez, E.;Moragues, J.J.;Miguel, P.;Miragall, C.;Calderon, P.A.
    • Steel and Composite Structures
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    • v.7 no.5
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    • pp.405-419
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    • 2007
  • This paper presents the development of some numerical models based on the results of laboratory tests performed on axially loaded RC columns strengthened with steel angles and strips. These numerical models consider the nonlinearity of the building materials and the effects of the contact interfaces between different materials. The results of the finite element models accurately describe the general behaviour of the strengthened columns. This study allows engineers to assess the relative importance of the mechanisms acting on the strengthened RC columns. Constructive recommendations are also provided in this paper.

Shear strengthening of RC beams with Basalt Fiber Reinforced Polymer (BFRP) composites

  • Kar, S.;Biswal, K.C.
    • Advances in concrete construction
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    • v.10 no.2
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    • pp.93-104
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    • 2020
  • Basalt fiber is an eco-friendly fiber and comparatively newer to the world of fiber-reinforced polymer (FRP) composites. A limited number of studies have been reported in the literature on the strengthening of reinforced concrete (RC) beams with basalt fiber reinforced polymer (BFRP). The present experimental work explores the feasibility of using the BFRP strips for shear strengthening of the RC beams. The strengthening schemes include full wrap and U-wrap. A simple mechanical anchorage scheme has been introduced to prevent the debonding of U-wrap as well as to utilize the full capacity of the BFRP composite. The effect of varying shear span-to-effective depth (a/d) ratio on the behavior of shear deficient RC beams strengthened with BFRP strips under different schemes is examined. The RC beams were tested under a four-point loading system. The study finds that the beams strengthened with and without BFRP strips fails in shear for a/d ratio 2.5 and the enhancement of the shear capacity of strengthened beams ranges from 5% to 20%. However, the strengthened beams fail in flexure, and the control beam fails in shear for a higher a/d ratio, i.e., 3.5. The experimental results of the present study have been compared with the analytical study and found that the latter gives conservative results.

Structural and Magnetic Properties of LiZnO Added MgFe2O4 Composite

  • Tadi, Ravindar;Kim, Yong-Il;Kim, Cheol-Gi;Ryu, Kwon-Sang
    • Journal of Magnetics
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    • v.15 no.4
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    • pp.165-168
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    • 2010
  • $Li_{0.1}Zn_{0.9}O$ and $MgFe_2O_4$ powders were synthesized using chemical methods and mixed in different proportions to prepare a mixture of $Li_{0.1}Zn_{0.9}O$ and $MgFe_2O_4$ that was thermally treated between 900 to $1100^{\circ}C$ for 1 hour. Structural characterization was done using X-ray powder diffraction measurements. Grain sizes and morphologies of $Li_{0.1}Zn_{0.9}O$, $MgFe_2O_4$, and $Li_{0.1}Zn_{0.9}O+MgFe_2O_4$ samples were observed using a scanning electron microscope. Variation of magnetic properties of the $Li_{0.1}Zn_{0.9}O+MgFe_2O_4$ samples due to the addition of $Li_{0.1}Zn_{0.9}O$ was studied in relation to the structural changes occurring due to the thermal treatment. In particular, changes in the cationic distribution between the tetrahedral and octahedral positions were studied with respect to the increase of the annealing temperature. Magnetization was found to be dependent on the cations distributed in the tetrahedral and octahedral sites of the $MgFe_2O_4$.

A Nano-power Switched-capacitor Voltage Reference Using MOS Body Effect for Applications in Subthreshold LSI

  • Zhang, Hao;Huang, Meng-Shu;Zhang, Yi-Meng;Yoshihara, Tsutomu
    • JSTS:Journal of Semiconductor Technology and Science
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    • v.14 no.1
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    • pp.70-82
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    • 2014
  • A nano-power CMOS voltage reference is proposed in this paper. Through a combination of switched-capacitor technology with the body effect in MOSFETs, the output voltage is defined as the difference between two gate-source voltages using only a single PMOS transistor operated in the subthreshold region, which has low sensitivity to the temperature and supply voltage. A low output, which breaks the threshold restriction, is produced without any subdivision of the components, and flexible trimming capability can be achieved with a composite transistor, such that the chip area is saved. The chip is implemented in $0.18{\mu}m$ standard CMOS technology. Measurements show that the output voltage is approximately 123.3 mV, the temperature coefficient is $17.6ppm/^{\circ}C$, and the line sensitivity is 0.15 %/V. When the supply voltage is 1 V, the supply current is less than 90 nA at room temperature. The area occupation is approximately $0.03mm^2$.

Welded plate and T-stub tests and implications on structural behavior of moment frame connections

  • Dong, P.;Kilinski, T.
    • Steel and Composite Structures
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    • v.2 no.1
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    • pp.35-50
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    • 2002
  • A series of tests on simple-welded plate specimens (SWPS) and T-stub tension specimens simulating some of the joint details in moment frame connections were conducted in this investigation. The effects of weld strength mismatch and weld metal toughness on structural behavior of these specimens were considered under both static and dynamic loading conditions. Finite element analyses were performed by taking into account typical weld residual stress distributions and weld metal strength mismatch conditions to facilitate the interpretation of the test results. The major findings are as follows: (a) Sufficient specimen size requirements are essential in simulating both load transfer and constraint conditions that are relevant to moment frame connections, (b) Weld residual stresses can significantly elevate stress triaxiality in addition to structural constraint effects, both of which can significantly reduce the plastic deformation capacity in moment frame connections, (c) Based on the test results, dynamic loading within a loading rate of 0.02 in/in/sec, as used in this study, premature brittle fractures were not seen, although a significant elevation of the yield strength can be clearly observed. However, brittle fracture features can be clearly identified in T-stub specimens in which severe constraint effects (stress triaxiality) are considered as the primary cause, (d) Based on both the test and FEA results, T-stub specimens provide a reasonable representation of the joint conditions in moment frame connections in simulating both complex load transfer mode and constraint conditions.

A simplified analysis of catenary action in steel beams in fire and implications on fire resistant design

  • Wang, Y.C.;Yin, Y.Z.
    • Steel and Composite Structures
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    • v.6 no.5
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    • pp.367-386
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    • 2006
  • This paper describes the results of a numerical investigation of the large deflection behaviour of steel beams under fire conditions, taking into consideration the effect of catenary action provided by the surrounding structures. The main focus is on the development, validation and application of a simplified calculation method that may be adopted in design calculations. Because no experimental result is available for validation of the simplified calculation method, the finite element program ABAQUS has been used to simulate the large deflection behaviour of a number of steel beams so as to provide alternative results for validation of the proposed method. Utilising catenary action has the potential of eliminating fire protection to all steel beams without causing structural failure in fire. However, practical application of catenary action will be restricted by concerns over large beam deflection causing integrity failure of the fire resistant compartment and additional cost of strengthening the connections and the surrounding structures to resist the catenary forces in the steel beams. This paper will provide a discussion on practical implications of utilising catenary action in steel beams as a means of eliminating fire protection. A number of examples will then be provided to illustrate the type of steel framed structure that could benefit the most from exploiting catenary action in fire resistant design.

Axial behavior of RC columns strengthened with SCC filled square steel tubes

  • Lu, Yi-Yan;Liang, Hong-Jun;Li, Shan;Li, Na
    • Steel and Composite Structures
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    • v.18 no.3
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    • pp.623-639
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    • 2015
  • Self-compacting Concrete (SCC) Filled Square steel Tubes (SCFST) was used to strengthen square RC columns. To establish the efficiency of this strengthening method, 17 columns were tested under axial compression loading including 3 RC columns without any strengthening (WRC), 1 RC column strengthened with concrete jacket (CRC), 13 RC columns strengthened with self-compacting concrete filled square steel tubes (SRC). The experimental results showed that the use of SCFST is interesting since the ductility and the bearing capacity of the RC columns are greatly improved. The improvement ratio is significantly affected by the nominal wall thickness of steel tubes (t), the strength grade of strengthening concrete (C), and the length-to-width ratio (L / B) of the specimens. In order to quantitatively analyze the effect of these test parameters on axial loading behavior of the SRC columns, three performance indices, enhancement ratio (ER), ductility index (DI), and confinement ratio (CR), were used. The strength of the SRC columns obtained from the experiments was then employed to verify the proposed mode referring to the relevant codes. It was found that codes DBJ13-51 could relatively predict the strength of the SRC columns accurately, and codes AIJ and BS5400 were relatively conservative.

Magnetic Properties of Multilayered and Mixed $Pr_{0.65}$Ca_{0.35}MnO_3/La_{0.7}Sr_{0.3}MnO_3$ Films

  • V. G. Prokhorov;Lee, Y. P.;V. S. Flis;Park, J. S.
    • Journal of the Korean Vacuum Society
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    • v.12 no.S1
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    • pp.67-69
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    • 2003
  • The magnetic properties of single- and poly-crystalline $La_{0.7}Sr_{0.3}MnO_3/Pr_{0.65}Ca_{0.35}MnO_3$ multilayered (ML) films, and composite (CP) $(La_{0.7}Sr_{0.3})_{0.5}(Pr_{0.65}Ca_{0.35}_{0.5}MnO_3$ films, prepared by laser ablation, have been investigated in a wide temperature range. It was shown that the transformation from an incoherent to a coherent interface in the ML films leads to an enhancement of the ferromagnetic coupling between layers and to a single-phase magnetic transition. The amorphous CP films demonstrate a paramagnetic behavior of the magnetization with a sharp peak at $T_{G}\approx$45 K, which was interpreted as the formation of Griffiths phase. A short-term annealing at $750^{\circ}C$ induced the complete crystallization of film, and a recovery of the ferromagnetic and the metal-insulator transitions.

Performance Characteristics of Anode-Supported Tubular Solid Oxide Fuel Cell (연료극 지지체식 원통형 고체산화물 연료전지의 성능 특성)

  • Song Rak-Hyun;Song Keun-Suk
    • Korean Journal of Materials Research
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    • v.14 no.5
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    • pp.368-373
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    • 2004
  • To improve the conventional cathode-supported tubular solid oxide fuel cell (SOFC) from the viewpoint of low cell power density, expensive fabrication process and high operation temperature, the anode-supported tubular solid oxide fuel cell was investigated. The anode tube of Ni-8mol% $Y_2$O$_3$-stabilized $ZrO_2$ (8YSZ) was manufactured by extrusion process, and, the electrolyte of 8YSZ and the multi-layered cathode of $LaSrMnO_3$(LSM)ILSM-YSZ composite/$LaSrCoFeO_3$ were coated on the surface of the anode tube by slurry dip coating process, subsequently. Their cell performances were examined under gases of humidified hydrogen with 3% water and air. In the thermal cycle condition of heating and cooling rates with $3.33^{\circ}C$/min, the anode-supported tubular cell showed an excellent resistance as compared with the electrolyte-supported planar cell. The optimum hydrogen flow rate was evaluated and the air preheating increased the cell performance due to the increased gas temperature inside the cell. In long-term stability test, the single cell indicated a stable performance of 300 mA/$\textrm{cm}^2$ at 0.85 V for 255 hr.