• 한국재료학회지
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• 제34권6호
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• pp.275-282
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• 2024

In this work, we investigated the photo-degradation performance of MnO₂-SiC fiber-TiO₂ (MnO₂-SiC-TiO₂) ternary nanocomposite according to visible light excitation utilizing methylene blue (MB) and methyl orange (MO) as standard dyes. The photocatalytic physicochemical characteristics of this ternary nanocomposite were described by X-ray diffraction (XRD), scanning electron microscopy (SEM), tunneling electron microscopy (TEM), ultraviolet-visible (UV-vis), diffuse reflectance spectroscopy (DRS), electrochemical impedance spectroscopy (EIS), photocurrent and cyclic voltammogram (CV) test. Photolysis studies of the synthesized MnO₂-SiC-TiO₂ composite were conducted using standard dyes of MB and MO under UV light irradiation. The experiments revealed that the MnO₂-SiC-TiO₂ exhibits the greatest photocatalytic dye degradation performance of around 20 % with MB, and of around 10 % with MO, respectively, within 120 min. Furthermore, MnO₂-SiC-TiO₂ showed good stability against photocatalytic degradation. The photocatalytic efficiency of the nanocomposite was indicated by the adequate photocatalytic reaction process. These research results show the practical application potential of SiC fibers and the performance of a photocatalyst composite that combines these fibers with metal oxides.

• The Korean Journal of Ceramics
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• 제3권1호
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• pp.52-56
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• 1997

The Pt doped $TiO_2$ composite membranes were prepared by the sol-gel process. The Pt doped titania sol was peptized with hydrochloric acid in the pH range of 1.23 to 1.32 at 5$0^{\circ}C$. The average particle size of the Pt doped titania sol was shown to be below 15nm and well dispersed in the solution. XPS show the Pt elements continuous and homogeneous dispersed in the $TiO_2$ membrane. The mean particle size of the Pt doped $TiO_2$ composite membrane has smaller than that of the undoped $TiO_2$ composite membrane. The average pore size of the Pt doped $TiO_2$ composite membrane was increased from 58 to 193 $\AA$ with firing temperature changed from 550 to 85$0^{\circ}C$. It was observed that the Pt doped $TiO_2$ composite membranes showed crack-free and homogeneous microstructue as well as narrow particle size distribution up to above 75$0^{\circ}C$.

• 한국재료학회지
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• 제12권11호
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• pp.883-888
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• 2002

We investigated the void formation in composite-titanium silicide($TiSi_2$) process. We varied the process conditions of polycrystalline/amorphous silicon substrate, composite $TiSi_2$ deposition temperature, and silicidation annealing temperature. We report that the main reason for void formation is the mass transport flux discrepancy of amorphous silicon substrate and titanium in composite layer. Sheet resistance in composite $TiSi_2$ without patterns is mainly affected by silicidation rapid thermal annealing (RTA) temperature. In addition, sheet resistance does not depend on the void defect density. Sheet resistance with sub-0.5 $\mu\textrm{m}$ patterns increase abnormally above $850^{\circ}C$ due to agglomeration. Our results imply that $sub-750^{\circ}C$ annealing is appropriate for sub 0.5 $\mu\textrm{m}$ composite X$sub-750_2$ process.

• 한국표면공학회지
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• 제40권6호
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• pp.279-282
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• 2007

Cr-Mo-Si-C-N coatings were deposited on steel and Si wafer by a hybrid system of AIP and sputtering techniques using Cr, Mo and Si target in $Ar/N_2/CH_4$ gaseous mixture. Instrumental analyses of XRD and XPS revealed that the Cr-Mo-Si-C-N coatings must be a composite consisting of fine(Cr, Mo and Si)(C and N) crystallites and amorphous $Si_3N_4$ and SiC. The hardness value of Cr-Mo-Si-C-N coatings significantly increased from 41 GPa of Cr-Mo-C-N coatings to about 53 GPa with Si content of 9.3 at.% due to the refinement of (Cr, Mo and Si)(C and N) crystallites and the composite microstructure characteristics. A systematic investigation of the microstructures and mechanical properties of Cr-Mo-Si-C-N coatings prepared with various Si contents is reported in this paper.

• 한국세라믹학회지
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• 제43권10호
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• pp.660-665
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• 2006

The mechanical properties of $Al_2O_3$-SiC composites manufactured with adding various amount and size of SiC particles have been measured and analyzed. Generally, the elastic modulus of the composites shows about 50% less than that of PL-8 (45 wt% $Al_2O_3$-51 wt% $SiO_2$-4 wt% other oxides), but the flexural strength is similar with each other. The impact resistance property of $Al_2O_3$-SiC composite against high velocity copper jet was lower than that of PL-8 when SiC particles of approximately 3 $\mu$m diameter was added to. It is caused probably due to the micro-pores made by oxidation of SiC particles. However, in the case of the less-weighted $Al_2O_3$-SiC composite adding to 10 wt% SiC with average diameter of 10 $\mu$m and sintering at 1200$^{\circ}C$, the impact resistance property was improved up to 37 percent compared with that of PL-8.

• 한국재료학회:학술대회논문집
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• 한국재료학회 2001년도 추계 학술발표강연 및 논문개요집
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• pp.133-133
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• 2001

• 유기물자원화
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• 제12권4호
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• pp.95-104
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• 2004

본 연구에서는 가연성 건설폐기물 재활용의 일환으로, 폐발포폴리스티렌의 스티렌 용액에 가교제 및 개시제를 첨가하여 제조한 결합재와, 폐목재 칩을 이용하여, 폐목재-플라스틱 복합패널을 제조하였다. 전열 프레스를 이용하여 다양한 결합재량 및 충전재-결합재 비를 갖는 복합패널 공시체를 제조하였으며, 그 겉보기 밀도, 흡수율, 흡수에 의한 팽창률, 휨강도, 내수성 등에 관한 일련의 실험을 행하였다. 폐목재-플라스틱 복합패널의 겉보기밀도는 결합재량 및 충전재-결합재비의 증가에 따라 증대하며, 그 휨강도 및 습윤 휨강도는, 결합재량 35%, 충전재-결합재비 0.8에 있어서 최대치에 이른다. 흡수율 및 흡수에 의한 두께 팽창률은, 결합재량 및 충전재-결합재비의 증가에 따라 현저하게 감소한다. 결합재량 30%이상의 경우, 충전재-결합재비에 관계없이, 복합패널의 24h 상온 수중($20^{\circ}C$) 침지 및 2h 끓는 물중($100^{\circ}C$)＋1h상온 수중($20^{\circ}C$) 침지에 의한 휨강도의 감소는 거의 발생하지 않으며, 높은 내수성을 발현한다.

• 한국가스학회지
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• 제15권1호
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• pp.30-34
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• 2011

본 논문은 104L의 저장용량과 70MPa의 사용압력을 갖는 수소연료탱크용 복합소재 압력용기에 관한 강도안전성을 해석한 평가연구이다. 탄소섬유 복합용기의 내측은 6061-T6의 알루미늄 라이너를 사용하고, 외경측은 원주방향을 따라서 탄소섬유 후프층을 형성하고, 또한 $12^{\circ}C$ 적층과 $70^{\circ}C$ 적층을 헤리컬방향으로 경사지게 감아서 제작하였다. 복합소재 연료탱크의 강도안전성에 대한 FEM 해석결과는 US DOT-CFFC와 KS B ISO 11119-2 규정에 따라 평가되었다. FEM 해석결과에 의하면, 104L의 복합용기로 제시된 설계모델을 US DOT-CFFC와 KS B ISO 11119-2 기준으로 평가할 때 모두 안전하다할 수 있다. 그렇지만, 탄소섬유 연료탱크에 대한 계산결과는 한국의 평가기준을 사용하기보다는 미국의 안전기준을 적용하는 것이 더 안전하다는 해석결과를 알 수 있다. 따라서 70MPa의 수소연료 압력용기의 강도안전성을 충분히 확보하기 위해서는 미국의 DOT-CFFC 안전기준에 의거 평가하고 설계하는 것이 바람직하다.

• 한국표면공학회지
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• 제50권5호
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• pp.301-307
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• 2017

The purpose of this study is to investigate the electrical properties of thick-film resistor (TFR) prepared from $CaO-ZnO-B_2O_3-Al_2O_3-SiO_2$ (CZBAS) glass containing $RuO_2$ particles. $RuO_2$-glass composite powder was made by mixing and melting oxide powders of constituents. For comparison, $RuO_2$ powder was simply mixed with glass powder. $RuO_2$-40wt% glass composite and mixture were dispersed in an organic binder to obtain printable resistor paste and then thick-film was formed by screen printing, followed by sintering at the range between $750^{\circ}C$ and $900^{\circ}C$ for 10 min with a heating rate of $50^{\circ}C/min$ in an ambient atmosphere. $RuO_2$-glass composite sample showed much higher resistance compared to the simple mixed sample. This could be attributed to the difference in conducting mechanism. After sintering at $850^{\circ}C$, temperature coefficient of resistance of composite sample was lower than that of simple-mixed sample. TFR with dense and homogeneous microstructure could be obtained by using $RuO_2$-glass composite powder.

• 한국복합재료학회:학술대회논문집
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• 한국복합재료학회 2002년도 춘계학술발표대회 논문집
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• pp.73-76
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• 2002

This study developed SiC/Al composites for electronic packaging to which reinforcements were added with the volume fractions of 49%, 56% and 63% by the squeeze casting method. 0.8 wt.% of the inorganic binder as well as the $Al_2O_3$ fiber and SiC particles with the volume fraction of 1:10 were added to the SiC/Al composites For the produced SiC/Al composites, the CTEs (coefficients of thermal expansion) were measured from 30 to $300^{\circ}C$ and compared with the FEM numerical simulation to analyze the temperature dependent properties. The experiment showed the CTEs of SiC/Al composites that were intermediate values of those of Rule of Mixture and Turner's Model. The CTEs were close to Turner's Model in the room temperature and approached the Rule of Mixture as the temperature increases. These properties analyzed from the difference of the average stress acting between the matrix and the reinforcements proposed in this study