• Title/Summary/Keyword: butadiene rubber

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Surface Modification of Polymeric Material Using Atmospheric Plasma (대기압 플라즈마를 이용한 고분자 소재의 표면개질)

  • Sim, Dong-Hyun;Seul, Soo-Duk
    • Polymer(Korea)
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    • v.32 no.5
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    • pp.433-439
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    • 2008
  • An atmospheric plasma pre-treatment method was applied to polyurethane foam (density: 0.27) and rubber (butadiene rubber) to improve its contact angle and adhesion using atmospheric plate type reactor. In order to investigate the optimum reaction condition of plasma treatment, type of treatment gas (nitrogen, argon, oxygen, air), rate of gas flow ($30{\sim}100\;mL/min$), and treated time ($0{\sim}30\;s$) were examined in a plate plasma reactor. The result of the surface modification with respect to the treatment procedure was characterized by using SEM and ATR-FTIR. Due to a decrease of the contact angle of various materials, the greatest adhesion strength was achieved at optimum condition such as flow rate of 100 mL/min, reaction time of polyurethane foam 10 s and rubber 3 s for an atmosphere nitrogen gas. Consequently, the atmospheric plasma treatment reduced the wettability of the polyurethane foam and rubber also resulted in the improvement of the adhesion.

Mathematical Modeling and Analysis on the Behavior of VOC in an Indoor Environment (휘발성 유기화합물의 거동특성 예측을 위한 수학적 모델링 및 실내 환기특성 연구)

  • 이승철;최청렬;김창녕
    • Korean Journal of Air-Conditioning and Refrigeration Engineering
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    • v.13 no.7
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    • pp.627-636
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    • 2001
  • This paper presents a numerical analysis of the emission process of volatile organic compound(VOC) from building material and its diffusion in a room. A polypropylene styrene-butadiene rubber(SBR) floor plate is chosen as the emission source of VOC. This study investigates spatial concentration distributions and time history of room-averaged VOC concentration for both with and without flushing. The results of this study show that for calculation based on ten-days period the room averaged VOC concentrations with and without flushing are quite different. the results thus suggest the need of flushing for new buildings.

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Radiation Crosslinking and Shrinkable Properties of PVC (PVC의 방사선 가교와 열수축 특성)

  • Nho, Young Chang
    • Applied Chemistry for Engineering
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    • v.3 no.2
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    • pp.341-348
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    • 1992
  • PVC was compounded with various crosslinking agents, plasticizers and acrylonitrile butadiene rubber(NBR) to evaluate their effects on the radiation gel percent, elongation at break, heat distortion and heat shrinkage. Gel yield of PVC increased with increasing unsaturation levels per molecular weight of crosslinking agents while PVC containing NBR was more sensitive to crosslinking than PVC itself regardless of the types of crosslinking agents and plasticizers. It was found that gel percent was increased with increasing radiation dose, while heat distortion was decreased with increasing gel percent. Heat shrinkage was increased with decreasing stretching temperature and increasing annealing temperature.

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Prediction of Compressive Strength of Concretes Containing Silica Fume and Styrene-Butadiene Rubber (SBR) with a Mathematical Model

  • Shafieyzadeh, M.
    • International Journal of Concrete Structures and Materials
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    • v.7 no.4
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    • pp.295-301
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    • 2013
  • This paper deals with the interfacial effects of silica fume (SF) and styrene-butadiene rubber (SBR) on compressive strength of concrete. Analyzing the compressive strength results of 32 concrete mixes performed over two water-binder ratios (0.35, 0.45), four percentages replacement of SF (0, 5, 7.5, and 10 %) and four percentages of SBR (0, 5, 10, and 15 %) were investigated. The results of the experiments were showed that in 5 % of SBR, compressive strength rises slightly, but when the polymer/binder materials ratio increases, compressive strength of concrete decreases. A mathematical model based on Abrams' law has been proposed for evaluation strength of SF-SBR concretes. The proposed model provides the opportunity to predict the compressive strength based on time of curing in water (t), and water, SF and SBR to binder materials ratios that they are shown with (w/b), (s) and (p).This understanding model might serve as useful guides for commixture concrete admixtures containing of SF and SBR. The accuracy of the proposed model is investigated. Good agreements between them are observed.

Preparation and Characterization of Anionic Emulsified Asphalt with Enhanced Adhesion Properties

  • Lee, Eun-Kyoung
    • Elastomers and Composites
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    • v.50 no.4
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    • pp.304-313
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    • 2015
  • In this study, the anionic emulsified asphalt was prepared by dispersing asphalt particles evenly into water with combination of anionic and nonionic surfactants. Effects of NaOH and $CaCl_2$ on the phase stability of the emulsified asphalt were also investigated through zeta potential value and rheology behavior; the emulsified asphalt added with NaOH and $CaCl_2$ showed higher zeta potential value than that the asphalt with addition of only anionic and nonionic surfactants. In addition, with regard to shear thinning behaviors, it was found that pH of the emulsified anionic asphalt and $Ca^{2+}$, counter ion, affected the phase stability. SBR (styrene-butadiene-rubber) latex, EPD (water dispersed Epoxy), PU (polyurethane) and RI-10S, SBS (styrene-butadiene-styrene)-based property improvement additive, were used and studied to enhance the adhesion properties with the aggregates. RI-10S, however, was found to be only compatible with the anionic emulsified asphalt; the coating rate, adhesion and compression strength were increased with the RI-10S content.

Novel Smart Polymeric Composites for Thermistors and Electromagnetic Wave Shielding Effectiveness from TiC Loaded Styrene-Butadiene Rubber

  • Sung, Yong-Kiel;Farid EI-Tantawy
    • Macromolecular Research
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    • v.10 no.6
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    • pp.345-358
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    • 2002
  • The electrical conductivity during vulcanization process was measured as a function of time for the system of TiC loaded styrene-butadiene rubber (SBR) composites. The phenomenon of negative and positive temperature coefficients of conductivity and its conduction mechanism were also studied for the SBR polymeric composites. The current-voltage characteristics of the polymeric composites were non-linear in high voltage and showed a switching effect. The effects of temperature on the thermal conductivity and effective dielectric constant were measured. The measured parameters were found to be dependent on TiC concentration. The electromagnetic wave shielding (EMS) of the SBR-TiC polymeric composite was also examined. The SBR filled with TiC could be expected to be promising novel smart polymeric composites for self-electrical heating, temperature sensor, time delay switching, and electro-magnetic wave shielding effectiveness.

Process Development and Analysis of Diorefinery for the Coproduction of 1,3-Butadiene and Butene Oligomer (1,3-부타디엔과 부텐 올리고머 공동 생산을 위한 바이오 정유 공정의 설계 및 분석)

  • AHN, BYEONGCHAN;PARK, JIN-NAM;WON, WANGYUN
    • Journal of Hydrogen and New Energy
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    • v.32 no.6
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    • pp.618-635
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    • 2021
  • Environmental issues caused by our dependence on fossil fuels have caused our society to move toward new renewable sources of energy and chemicals. In this study, we develop an integrated process that co-produces butene oligomer (i.e., biofuels) and 1,3-butadiene (i.e., monomer for the production of synthetic rubber). To minimize utility consumption, we conduct heat integration. Then, we conduct a range of techno-economic analysis and life-cycle assessment to investigate economic and environmental feasibility of the proposed process.

SBR(Styrene Butadiene Rubber)

  • Baek, Bong-Gi
    • The tire
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    • s.16
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    • pp.21-27
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    • 1968
  • SBR의 가공기술은 이미 널리 보급되어 있으므로 본고에서는 미국에서의 SBR개발과정을 중점적으로 다루고 사용기술 및 용도에 대해서는 기본적인 요점만 해설키로 한다. SBR의 용도별 전문적인 가공기술은 후일 별도로 논술키로 한다.

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