• Title/Summary/Keyword: bubbling

검색결과 219건 처리시간 0.025초

무격막식 해수 전기분해 방식을 통한 배연 탈질에 관한 연구 (A Study on the NOx Reduction of Flue Gas Using Un-divided Electrolysis of Seawater)

  • 김태우;최수진;김종화;송주영
    • Korean Chemical Engineering Research
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    • 제50권5호
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    • pp.825-829
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    • 2012
  • 본 연구에서는 전기분해 처리된 해수의 유효염소농도와 온도에 의한 배가스 중 NO의 산화 특성을 실험적으로 살펴보았다. 실험은 무격막식 전해수가 채워진 버블링 반응기에 반응가스를 공급하여 NO 농도의 변화를 분석하였다. 폐순환 전기분해 시스템의 경우 정전류 조건에서 전해 시간이 길어질수록 전해수 내에 유효염소농도가 상승하였고, 전해수의 유효염소농도가 높을수록 NO가 $NO_2$로 산화되는 반응이 촉진됨을 확인하였다. 또한 동일한 유효염소농도를 가지는 전해수의 경우에도 온도가 높을수록 NO 산화율이 증가하였다.

Benchmark Dose Modeling of In Vitro Genotoxicity Data: a Reanalysis

  • Guo, Xiaoqing;Mei, Nan
    • Toxicological Research
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    • 제34권4호
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    • pp.303-310
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    • 2018
  • The methods of applied genetic toxicology are changing from qualitative hazard identification to quantitative risk assessment. Recently, quantitative analysis with point of departure (PoD) metrics and benchmark dose (BMD) modeling have been applied to in vitro genotoxicity data. Two software packages are commonly used for BMD analysis. In previous studies, we performed quantitative dose-response analysis by using the PROAST software to quantitatively evaluate the mutagenicity of four piperidine nitroxides with various substituent groups on the 4-position of the piperidine ring and six cigarette whole smoke solutions (WSSs) prepared by bubbling machine-generated whole smoke. In the present study, we reanalyzed the obtained genotoxicity data by using the EPA's BMD software (BMDS) to evaluate the inter-platform quantitative agreement of the estimates of genotoxic potency. We calculated the BMDs for 10%, 50%, and 100% (i.e., a two-fold increase), and 200% increases over the concurrent vehicle controls to achieve better discrimination of the dose-responses, along with their BMDLs (the lower 95% confidence interval of the BMD) and BMDUs (the upper 95% confidence interval of the BMD). The BMD values and rankings estimated in this study by using the EPA's BMDS were reasonably similar to those calculated in our previous studies by using PROAST. These results indicated that both software packages were suitable for dose-response analysis using the mouse lymphoma assay and that the BMD modeling results from these software packages produced comparable rank orders of the mutagenic potency.

배연가스의 $NO_x$제거용 코로나 방전장치에서 OH 발광 스펙트럼 측정 및 관련 반응 연구 (Study on the Measurement of Emission Spectrum and Reaction Mechanism of OH Radical in the Nitrogen Corona Discharge System for Removal of $NO_x$ in Flue Gas)

  • 박철웅;한재원;신동남
    • 한국연소학회지
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    • 제4권1호
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    • pp.27-38
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    • 1999
  • We constructed a wire-cylinder type pulsed corona discharge system for $NO_x$ removal, which was operated in room temperature. A emission spectrometer was built with a boxcar averager and monochrometer equipped with photo-multiplier tube detector. The sensitivity of the emission spectrometer was greatly improved by synchronizing the emission spectrometer with pulsed corona discharge system using a triggered spark-gap switch. $N_2$ spectrum($c^3{\Pi}_u{\rightarrow}X^1{\Sigma}_g{^+}$) was measured in the range of 300 - 450 nm and oxidizing OH radical emission($A^2{\Sigma}^+{\rightarrow}X^2{\Pi}$) was measured in case $N_2$ was supplied with water bubbling. As wet gas composition of inlet $N_2$ supplied in the discharge system increased, the intensity of OH emission was increased and saturated at wet gas composition 50%. We also investigated additive effect of $C_2H_4,\;H_2O,\;H_2O_2$ on the intensity of OR emission and $NO/NO_2/NO_x$ reduction and analysed the related reaction mechanism in corona discharge process. $H_2O_2$ additive increased the intensity of OH emission and $NO/NO_x$ reduction.

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중방식 도료의 내식성에 미치는 첨가제의 영향 (The Effect of Additive to Corrosion Resistance of Heavy Anti-Corrosive Paint)

  • 문경만;조황래;이명훈;김현명;이인원;전호환
    • 한국해양공학회지
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    • 제21권3호
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    • pp.65-70
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    • 2007
  • There are many kinds of protection methods for marine structures, with varyingeconomical and environmental advantages. The coating protection method is being widely used in both continental and marine structures. In this study, by adding some additives, such as Zn powder(Zn), carbon black(CB) to epoxy anti-corrosive paint, the effect on the corrosion resistance was investigated throughan electrochemical method. The additive of Zn(20)+CB(10) showed the lowest passivity current density. Polarization resistance in both cyclic voltammogram and impedance measurement of an additive of Zn(20)+CB(10) was also the largest value, compared to other additives. Furthermore, rusting and bubbling was not observed on the surface of the test specimen with the additive of Zn(20)+CB(10), compared to other specimens. It is suggested that the corrosion resistance of the anti-corrosive paint can be improved by using some additives.

방사선 조사시의 수도종자의 수분함량과 산소와의 관계 (Post-Irradiation Oxygen Effect of Rice Seeds in Varying Seed Water Content)

  • 이영일;최광태
    • 한국작물학회지
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    • 제20권
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    • pp.69-73
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    • 1975
  • 방사선후처리로서 산소가 수분함량이 다른 수도종자에 미치는 영향을 조사코저 수분함량 5.6∼14.7%까지의 종자에 3∼25kR의 방사선량을 조사한 후 산소 및 질소로 bubbling한 상태에서 hydration처리하였다. 효과가 현저하여 5.6∼12.9%까지는 산소처리에 의한 묘장 및 생존율의 감소가 나타났지만 13.9%부터 그 이상에서는 차이가 없었다. 엽록소돌연변이율 및 불임율은 6.5%의 저수분에서 13.0%의 고수분함량에 이르기까지 공히 산소처리에 의한 영향이 있었고 특히 저수분함량일수록 또는 방사선량이 높을수록 그차이는 현저하였다.

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액상으로 분사되는 기체의 불안정성 해석 (Instability analysis of gas injection into liquid)

  • 김형준;권세진
    • 한국추진공학회:학술대회논문집
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    • 한국추진공학회 2006년도 제26회 춘계학술대회논문집
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    • pp.57-60
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    • 2006
  • 액상의 환경으로 고속의 기체가 분사될 때 기체-액체 표면에서 일어나는 불안정성에 대해 점성전위 유동의 이론을 이용하여 분석하였다. 기체의 속도가 낮을 경우 액상으로 기포로 형성되지만 속도가 증가하면서 기체는 제트의 형태로 변하게 되는데, 천음속 구간에서 제트로 변하게 되는 것으로 알려져 있다. 본 연구에서는 주로 액체 제트를 해석하는데 사용된 점성전위유동이론을 기체 제트의 불안정성 해석에 응용하였다. 천음속 구간에서 기체 제트의 성장률이 변하는 것을 확인하였다. 초음속 구간으로 가면서 성장률이 감소하는 것을 확인하였다. 그리고 이를 레이놀즈수와 같은 무차원수에 대해 기체 제트의 성장률의 변화에 대해 알아보았다.

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Digestion of settleable solids from recirculating fish tank as nutrients source for the microalga Scenedesmus sp. cultivation

  • Rotthong, Maneechotiros;Chiemchaisri, Wilai;Tapaneeyaworawong, Paveena;Powtongsook, Sorawit
    • Environmental Engineering Research
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    • 제20권4호
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    • pp.377-382
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    • 2015
  • The high concentration of nitrogen and phosphorus in wastewater incorporated with the ability to use carbon dioxide as the carbon source make the microalgae become more attractive in wastewater treatment process. This study evaluates the optimal conditions for the digestion of settelable solids from the recirculating aquaculture system to produce the biomass of the green microalga Scenedesmus sp. After solids separation, aerobic digestion of settleable solids under disperse condition produced nitrate as the final product of consequently ammonification and nitrification processes. With the optimal digestion procedure, nitrate concentration during aerobic digestion in 2000 mL vessel increased from $9.63{\pm}0.65mg\;N/L$ to $58.66{\pm}0.06mg\;N/L$ in 10 days. Thereafter, cultivation of Scenedesmus sp. was performed in 1000 mL Duran bottle with air bubbling. The highest Scenedesmus sp. specific growth rate of $0.321{\pm}0.01/d$ was obtained in treatment using liquid fraction after aerobic digestion as the whole culture medium for Scenedesmus sp. cultivation. With this study, digestion of $8,800{\pm}128.12mg\;dry\;weight/L$ of settleable solids from fish pond finally produced $1,235{\pm}21mg\;dry\;weight/L$ of Scenedesmus sp. biomass.

Al계 편정합금의 중력 편석에 관한 연구 (I);Pb, Bi 입자의 분산에 미치는 용탕처리의 영향 (A Study on the Gravity Segregation in Monotectic Al Alloys.(I);The Effect of Melting Treatment on the Distribution of Pb, Bi Particles.)

  • 황호을;이재하;정성인;최정철;윤의박
    • 한국주조공학회지
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    • 제10권4호
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    • pp.316-323
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    • 1990
  • To improve free-cutting property, fine Pb, Bi particles is necessary to be distributed evenly in Al-Cu alloy. The control of added element size and distribution are very difficult because of the insolubility and gravity segregation of Pb, Bi in the matrix. Therefore, in this study, mechanical stirring of the melt, inert gasbubbling, the addition of degasser are used for the fine distribution of Pb, Bi particles. The best distribution are obtained by stirring with 500 rpm for 10min., Ar gas bubbling with 600cc/min for 5min. and degassing with 0.8wt% degasser. As increasing cooling rate, fine grain size and finely dispersed particles were observed. The optimum pouring temperature was $650^{\circ}C$.

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$\gamma$-선의 조사를 이용한 하수처리장 방류수 처리에 관한 연구 (A Study on the Treatment of Secondary Effluent by ${\gamma}-ray$ Irradiation)

  • 이면주;정영도;박순달
    • 환경위생공학
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    • 제13권2호
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    • pp.106-114
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    • 1998
  • This study was carried out for the purpose of industrial reuse of effluent released from activated sludge unit by $\gamma $-ray irradiation technique. The dissolved organic carbon in the effluent of an activated sludge unit is mostly refractory or inert material which are difficult to be degraded by micro organism. The effluent generated from activated sludge unit was irradiated with Co$^{60}$ $\gamma $-ray under condition of air bubbling. The effects of irradiation on the pH, COD, TOC, color, molecular weight distribution were investigated by membrane filtration and u.v.-spectrum analysis. With increasing dose, the TOC was decreased smoothly. The COD was increased at lower dose, while the COD was decreased at higher dose. The TOC and COD, however, were decreased smoothly when TiO$_{2}$ was added to the solution. It was thought that the differential decreasing trend of COD and TOC in according to the absence or presence of TiO$_{2}$ was due to the molecular weight distribution shifted from group of higher molecular weight to group of lower one which are more easy to be decomposed. The removal efficiency of color was 71.5% and it was increased to 85.7% when TiO$_{2}$ was added to the solution. The $\gamma $-ray irradiation was effective on the production of chlorine.

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정수 및 폐수처리에서 오존 미세기포와 초미세기포 기술의 적용 : 리뷰 (Applications of Ozone Micro- and Nanobubble Technologies in Water and Wastewater Treatment: Review)

  • 테킬 안디넷;김일호;이재엽
    • 상하수도학회지
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    • 제31권6호
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    • pp.481-490
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    • 2017
  • Water and wastewater treatment has always been a challenging task due to the continuous increase in amount and the change in characteristics of the poorly biodegradable and highly colored organic matters, as well as harmful micro-organisms. Advanced techniques are therefore required to successfully remove these pollutants from water before reuse or discharge to receiving water bodies. Application of ozone, which is a powerful oxidant and disinfectant, alone or as part of advanced oxidation process depends on the complex kinetic reactions and the mass transfer of ozone involved. Micro- and nano bubbling considerably improves gas dissolution compared to conventional bubbles and hence mass transfer. It can also intensify generation of hydroxyl radical due to collapse of the bubbles, which in turn facilitates oxidation reaction under both alkaline as well as acidic conditions. This review gives the overview of application of micro- and nano bubble ozonation for purification of water and wastewater. The drawbacks of previously considered techniques and the application of the hydrodynamic ozonation to synthetic aqueous solutions and various industrial wastewaters are systematically reviewed.