• Korean Chemical Engineering Research
• /
• v.57 no.2
• /
• pp.210-218
• /
• 2019

Batch experiment studies were carried out on the adsorption of the major tar compound, 2-picoline, derived from the plant cell cultures of Taxus chinensis, using Sylopute while varying parameters such as initial 2-picoline concentration, contact time and adsorption temperature. The experimental data were fitted to the Langmuir, Freundlich, Temkin and Dubinin-Radushkevich isotherm models. Comparison of results revealed that the Langmuir isotherm model could account for the adsorption isotherm data with the highest accuracy among the four isotherm models considered. From the analysis of adsorption isotherms, it was found that adsorption capacity decreased with increasing temperature and the adsorption of 2-picoline onto Sylopute was favorable. The kinetic data were well described by the pseudo-second-order kinetic model, while intraparticle diffusion and boundary layer diffusion did not play a dominated role in 2-picoline adsorption according to the intraparticle diffusion model. Thermodynamic parameters revealed the exothermic, irreversible and non-spontaneous nature of adsorption. The isosteric heat of adsorption decreased as surface loading ($q_e$) increased, indicating a heterogeneous surface.

• Tribology and Lubricants
• /
• v.35 no.1
• /
• pp.30-36
• /
• 2019

The tribological properties of paper-based friction materials are crucial to the performance of a wet clutch system. In this work, the friction and wear characteristics of a paper-based friction material in boundary lubrication state was experimentally investigated using a pin-on-reciprocating tribotester under various normal forces and temperatures. It was found that the wear rate of the friction material increased from $5.8{\times}10^{-6}mm^3/N/cycle$ to $5.5{\times}10^{-5}mm^3/N/cycle$ after 1,700 cycles of testing at $80^{\circ}C$ as normal force increased from 2 N to 7 N. The friction coefficient was also found to increase from 0.135 to 0.155 with increasing normal force from 2 N to 7 N. The increase in contact pressure with increasing normal force may be responsible for these results. In addition, as temperature increased from $20^{\circ}C$ to $80^{\circ}C$, the wear rate of the friction materials increased from $2.0{\times}10^{-5}mm^3/N/cycle$ to $3.6{\times}10^{-5}mm^3/N/cycle$ while the friction coefficient decreased from 0.163 to 0.146. This result may be associated with the decrease in the hardness of friction materials with increasing temperature. Furthermore, plastic deformation on the friction materials was mainly observed after the test. The outcome of this work may be useful to gain a better understanding of the tribological properties of friction materials, and therefore can contribute to the development of friction materials with enhanced performance for wet clutch systems.

• Journal of Electrochemical Science and Technology
• /
• v.10 no.3
• /
• pp.335-343
• /
• 2019

In this study, $Sr_2Ni_{1.8}Mo_{0.2}O_{6-{\delta}}$ (SNM) with a double perovskite structure was investigated as an alternative anode for use in the $CH_4$ fuel in solid oxide fuel cells. SNM demonstrates a double perovskite phase over $600^{\circ}C$ and marginal crystallization at higher temperatures. The Ni nanoparticles were exsolved from the SNM anode during the fabrication process. As the SNM anode demonstrates poor electrochemical and electro-catalytic properties in the $H_2$ and $CH_4$ fuels, it was modified by applying a samarium-doped ceria (SDC) coating on its surface to improve the cell performance. As a result of this SDC modification, the cell performance improved from $39.4mW/cm^2$ to $117.7mW/cm^2$ in $H_2$ and from $15.9mW/cm^2$ to $66.6mW/cm^2$ in $CH_4$ at $850^{\circ}C$. The mixed ionic and electronic conductive property of the SDC provided electrochemical oxidation sites that are beyond the triple boundary phase sites in the SNM anode. In addition, the carbon deposition on the SDC thin layer was minimized due to the SDC's excellent oxygen ion conductivity.

• The Sea:JOURNAL OF THE KOREAN SOCIETY OF OCEANOGRAPHY
• /
• v.24 no.2
• /
• pp.249-265
• /
• 2019

A passive sampler is one of the promising methods to easily and more accurately predict the free dissolved and bioavailable concentration ($C_{free}$) in seawater or pore water in sediments. In Europe and the United States, the use of passive samplers has been highly encouraged for more accurate marine environmental risk assessment. However, long deployment time in the field causes problems such as biofouling of the samplers, so there are few studies using passive samplers in Korea. Therefore, we review the principle and basic characteristics of the passive sampler for persistent organic pollutants, and introduce various improvement cases for the field applications of the passive sampler.

• Tribology and Lubricants
• /
• v.35 no.2
• /
• pp.123-131
• /
• 2019

This study characterizes the coastdown performances of two small electric motors supported on high-speed ball bearings (BBs) and gas foil bearings (GFBs), and it predicts their acceleration performances. The two motors have identical permanent magnetic rotors and mating stators. However, the shaft of the GFBs has a larger mass and polar/transverse moments of inertia than that of the BBs. Motor coastdown tests demonstrate that the rotor speed decreases linearly with the BBs and nonlinearly with the GFBs. A simple model for the BBs predicts a constant drag torque and linear decay of speed with time. The test data validate the model predictions. For the GFBs, the hydrodynamic lubrication model predictions reveal that the drag torque increases linearly with speed, and the speed decreases exponentially with time. The predictions agree very well with the test data in the speed range of 100-30 krpm. The boundary lubrication model predicts a constant drag torque and linear decay of speed with time. The predictions agree well with the test data below 15 krpm. Mixed lubrication occurs in the speed range of 30-15 krpm. Rotor acceleration performances are predicted based on the characteristics of deceleration performances. The GFBs require more time to reach 100,000 krpm than the BBs because of their larger shaft polar moment of inertia. However, predictions for the assumed identical polar moment of inertia reveal that the GFBs have a nearly identical acceleration performance to that of the BBs with a motor torque greater than $0.03N{\cdot}m$.

• Journal of the Korea Institute of Information and Communication Engineering
• /
• v.23 no.3
• /
• pp.267-275
• /
• 2019

Currently, due to the widespread use of a smartphone, QR codes allow users to access a variety of added services. However, the QR codes posted on curved surfaces tend to be non-uniformly illuminated and bring about the decline of recognition rate. So, in this paper, the block-adaptive binarization policy is adopted to find an optimal threshold appropriate for bimodal image like QR codes. For a large block, its histogram distribution is found to get an initial threshold and then the block is partitioned to reflect the local characteristics of small blocks. Also, morphological operation is applied to their neighboring boundary at the discontinuous at the QR code junction. This paper proposes an authentication method based on the color code, uniquely painted within QR code. Through a variety of practical experiments, it is shown that the proposed algorithm outperforms the conventional method in detecting QR code and also maintains good recognition rate up to 40 degrees on curved surfaces.

• Wind and Structures
• /
• v.28 no.1
• /
• pp.31-47
• /
• 2019

The accurate prediction of snow distributions under the wind action on roofs plays an important role in designing structures in civil engineering in regions with heavy snowfall. Affected by some factors such as building shapes, sizes and layouts, the snow drifting on roofs shows more three-dimensional characteristics. Thus, the research on three-dimensional snow distribution is needed. Firstly, four groups of stepped flat roofs are designed, of which the width-height ratio is 3, 4, 5 and 6. Silica sand with average radius of 0.1 mm is used to model the snow particles and then the wind tunnel test of snow drifting on stepped flat roofs is carried out. 3D scanning is used to obtain the snow distribution after the test is finished and the mean mass transport rate is calculated. Next, the wind velocity and duration is determined for numerical simulations based on similarity criteria. The adaptive-mesh method based on radial basis function (RBF) interpolation is used to simulate the dynamic change of snow phase boundary on lower roofs and then a time-marching analysis of steady snow drifting is conducted. The overall trend of numerical results are generally consistent with the wind tunnel tests and field measurements, which validate the accuracy of the numerical simulation. The combination between the wind tunnel test and CFD simulation for three-dimensional typical roofs can provide certain reference to the prediction of the distribution of snow loads on typical roofs.

• Korean Journal of Environmental Agriculture
• /
• v.39 no.4
• /
• pp.289-296
• /
• 2020

BACKGROUND: There is a need for a revolutionary method to overcome the problem of biochar, which has relatively low adsorption capacity for existing anion pollutants, along with collectively recycling fallen leaves, a kind of forest by-product. Therefore, the objective of this study was to prepare iron-decorated biochar derived from fallen leaves (Fe-FLB), and to evaluate their adsorption properties to Congo red (CR) as anionic dye. METHODS AND RESULTS: The adsorption properties of CR by fallen leaves biochar (FLB) and Fe-FLB were performed under various conditions such as initial CR concentration, reaction time, pH and dosage with isotherm and kinetic models. In this study, Fe-FLB prepared through iron impregnation and pyrolysis of fallen leaves contained 56.9% carbon and 6.3% iron. Congo red adsorption by FLB and Fe-FLB was well described by Langmuir model and pseudo second order model and the maximum adsorption capacities of FLB and Fe-FLB were 1.1 mg/g and 25.6 mg/g, respectively. In particular, it was found that the adsorption of CR was occurred by chemical adsorption process by the outer boundary layer of Fe-FLB. CONCLUSION: Overall, the production of Fe-FLB using fallen leaves and using it as an anion adsorbent is considered to be a way to overcome the problem of biochar with relatively low anion adsorption in addition to the reduction effect of waste.

• Journal of the Korean Society of Environmental Restoration Technology
• /
• v.24 no.3
• /
• pp.1-18
• /
• 2021

England's green belt policy as it delivered its framework to designating the development restriction zones(DRZ) in Korea is the key to address issues which try to change green belt boundary or/and housing development. Therefore it should necessarily be reviewed on the understanding of how England has been formulating a national policy to deal with the issues focusing on opportunities for housing development and recreation. This study explored the discourse and framework of England's green belt policy as well as driver changes of housing development and recreation. Results show several characteristics of England's green belt policy which are civil society consensus on conservation and management, limited small-scale housing development through management of release rates, a systematic procedure for application and approval, open-recreation space expansion and utilisation under the premise of conservation of natural green areas, and management structure by the involvement of NGO organisations. Therefore, five suggestions can be delivered to developing Korea's DRZ frameworks: first, preceding social consensus on the preservation value of development-restricted zones, second, addressing housing shortages in different alternatives e.g.) environmental-friendly small-scale housing, third, institutionalising the total proportion of release, fourth, establishing an open-recreation space, fifth, introducing expanded public-private partnerships. Ultimately securing the legitimacy of the nation's development-restricted zone system can contribute positively to the environment preservation and human health by promoting public leisure activities in terms of the recent increase in external activities caused by the Covid-19 crisis. Concluding remarks are here that the understanding of England's green belt policy can be delivered to and help formulate domestic policy addressing current issues.

• Journal of the Korean Society of Marine Environment & Safety
• /
• v.26 no.7
• /
• pp.881-891
• /
• 2020

In recent years, large-scale development of coastal areas has caused the loss of many lives and extensive property damage in coastal areas, due to wave overtopping caused by high-wave invasion and strong typhoons. However, coastal inundation studies considering the characteristics of domestic coastal areas are insufficient. This study is a methodology study that aimed to reproduce inundation of surge and wave complex elements by applying the ADCSWAN (ADCIRC+SWAN) and FLOW-3D models. In this study, the boundary data (sea level, wave) of the FLOW-3D model was extracted using the ADCSWAN (ADCIRC+SWAN) model and applied as the input value of the FLOW-3D model and a reproduction was created of the Flooding due to surge and overtopping in Busan Marine City when the typhoon Chaba passed. In addition, the existing overtopping empirical equation and the overtopping calculated by the FLOW-3D model were compared, and for coastal inundation, a qualitative verification was performed using the Inundation Trace Map of Land and Geospatial Informatrix Corporation, and the effectiveness of this study was reviewed.