• Elastomers and Composites
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• v.59 no.1
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• pp.1-7
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• 2024

Nanorod graphitic carbon nitride (g-C₃N₄) was synthesized by reacting melamine (C₃H₆N₆) with trithiocyanuric acid (C₃H₃N₃S₃) in distilled water for 10 h at room temperature. The resulting mixture was calcined at 550℃ for 2 h in an electric furnace under an air atmosphere. Nanorod g-C₃N₄/Ag₃PO₄ composites were prepared by adding nanorod graphitic carbon nitride (g-C₃N₄) powder, silver nitrate (AgNO₃), ammonia (NH₃·H₂O, 25.0-30.0%), and sodium hydrogen phosphate (Na₃HPO₄) to distilled water. The samples were characterized via X-ray diffraction, scanning electron microscopy, and Fourier-transform infrared spectroscopy. The photocatalytic activities of the nanorod g-C₃N₄/Ag₃PO₄ composites were demonstrated via the degradation of organic dyes, such as methylene blue and methyl orange, under blue light-emitting diode irradiation and evaluated using UV-vis spectrophotometry.

• Journal of Korean Society of Water and Wastewater
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• v.38 no.2
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• pp.95-107
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• 2024

This study proposes the use of a cobalt-based Prussian blue analogue (Co-PBA; potassium cobalt hexacyanoferrate), as an adsorbent for the cost-effective recovery of aqueous ammonium ions. The characterization of Co-PBA involved various techniques, including Fourier-transform infrared spectroscopy, X-ray diffraction, scanning electron microscopy, nitrogen adsorption-desorption analysis, and zeta potential. The prepared Co-PBA reached an adsorption equilibrium for ammonium ions within approximately 480 min, which involved both surface adsorption and subsequent diffusion into the interior. The isotherm experiment revealed a maximum adsorption capacity of 37.29 mg/g, with the Langmuir model indicating a predominance of chemical monolayer adsorption. Furthermore, the material consistently demonstrated adsorption efficiency across a range of pH conditions. Notably, adsorption was observed even when competing cations were present. Co-PBA emerges as a readily synthesized adsorbent, underscoring its efficacy in ammonium removal and selectivity toward ammonium.

• Journal of Plant Biology
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• v.15 no.1
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• pp.13-22
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• 1972

In the present paper, seven marine algae collected from the coasts of Korea are described. The two blue-green algae, Coccochloris stagnina Sprengel and Entophysalis conferta (Kuetz.) Drouet and Daily, one brown alga, Ralfsia verrucosa(Aresch.) J. Ag., and the two red algae, Enelittosiphonia hakodatensis (Yendo) Segi and Symphyocladia pennata Okamura, are recorded newly in our country. The other two blue-green algae, Anacystis dimidiata (Kuetz.) Drouet and Daily and Phormidium tenue (Meneghini) Gomont, are recorded for the first time marine water in our country.

• Korean Journal of Ecology and Environment
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• v.42 no.3
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• pp.404-406
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• 2009

This study note wished to introduce special-purpose ship for algae removal that is developed by core technology of our country. The ship is consisted of main frame and adjuvant that can attach and detach as cross (+) shape of a character. The characteristics of ship are super light weight and low draft. That is consisted of four devices as suction, collection, filtration and recovering units. Among these, filtration used screen filter (mesh size 30 ${\mu}m$). Also, can separate and remove water and algae by compression air participle notion. Percentage of moisture content of concentrated algal particle was 85%. Water parted with algae finally is exhausted to water area. Removal efficiency that compare by chlorophyll-$\alpha$ concentration was about 57% (inflow: 83.2 ${\mu}g\;L^{-1}$, outflow: 35.8 $[\mu}g\;L^{-1}$) without physical and chemical pretreatment. Forward, need to achieve effect test in various conditions (algal biomass, flow etc.) for efficiency and technological elevation of exclusion device. We wished to contribute in presuppression system construction of massive algal development that manage blue-green algae occurrence area effectively, and prevents spread as lower part of reservoir.

• Applied Chemistry for Engineering
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• v.16 no.3
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• pp.366-371
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• 2005

In this study treatment efficiencies of methylene blue were evaluated in term of BOD, COD, TOC, absorbance and initial decolorization rates. Ozonation of the dye in distilled water was performed in a laboratory scale cylindrical batch reactor. The decolorization process of methylene blue was carried out by bubbling ozone at the bottom of a bubble column reactor containing the dye solution. Decolorization, determined by measuring the light absorbance at the maximum wavelength in the (${\lambda}_{max}$, 660 nm), was almost complete after 40 min with an ozone concentration of $50{\pm}10mg/L$. The $TOC/TOC_0$ ratio after ozonation was about 83.8%, the COD was diminished to 44.0% of the initial value. The $BOD_5/COD$ ratio was increased from 64.2% to about 90.8%, indicating an enhancement of biodegradable compounds in the ozonated solutions. The pseudo first-order rate constants of the ozonation was $3.30{\times}10^{-2}min^{-1}$ and the activation energy was $3.01kcal{\cdot}mol^{-1}$ at $30^{\circ}C$.

• Proceedings of the KSRS Conference
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• v.1
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• pp.495-498
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• 2006

Optical profile and spectral absorption of suspended solids in waters of Sanya bay was measured on August 8-14, 2003. Optical profile was taken by using MicroPro optical profile. Apparent optical indexes, vertical diffuse attenuation coefficient ($K_d$) and water leaving radiance (Lw), were calculated. $K_d$ at the blue end of the spectrum was greater than that at the red end of the spectrum in waters near Sanya River mouth, however, in waters near open sea, $K_d$ at the blue end of the spectrum was smaller than that at the red end of the spectrum. Distribution of water leaving radiance was relatively higher in waters near Sanya River mouth, but relatively weaker in near open sea water. Spectral absorption of suspended particulates was also measured. Results showed that the spectral absorption of chlorophyll a was greater in waters near Sanya river mouth, but relatively weaker in waters near open sea, which indicated higher concentration of phytoplankton in waters near Sanya river mouth. Except for water at the 5th sampling station, the ratio of spectral absorption of chlorophyll a to total suspended particulates in surface waters was greater than that in bottom waters at all stations.

• Bulletin of the Korean Chemical Society
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• v.33 no.11
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• pp.3593-3596
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• 2012

The water-soluble conjugated polymer with fluorescence quenching as a result of electrostatic interaction and aggregation was synthesized through Suzuki polymerization. The absorption and emission of anionic polymer (a-PFP) is blue shifted as compared with cationic polymer (c-PFP) although getting same backbone, and the absolute PL quantum efficiency of a-PFP in water is over 90% due to good solubility in aqueous solution. We anticipate that the fluorescence quenching of anionic and cationic polymers, with same conjugated backbone, could be shown in aqueous solution.

• Proceedings of the Korea Water Resources Association Conference
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• 2009.05a
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• pp.1744-1747
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• 2009

하천의 상류부터 하류까지 통합적이고 유기적인 수질관리를 통해 모든 생명에 젖줄이 될 수 있는 하천환경을 조성하는 방안을 모색하고 가용 수자원의 효율적 활용을 통해 건천화된 영산강의 유량을 풍부하게 하는 한편, 이상강우에 대비한 고품격 하천설계로 재해로부터 안전한 하천으로 역할을 수행할 수 있는 방안을 강구할 필요가 있다. 더욱 생물의 서식지를 복원하고 단절된 하천을 연계하여 BLUE-GREEN 네트워크를 형성하고 하천의 생물다양성을 증진하여 많은 동 식물들이 활동하고 서식하는 생태적으로 건전한 하천으로 조성하는 방안과 마한 및 백제문화의 산물인 영산강 유역의 역사유적과 황금박쥐 서식처 등과 같은 환경자원을 발굴 연계하여 미래지향적인 지역문화를 재창조하는 방안을 모색할 필요가 있다. 따라서 본 연구에서는 미래지향적 인 지역문화를 창조하고 하천의 생물다양성을 증진하기 위해 가장 우선시 되어야 할 수질개선을 위해 영산강 유역에서 가장 시급한 문제점을 발굴하고 맑고 문제점 해결을 위한 대안을 설정하여 수질모델을 이용하여 대안에 따른 수질모델을 이용하여 수질개선 효과를 분석하였다.

• Journal of Ecology and Environment
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• v.36 no.4
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• pp.293-302
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• 2013

The present study summarizes the occurrence, distribution and autecology of 12 taxa of the class Cyanophyceae collected from several swamps, reservoir and highland wetlands in South Korea from 2009 to 2012. A new species, Anabaena koreana sp. nov. and 11 taxa of blue-green algae newly recorded are described and illustrated. Anabaena koreana is similar to A. oumiana, A. spiroides and A. crassa in that the trichomes form regular coils. However, A. koreana is distinguished from these three species by the morphological characteristics of the vegetative cell, heterocyst, and akinet shape and size. This study considers 12 blue-green algal species, including a new species, Anabaena koreana sp. nov. and 11 species that are recorded for the first time in the Korean freshwater algal flora. Among them, the genus Nostochopsis Wood ex Bornet et Flahault 1886 had not previously been recorded in Korea.

• YAKHAK HOEJI
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• v.9 no.1_2
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• pp.14-17
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• 1965

It has been known that the organic base complexes formed with the anionic acid base indicators are highly soluble in non-polar solvents but relatively insoluble in water. In the work reported here the formation of the complex between chloropromazine and bromothymol blue was studied and applied it to the determination of the base. The values to determine the binding ratio of the base with the indicator at pH 3.5 obtained from the application of Job's method of continuous variation and mol ratio method were both 1:1. From the application of this reaction to the determination of the base with carbon tetrachloride as the solvent for the extraction, fairy good results have been obtained.