• Title/Summary/Keyword: blending rate

Search Result 172, Processing Time 0.027 seconds

Control of Enzymatic Degradability of Biodegradable Polylactide by Blending with Non-degradable Polymers (비 분해성고분자와 블렌드를 이용한 생분해성 폴리유산의 효소분해속도 조절)

  • Jang, Seong-Ho;Park, Sang-Bo;Lee, Won-Ki
    • Journal of Environmental Science International
    • /
    • v.19 no.9
    • /
    • pp.1161-1167
    • /
    • 2010
  • The effects of addition of non degradable polymers, polystyrene (PS) and poly(methyl methacrylate) (PMMA) on the rate of enzymatic degradation of biodegradable poly(l-lactide) (PLLA) have been studied in term of surface structure. Since a component in multicomponent polymeric system has shown surface enrichment, PS and PMMA which have lower surface energy than PLLA were selected as a minor blend component (5 wt%). Enzymatic degradation was carried out at $37^{\circ}C$ and pH 8.5 in the aqueous solution of Proteinase K. Two blend systems, partially miscible (PS/PLLA) and immiscible (PMMA/PLLA), showed the surface enrichment of 4 and 2 times of PS and PMMA, respectively. From the weight loss profile data, the slow degradation rate of both blend films was observed. This indicates that PS or PMMA domains which exist at surface act as a retardant of enzymatic attack.

Cure Reactions of Epoxy/Anhydride/(Polyamide Copolymer) Blends

  • Youngson Choe;Kim, Wonho
    • Macromolecular Research
    • /
    • v.10 no.5
    • /
    • pp.259-265
    • /
    • 2002
  • The cure kinetics of blends of epoxy (DGEBA, diglycidyl ether of bisphenol A)/anhydride resin with polyamide copolymer, poly(dimmer acid-co-alkyl polyamine), were studied using differential scanning calorimetry (DSC) under isothermal condition. On increasing the amount of polyamide copolymer in the blends, the reaction rate was increased and the final cure conversion was decreased. Lower values of final cure conversions in the epoxy/(polyamide copolymer) blends indicate that polyamide hinders the cure reaction between the epoxy and the curing agent. The value of the reaction order, m, for the initial autocatalytic reaction was not affected by blending polyamide copolymer with epoxy resin, and the value was approximately 1.3, whereas the reaction order, n, for the general n-th order of reaction was increased by increasing the amount of polyamide copolymer in the blends, and the value increased from 1.6 to 4.0. A diffusion-controlled reaction was observed as the cure conversion increased and the rate equation was successfully analyzed by incorporating the diffusion control term for the epoxy/anhydride/(polyamide copolymer) blends. Complete miscibility was observed in the uncured blends of epoxy/(polyamide copolymer) up to 120 $^{\circ}C$, but phase separations occurred in the early stages of the curing process at higher temperatures than 120 "C. During the curing process, the cure reaction involving the functional group in polyamide copolymer was detected on a DSC thermogram.gram.

Study on Effect of Aromatherapy on Physiological and Psychological Aspect of Patients with Pain (향기요법이 통증환자의 생리적 및 심리적 측면에 미치는 효과)

  • Song, Min-Sun;Suh, Young-Sook;Choi, Chan-Hun
    • Journal of Physiology & Pathology in Korean Medicine
    • /
    • v.25 no.4
    • /
    • pp.748-754
    • /
    • 2011
  • The purpose of this study was to investigate the effect of aromatherapy on pain level, blood pressure, pulse rate, sleep, anxiety and depression of patients with pain. This study used a non equivalent quasi-experimental design. Aromatherapy was the inhalation of blending oils with lavender, eucalyptus, peppermint for 3 weeks. As the estimation for the physiological aspect, the visual analogy scale (VAS) for the pain level, blood pressure and pulse rate were measured. Also, as the estimation for the psychological aspect, Sleep of Snyder-Halpern & Verra, anxiety of Spielbeger and depression of Beck were used. The data were analyzed by SAS program using $x^2$ test, Fisher's exact test, Cronbach ${\alpha}$ and t-test. The results of this study were as follows. Pain level(p=0.001), state anxiety(p=0.018), trait anxiety(p=0.002), and depression(p<0.001) improved significantly in the experimental group. Also, there was significant difference between the experimental group and the control group on the depression(p=0.012). Aromatherapy was effective in physiological and psychological therapy. Also it can be applied in combination with existing Oriental medical therapy.

A study on the heat dissipation characteristic of thermal interface materials with Graphene, Cu and Ag nano powders (Graphene, Cu와 Ag 나노 파우더를 이용한 열전도재의 방열 특성에 관한 연구)

  • Park, Sang-Hyeok;Im, Sung-Hoon;Kim, Hyun-Ji;Noh, Jung-Pil;Huh, Sun-Chul
    • Journal of the Korean Society of Industry Convergence
    • /
    • v.22 no.6
    • /
    • pp.767-773
    • /
    • 2019
  • The thermal diffusion performance of the electronic device is a factor for evaluating the stability of the electronic device. Therefore, many of research have been conducted to improve the thermal characteristics of thermal interface materials, which are materials for thermal diffusion of electronic products. In this study, nano thermal grease was prepared by blending graphene, silver and copper nano powders into a thermal grease, a type of thermal interface materials, and the heat transfer rate was measured and compared for the purpose of investigating the improved thermal properties. As a result, the thermal properties were good in the order of graphene, silver and copper, which is thought to be due to the different thermal properties of the nano powder itself.

Preparative Isolation of Ginseng Saponin from Panax ginseng Root Using High-speed Countercurrent Chromatography (High-speed countercurrent chromatography를 이용한 인삼 saponin의 대량 분리 농축)

  • Lee, Chang-Ho;Lee, Boo-Yong
    • Korean Journal of Food Science and Technology
    • /
    • v.36 no.3
    • /
    • pp.518-521
    • /
    • 2004
  • Ginseng saponin was isolated from panax ginseng root using high-speed countercurrent chromatography (HSCCC). Preliminary studies were performed to optimize physical properties of two-phase solvent system and operating parameters including rotation speed of column, elution mode of mobile phase, and flow rate. Two-phase solvent system for isolation of ginseng saponins was composed of chloroform, water, and methanol as blending solvent. Chloroform-aqueous methanol (4:6) systems with various concentration of methanol in water were evaluated for retention of stationary phase in column. Retention of stationary phase decreased with increasing flow rate in tail-to-head elution mode using upper phase as mobile phase and head-to-tail elution mode using lower phase as mobile phase. Latter mode produced high retention at flow rate of 5 mL/min. Optimum conditions for isolation of saponin were chloroform/methanol/water (40/39/21) solvent system; mobile phase, of lower organic layer, flow rate, of 5 mL/min, head to tail elution mode, rotation speed, of 800 rpm, and sample injection, of $200{\mu}L$, Recovery yield of ginseng saponin from panax ginseng root extract by HSCCC was 63.6%, and the purity of HSCCC fractions was verified by TLC.

Proper Mixing Ratio for Securing Quality of Free-form Panel (비정형 패널의 형상 품질확보를 위한 적정 배합비 도출)

  • Kim, Min-Sik;Park, Chae-Wool;Kim, Ki-Hyuk;Do, Sung-Lok;Lee, Dong-Hoon
    • Journal of the Korea Institute of Building Construction
    • /
    • v.19 no.5
    • /
    • pp.449-456
    • /
    • 2019
  • Recent developments in architectural technologies and programs have enabled architects to think creatively and design free-form architecture. however, there are many problems in the production technology of FCP(Free-Form Concrete Panel). In particular, reduced accuracy due to lack of free-form panel production technology can lead to redesign of buildings as a result, problems such as an increase in construction cost and period. Therefore, this experiment aimed to compensate the decrease of the accuracy according to the displacement difference and to derive the proper mixing ratio for maintaining the shape during the free-form panel curing. In this study, molds were made using paraffin that is a recyclable phase change material. Concrete Panel is usually produced from Portland cement, dead burn magnesia, phosphate, borax and fine aggregate. In this study, four mixing ratios of FCP were selected after each material was blended to determine the proper blending ratio of the fluidity phase, the water absorption rate and the water content of the test piece. FCP was fabricated on the basis of the selected four compounding ratios and thickness and error rate were measured. Based on the error rate of the measured FCP, the quality standard was satisfied among the four compounding ratios.

The Influence of Feed Energy Density and a Formulated Additive on Rumen and Rectal Temperature in Hanwoo Steers

  • Cho, Sangbuem;Mbiriri, David Tinotenda;Shim, Kwanseob;Lee, A-Leum;Oh, Seong-Jin;Yang, Jinho;Ryu, Chaehwa;Kim, Young-Hoon;Seo, Kang-Seok;Chae, Jung-Il;Oh, Young Kyoon;Choi, Nag-Jin
    • Asian-Australasian Journal of Animal Sciences
    • /
    • v.27 no.11
    • /
    • pp.1652-1662
    • /
    • 2014
  • The present study investigated the optimum blending condition of protected fat, choline and yeast culture for lowering of rumen temperature. The Box Benken experimental design, a fractional factorial arrangement, and response surface methodology were employed. The optimum blending condition was determined using the rumen simulated in vitro fermentation. An additive formulated on the optimum condition contained 50% of protected fat, 25% of yeast culture, 5% of choline, 7% of organic zinc, 6.5% of cinnamon, and 6.5% of stevioside. The feed additive was supplemented at a rate of 0.1% of diet (orchard grass:concentrate, 3:7) and compared with a control which had no additive. The treatment resulted in lower volatile fatty acid (VFA) concentration and biogas than the control. To investigate the effect of the optimized additive and feed energy levels on rumen and rectal temperatures, four rumen cannulated Hanwoo (Korean native beef breed) steers were in a $4{\times}4$ Latin square design. Energy levels were varied to low and high by altering the ratio of forage to concentrate in diet: low energy (6:4) and high energy (4:6). The additive was added at a rate of 0.1% of the diet. The following parameters were measured; feed intake, rumen and rectal temperatures, ruminal pH and VFA concentration. This study was conducted in an environmentally controlled house with temperature set at $30^{\circ}C$ and relative humidity levels of 70%. Steers were housed individually in raised crates to facilitate collection of urine and feces. The adaptation period was for 14 days, 2 days for sampling and 7 days for resting the animals. The additive significantly reduced both rumen (p<0.01) and rectal temperatures (p<0.001) without depressed feed intake. There were interactions (p<0.01) between energy level and additive on ruminal temperature. Neither additive nor energy level had an effect on total VFA concentration. The additive however, significantly increased (p<0.01) propionate and subsequently had lower acetate:propionate (A/P) ratios than non-additive supplementation. High concentrate diets had significantly lower pH. Interactions between energy and additive were observed (p<0.01) in ammonia nitrogen production. Supplementation of diets with the additive resulted in lower rumen and rectal temperatures, hence the additive showed promise in alleviating undesirable effects of heat stress in cattle.

An experimental study on the injection and spray characteristics of butanol (부탄올의 분사 및 분무특성에 관한 실험적 연구)

  • JEONG, Tak-Su;WANG, Woo-Gyeong;KIM, Sang-Am
    • Journal of the Korean Society of Fisheries and Ocean Technology
    • /
    • v.53 no.1
    • /
    • pp.89-97
    • /
    • 2017
  • Butanol has an ability to improve the ignition quality due to its lower latent heat of vaporization; it has an advantage to reduce a volume of a fuel tank because its energy density is higher than that of ethanol. Also, butanol-diesel oil blending quality is good because butanol has an effect to prevent the phase-separation between two fuels. Even if the blended oil contains water, it can reduce the corrosion of the fuel line. Thus, it is possible to use butanol-diesel oil blended fuel in diesel engine without modification, and it may reduce the environment pollution due to NOx and particulate and the consumption of diesel oil. Therefore, some studies are being advanced whether butanol is adequate as an alternative fuel for diesel engines, and the results of the combustion and exhaust gas emission characteristics are being presented. Though the injection and spray characteristics of butanol are more important in diesel combustion, the has not yet dealt with the matter. In this study, the influence in which differences of physical properties between butanol and diesel oil may affect the injection and spray characteristics such as injection rate, penetration, spray cone angle, spray velocity and process of spray development were examined by using CRDI system, injection rate measuring device and spray visualization system. The results exhibited that the injection and macroscopic spray characteristics of two fuels were nearly the same.

An Analysis of Luminance Histogram and Correlation of Motion Vector for Unsuitable Frames for Frame Rate Up Conversion (프레임율 상향 변환에 부적합한 프레임들에 대한 밝기값 히스토그램과 모션 벡터 상관성 분석)

  • Kim, Sangchul;Nang, Jongho
    • KIISE Transactions on Computing Practices
    • /
    • v.22 no.10
    • /
    • pp.532-536
    • /
    • 2016
  • Frame Rate Up Conversion (FRUC) generate interpolated frames between existing frames using motion estimation and motion compensation interpolation considering temporal redundancy. Falsely-estimated FRUC, however, can generate poor quality frames because FRUC typically uses blending-based interpolation method. As skipping an interpolating process between frames generate mis-estimated motion vectors, could improve Quality of Services of FRUC. In this Paper we analyze luminance histogram and motion vector consistency in frames generating poor quality interpolated frames. We conclude these features could help to be a clue in classifying the frames, which often result in the poor quality of FRUC results through the analysis and experiment.

Kinetics of Thermal Degradation of Polypropylene/Nanoclay/Wood Flour Nanocomposites

  • Mohan, D. Jagan;Lee, Sun-Young;Kang, In-Aeh;Doh, Geum-Hyun;Park, Byung-Dae;Wu, Qinglin
    • Journal of the Korean Applied Science and Technology
    • /
    • v.24 no.3
    • /
    • pp.278-286
    • /
    • 2007
  • As a part of enhancing the performance of wood-plastic composites (WPC), polypropylene (PP)/ nanoclay (NC)/ wood flour (WF) nanocomposites were prepared using melt blending and injection molding process to evaluate their thermal stability. Thermogravimetric analysis (TGA) was employed to investigate thermal degradation kinetics of the nanocomposites both dynamic and isothermal conditions. Dynamic scans of the TGA showed an increased thermal stability of the nanocomposites at moderate wood flour concentrations (up to 20 phr, percentage based on hundred percent resin) while it decreased with the addition of 30 phr wood flour. The activation energy $(E_a)$ of thermal degradation of nanocomposites increased when nanoclay was added and the concentration of wood flour increased. Different equations were used to evaluate isothermal degradation kinetics using the rate of thermal degradation of the composites, expressed as weight loss (%) from their isothermal TGA curves. Degradation occurred at faster rate in the initial stages of about 60 min., and then proceeded in a gradual manner. However, nanocomposites with wood flour of 30 phr heated at $300^{\circ}C$ showed a drastic difference in their degradation behavior, and reached almost a complete decomposition after 40 min. of the isothermal heating. The degree of decomposition was greater at higher temperatures, and the residual weight of isothermal degradation of nanocomposites greatly varied from about 10 to 90%, depending on isothermal temperatures. The isothermal degradation of nanocomposites also increased their thermal stability with the addition of 1 phr nanoclay and of wood flour up to 20 phr. But, the degradation of PP100/NC1/MAPP3/WF30 nanocomposites with 30 phr wood flour occurs at a faster rate compared to those of the others, indicating a decrease in their thermal stability.