• Title/Summary/Keyword: binder paste

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Printing Properties of Ag Paste with the Variation of Binder on the SiNx Coated Si Wafer (SiNx 층이 코팅된 Si Wafer에 바인더 종류에 따른 Ag 페이스트의 인쇄 특성)

  • Kang, Jea Won;Shin, Hyo Soon;Yeo, Dong Hun;Jeong, Dae Yong
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.27 no.2
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    • pp.85-90
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    • 2014
  • Ag paste has been used in the front electrode of the Si-solar cell. It is composed by Ag powder, glass frit, binder, solvent and dispersant. The role of the binder and the solvent is to make a flow and a printing property. However, it was not enough to report the printing properties with the variation of binder in the controled viscosity. In this study, we selected 3 kinds of typical binder which were used as binder for the paste in the industry, such as Ethyl cellulose, Hydroxypropyl cellulose and Acrylic. Ag pastes using these were prepared, controled viscosity and printed on the SiNx coated Si wafer. In the 'A paste' used Acrylic binder, printed hight was highest and 'H paste' used Hydroxypropyl cellulose binder was lowest. Because 'H paste' was high viscosity due to the molecular weight, the solvent was added in the paste to control the viscosity. Therefore, the content of solid was lower in 'H paste'. The relative pattern width which is related to the spreading of paste was the best in the case of 'H paste' and 'EH paste' at $30^{\circ}C$. It is thought that the optimization of the relative pattern width is possible for a paste by the controling shear thinning phenomenon. In the case of 'A paste', though printing hight was best, the pattern width was dependant on the temperature.

Analysis of Rheological Properties of Cement Paste with Binder Type and Composition Ratio (결합재 타입 및 구성비 변화에 따른 시멘트 페이스트의 레올로지 특성 분석)

  • Jeon, Sung IL;Nam, Jeong Hee;Lee, Moon Sup;Nho, Jae Myun
    • International Journal of Highway Engineering
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    • v.19 no.5
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    • pp.77-88
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    • 2017
  • PURPOSES : It is necessary to clarify the rheological properties of cement paste as a basic research in the development of mechanistic concrete mix design. The rheological properties of cement paste with different binder types, mix propositions, and with/without high range water reducers have been analyzed. METHODS : In this study, ordinary Portland cement, fly-ash, blast furnace slag, silica fume, and limestone powder were used as binders. The range of water-binder ratio was 0.3-0.5, and a total of 30 different mixes have been tested. The slump flow test, V-funnel test, and Dynamic Shear Rheometer (DSR) test were performed to analyze the rheological properties of cement paste. RESULTS : As a result of the slump flow test, it was found that the composition ratio of the binder contents greatly affected the paste flow when the high range water reducers were added. The results of V-funnel test showed that when the water-binder ratio was decreased without high range water reducers, the binder composition ratio had a large effect on the passing time of the V-funnel tester, but with high range water reducers the impact of the binder composition ratio was decreased. The slump flow and V-funnel have a certain relationship with the rheological factors (yield stress and plastic viscosity), but the correlation was not significant. Finally, we proposed the M-value considering the density and specific surface area of the binder. The correlation between rheological factors and M-value were better demonstrated than experimental values, but there is still a limit to predict the rheological factor in general mix design. CONCLUSIONS :In this study, the rheological properties of cement paste were analyzed. The binder type, composition ratio of binder, and with/without high range water reducers have combined to provide the complex effects on the rheological properties of cement paste. The correlation between the proposed M-value and rheological factor was found to be better than experimental results, but needs to be improved in the future.

Photovoltaic Characteristics of $TiO_2$ Paste for Dye-Sensitized Solar Cell with Binder, Binder-Free and Mixed Binder (염료감응 태양전지용 $TiO_2$ 페이스트의 바인더 유무와 혼합에 따른 광전변환 특성)

  • Baek, Hyoung-Youl;Li, Hu;Park, Kyung-Hee;Gu, Hal-Bon
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2007.06a
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    • pp.336-337
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    • 2007
  • The energy conversion characteristics of $TiO_2$ paste of dye-sensitized solar cell (DSSC) was investigated. In the case of DSSC without a binder, the current density increased due to the development of porosity. As for DSSC with a binder, the fill factor increased due to the development of network among the particles. The energy conversion efficiency of 7.2% was obtained due to the porosity and the network as for DSSC with the mixed binder (Vol. 50:50).

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The Influence of the Type of Silica Fume on the Property of Cement Binder for Ultra High Strength (초고강도용 시멘트 결합재의 물성에 미치는 실리카퓸 종류의 영향)

  • Kim, Ki-Hoon;Hwang, Yin-Seong;Kim, Sung-Su;Choi, Sung-Yong;Han, Min-Cheol;Han, Cheon-Goo
    • Proceedings of the Korean Institute of Building Construction Conference
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    • 2007.04a
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    • pp.51-54
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    • 2007
  • This study investigates the properties of paste and mortar from different types and forms of silica fume on cement binder for ultra high strength. Although most Silica Fumes distributed in the market fulfill the KS quality standard, each type showed different levels of loss of ignition. When evaluating cement binder for ultra high strength in a form of paste. Flow, viscosity and moving freely time show great difference depending on the Silica Fume's form and type of primary particle's dispersibility. The evaluation of Silica Fume's dispersibility can be possible with the paste test since there is a high correlation of flow quality between paste and mortar. The compressive strength when using Silica Fume was correlated to the SiO2 content. Synthetically, selecting Silica Fume with the most the ideal primary particle is the key to optimizing the formation for cement binder for ultra high strength.

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Effect of PET Film Treatment on Adhesive Properties Between PET Film and Conductive Paste (PET 필름과 전도성 페이스트의 접착성에 미치는 PET 필름 처리 영향)

  • Yeong Seo Hong;Youn Cheol Kim
    • Applied Chemistry for Engineering
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    • v.35 no.3
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    • pp.209-213
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    • 2024
  • To improve the adhesion properties between the conductive paste and PET film, the PET film was chemically treated using acids and bases and physically treated through corona discharge. A paste using ethylcellulose, which is used in actual industrial manufacturing and silane-treated CNF, as a binder was manufactured and coated on PET film to compare the adhesive properties. The specimen coated with a paste containing silane-treated CNF as a binder on a corona discharge-treated PET film showed the highest level of adhesion, 5B. On the other hand, it was confirmed that when PET film was chemically treated with acid/base, there was no improvement in adhesive properties.

The Preparation of Phosphor Screen for Video Phone Tube by Screen Printing Method (Screen Printing법에 의한 Video Phone Tube용 형광막 제조)

  • Lee Mi-Young;Lee Jong-Wook;Kim Young-Bae;Nam Su-Yong;Lee Sang-Nam;Moon Myung-Jun
    • Journal of Environmental Science International
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    • v.14 no.8
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    • pp.801-810
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    • 2005
  • The phosphor and ITO(Indium Tin Oxide) films for video phone tube (VPT) were simply prepared by the screen printing and thermal transfer methods. The increasing order of thermal firing of acrylic binder for phosphor and ITO was M6003 < M6664 < A/A 1919 < M500l < M670 1 and all mass of binders were perfectly decomposed at lower temperature than $400^{\circ}C.$ After thermal firing of phosphor paste, the residual of binder on the surface of phosphor could not be found by SEM. Aerosil as thickner provides the thixotropy property for phosphor paste but decrease the brightness of phosphor screen as residual after thermal firing. Since the thixotropy of M5001 binder without aerosil was shown and the storage modulus of phosphor paste by increasing the angular frequency was not nearly changed and the decrease of the storage modulus of phosphor paste by increasing the strain was remarkably shown. It was possible to prepare the phosphor paste which was predominant in the plate separation and the reproduction of pattern after the screen printing. Since the addition of dispersing agent to improve the printing process decreases the electrical conductivity and light transmission of ITa film, it could be found to be necessary the development of binder for phosphor paste that decreases the amount of dispersing agent possibly and does not use the aerosil as additive.

Novel Conductive Paste based on Cellulose Acetate Butyrate (셀룰로오스를 이용한 전도성 체이스트의 개발)

  • Kim, Tae-Hyun
    • Journal of the Korean Chemical Society
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    • v.51 no.2
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    • pp.171-177
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    • 2007
  • Polymer-based electrically conductive pastes have been used to make the conductive paths between voltage sources and devices. The pastes used for these applications consist of two main components: a polymer binder and a conductive filler. Having both low viscosity and good metal-encapsulating properties, cellulose acetate butyrate (CAB) was regarded to be a good candidate as a binder for the conductive paste. We have prepared a formulation for a novel conductive paste based on CAB. Preliminary studies showed that this conductive paste revealed stable conductivity, together with uniform coating and flexibility.

Effect of Carbon Filler and Ester Type Binder on the Reactivity and Adhesive Properties with PET Film of Conductive Paste (탄소필러와 에스테르계 바인더가 전도성 페이스트의 반응성 및 PET 필름과의 접착특성에 미치는 영향)

  • Shim, Chang Up;Ku, Hyo Sun;Kim, Youn Cheol
    • Applied Chemistry for Engineering
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    • v.33 no.4
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    • pp.381-385
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    • 2022
  • It is very important to secure the adhesion durability between the base film and the conductive paste for the development of a sensor for detecting hazardous chemicals. In this study, an ester binder was used to improve the adhesive properties which can be a problem when applying the sensor to the cross cut 0B or 1B grade. This problem was found while evaluating the adhesive properties by coating the polyaniline/graphene nano plate (GNP) paste on the polyethylene terephthalate (PET) film. When 10 wt% or more of the ester-based binder was added, the cross cut grade to which the sensor can be applied was 3B or higher. It was confirmed that the excessive addition of the binder may affect the electrical properties of the conductive paste and actually decrease the reactivity to sulfuric acid. To improve the electrical property, a carbon black (CB) content was varied resulting in the optimum electrical property observed at 2 wt% of CB.

Microstructure of Non-Sintered Inorganic Binder using Phosphogypsum and Waste Lime as Activator

  • Kim, Ji-Hoon;An, Yang-Jin;Mun, Kyung-Ju;Hyung, Won-Gil
    • Journal of the Korea Institute of Building Construction
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    • v.18 no.3
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    • pp.305-312
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    • 2018
  • This study is about the development of a non-sintered binder (NSB) which does not require a sintering process by using the industrial by-products Phosphogypsum (PG), Waste Lime (WL) and Granulated Blast Furnace Slag (GBFS). In this report, through SEM analysis of the NSB paste hardening body, micropore analysis of paste using the mercury press-in method and microstructure observation were executed to consider the influence of the formation of the pore structure and the distribution of pore volume on strength, and the following conclusions were reached. 1) Pore structure of NSB paste of early age is influenced by hydrate generation amount by GBFS and activator. 2) Through observing the internal microstructure of NSB binder paste, it was found that the strength expression at early age due to hydration reaction was achieved with a large amount of ettringite serving as the frame with C-S-H gel generated at the same time. It was confirmed that C-S-H gel wrapped around ettringite, and as time passed, the amount generated continually increased, and C-S-H gel tightly filled the pores of hardened paste, forming a dense network-type web structure. 3) For NSB-type cement, the degree of formation of gel pores below $10{\mu}m$ had a greater influence on strength improvement than simple pore reduction by charging capillary pores, and the pore size that had the greatest effect on strength was micropores with diameter below $10{\mu}m$.

Flexible Dye-sensitized Solar Cell Using Titanium Gel at Low Temperature (저온 티타늄 겔을 이용한 플렉시블 염료감응형 태양전지)

  • Ji, Seung Hwan;Park, Hyunsu;Kim, Doyeon;Han, Do Hyung;Yun, Hye Won;Kim, Woo-Byoung
    • Korean Journal of Materials Research
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    • v.29 no.3
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    • pp.183-188
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    • 2019
  • Flexible dye-sensitized solar cells using binder free $TiO_2$ paste for low temperature sintering are developed. In this paste a small amount of titanium gel is added to a paste of $TiO_2$ nanoparticle. Analysis of titanium gel paste prepared at $150^{\circ}C$ shows that it has a pure anatase phase in XRD and mesoporous structure in SEM. The formation of the titanium gel 1-2 nm coated layer is confirmed by comparing the TEM image analysis of the titanium gel paste and the pristine paste. This coating layer improves the excited electron transfer and electrical contact between particles. The J-V curves of the organic binder DSSCs fabricated at $150^{\circ}C$ shows a current density of $0.12mA/cm^2$ and an open-circuit voltage of 0.47 V, while the titanium gel DSSCs improves electrical characteristics to $5.04mA/cm^2$ and 0.74 V. As a result, the photoelectric conversion efficiency of the organic binder DSSC prepared at low temperature is as low as 0.02 %, but the titanium gel paste DSSCs has a measured effciency of 2.76 %.