• Title/Summary/Keyword: binary system

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Excess Volumes of Aqueous Solutions of Nonionic Amphiphile 2-(2-Hexyloxyethoxy)ethanol (비이온 양친매성 분자 2-(2-Hexyloxyethoxy)ethanol 수용액의 과잉 부피)

  • Lee, Jungno;Hwang, Yoonmi;Kang, Minhee;Lim, Kyung-Hee
    • Journal of the Korean Applied Science and Technology
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    • v.37 no.3
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    • pp.516-525
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    • 2020
  • The densities of aqueous solutions of the amphiphile 2-(2-hexyloxyethoxy)ethanol (C6E2) were measured at 279.15 K and 282.15 K by vibrating-tube densitometry. Then using the density data of the binary C6E2 (1)/water(2) system, the excess volumes and partial molar volumes were determined at various compositions. Excess volume VE exhibits negative deviation for the whole region of composition, which implies relatively stronger attraction between molecules. At the C6E2 mole fraction of around 0.45, VE was at its minimum. Partial molar volume ${\bar{V}}_1$ increases monotonously with the mole fraction x1(=x) and ${\bar{V}}_2$ decreases with x. Any particular point in ${\bar{V}}_1$ and ${\bar{V}}_2$, which may point to molecular association, was unobserved.

Effect of Green Microstructure on Sintered Microstructure and Mechanical Properties of Reaction-Bonded Silicon Carbide (성형미세구조가 반응소결 탄화규소체의 소결미세구조 및 기계적 특성에 미치는 영향)

  • 박현철;김재원;백운규;최성철
    • Journal of the Korean Ceramic Society
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    • v.36 no.1
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    • pp.97-105
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    • 1999
  • In the binary system of SiC and carbon, porosity and pore size distribution of green body was controlled by varying pH, by the addition of polyelectrolyte dispersants, and by using different particle size of starting powders. The preforms having different green microstructure were fabricated by slip casting from suspensions having different dispersion condition. The reaction bonding process was carried out for these preforms. The condition of reaction bonding was 1600$^{\circ}C$ and 20 min. under vacuum atmosphere. The analyses of optical and SEM were studied to investigate the effect of green microstructure on that of reaction bonded silicon carbide and subsequently the mechanical properties of sintered body was investigated. Different green microstructures were obtained from suspensions having different dispersion condition. It was found that the pore size could be remarkably reduced for a fine SiC(0.5$\mu\textrm{m}$). The bimodal microstructure was not found in the present study, which is frequently observed in the typical reaction bonded silicon carbide. It is considered that the ratio between SiC and C was responsible for the formation of bimodal microstructure. For the preform fabricated from the well dispersed suspension, the 3-point bending strength of reaction-bonded silicon carbide was 310${\pm}$40 MPa compared to the specimen fabricated from relatively agglomerated particles having lower value 260${\pm}$MPa.

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Scalable RSA public-key cryptography processor based on CIOS Montgomery modular multiplication Algorithm (CIOS 몽고메리 모듈러 곱셈 알고리즘 기반 Scalable RSA 공개키 암호 프로세서)

  • Cho, Wook-Lae;Shin, Kyung-Wook
    • Journal of the Korea Institute of Information and Communication Engineering
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    • v.22 no.1
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    • pp.100-108
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    • 2018
  • This paper describes a design of scalable RSA public-key cryptography processor supporting four key lengths of 512/1,024/2,048/3,072 bits. The modular multiplier that is a core arithmetic block for RSA crypto-system was designed with 32-bit datapath, which is based on the CIOS (Coarsely Integrated Operand Scanning) Montgomery modular multiplication algorithm. The modular exponentiation was implemented by using L-R binary exponentiation algorithm. The scalable RSA crypto-processor was verified by FPGA implementation using Virtex-5 device, and it takes 456,051/3,496347/26,011,947/88,112,770 clock cycles for RSA computation for the key lengths of 512/1,024/2,048/3,072 bits. The RSA crypto-processor synthesized with a $0.18{\mu}m$ CMOS cell library occupies 10,672 gate equivalent (GE) and a memory bank of $6{\times}3,072$ bits. The estimated maximum clock frequency is 147 MHz, and the RSA decryption takes 3.1/23.8/177/599.4 msec for key lengths of 512/1,024/2,048/3,072 bits.

Experiment and Simulation of 2-bed PSA for Hydrogen Separation from H2/CH4 Gas Mixture (수소/메탄 혼합 기체로부터 수소 분리를 위한 두 탑 PSA 실험과 전산 모사)

  • Nam, Gi-Moon;Jeong, Byung-Man;Kang, Seok-Hyun;Lee, Chang-Ha;Lee, Byung-Kwon;Choi, Dae-Ki
    • Korean Chemical Engineering Research
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    • v.43 no.2
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    • pp.249-258
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    • 2005
  • A two-column six-step pressure swing adsorption(PSA) process was to study separation of hydrogen from hydrogen and methane($60_{vol}%/40_{vol}%$) binary system onto activated carbon adsorbent. The effects of the feed gas pressure, the feed flowrate and the P/F(purge to feed) ratio on the process performance were evaluated. The cyclic steady-states of PSA process were reached to after 15 cycles. $H_2$ purity increases according as the P/F ratio and pressure increase and the feed flow rate decreases; however, $H_2$ recovery shows an opposite phenomena to the purity. PSA process simulation studied to find optimum operation condition. In the results, 22 LPM feed flowrate, 11 atm adsorption pressure and 0.10 P/F ratio might be optimal values to obtain more than 75% recovery and 99% purity hydrogen. In this study was non-isothermal and non-adiabatic model considering linear driving force(LDF) model and Langmuir-Freundlich adsorption isotherm considered to compare between prediction and experimental data.

Thermal Shock Resistance According to the Manufacturing Process of Lanthanum Gadolinium Zirconate Ceramic Igot for Thermal Barrier Coating by Electron Beam in the La2O3-Gd2O3-ZrO2 System (전자빔 증착 열차폐 코팅용 란타늄-가돌리늄 지르코네이트(La2O3-Gd2O3-ZrO2계) 세라믹 잉곳의 제조공정에 따른 열충격 저항성)

  • Choi, Seona;Chae, Jungmin;Kim, Seongwon;Lee, Sungmin;Han, Yoonsoo;Kim, Hyungtae;Jang, Byungkoog;Oh, Yoonsuk
    • Journal of the Korean institute of surface engineering
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    • v.50 no.6
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    • pp.465-472
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    • 2017
  • The ingot fabrication conditions related with the thermal shock bearing phase and microstructure have investigated for the rare earth zirconate ceramic material, lanthanum gadolinium zirconate, as a thermal barrier coating using electron beam evaporation method. The thermal shock resistance of the prepared ingot was evaluated by high energy electron beam irradiation. The rare earth zirconate ceramic powder was prepared by controlling the raw material powder composition of $La_2O_3$, $Gd_2O_3$ and $ZrO_2$ so as to have a composition of $(La_{0.3}Gd_{0.7})_2Zr_2O_7$ which was selected from the former study. Ingot samples were prepared under two conditions. The first condition is prepared by sintering the prepared powder mixture to form an ingot. The second condition is prepared by calcining the prepared powder mixture to form a composite phase and then sintering to form an ingot. X-ray diffraction(XRD) and Scanning Electron Microscope(SEM) were used to analyze phase forming behavior and microstructure of ingot samples. Nanoindentation method used to obtain elastic modulus and hardness of each ingot specimen. Also the stress distribution of ingot was simulated by using FEM method assuming the ingot surface was exposed to electron beam. As a results, in the case of an ingot having a network-shaped microstructure in which relatively coarse pores are included, it seems that the thermal shock resistance was higher than in the case of an ingot having a microstructure composed of relatively fine grains only or particles with the similar level size when the high energy electron beam irradiation.

Electrical Properties of Al3+ and Y3+ Co-doped SnO2 Transparent Conducting Films (Al3+와 Y3+ 동시치환 SnO2 투명전극 박막의 전기적 특성)

  • Kim, Geun-Woo;Seo, Yong-Jun;Sung, Chang-Hoon;Park, Keun-Young;Cho, Ho-Je;Heo, Si-Nae;Koo, Bon-Heun
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.25 no.10
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    • pp.805-810
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    • 2012
  • Transparent conducting oxides (TCOs) have wide range of application areas in transparent electrode for display devices, Transparent coating for solar energy heat mirrors, and electromagnetic wave shield. $SnO_2$ is intrinsically an n-type semiconductor due to oxygen deficiencies and has a high energy-band gap more than 3.5 eV. It is known as a transparent conducting oxide because of its low resistivity of $10^{-3}{\Omega}{\cdot}cm$ and high transmittance over 90% in visible region. In this study, co-doping effects of Al and Y on the properties of $SnO_2$ were investigated. The addition of Y in $SnO_2$ was tried to create oxygen vacancies that increase the diffusivity of oxygen ions for the densification of $SnO_2$. The addition of Al was expected to increase the electron concentration. Once, we observed solubility limit of $SnO_2$ single-doped with Al and Y. $\{(x/2)Al_2O_3+(x/2)Y_2O_3\}-SnO_2$ was used for the source of Al and Y to prevent the evaporation of $Al_2O_3$ and for the charge compensation. And we observed the valence changes of aluminium oxide because generally reported of valence changes of aluminium oxide in Tin - Aluminium binary system. The electrical properties, solubility limit, densification and microstructure of $SnO_2$ co-doped with Al and Y will be discussed.

Separation Properties of Sm/Nd with Karr Column (Karr column을 이용한 Sm/Nd 분리특성)

  • Eom Hyoung-Choon;Lee Jin-Young;Kim Sung-Don;Park Kye-Sung;Kim Jun-Soo
    • Resources Recycling
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    • v.14 no.6 s.68
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    • pp.10-15
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    • 2005
  • In this study, the separation of samarium to neodymium with Karr column was investigated. Separation properties of Sm/Nd binary system was estimated with experimental parameters such as flow rate, initial pH of aqueous phase, saponification of PC88A in organic phase and agitation speed. The extraction rate and distribution coefficient increased with increasing initial pH of aqueous phase at 16.5 ml/min(retention time 10 minute) of flow rate of organic and aqueous phase, and equilibrium pH of aqueous phase after extraction was maintained at 1.5 by saponified PC88A. Also, the extraction rate and distribution coefficient were drastically increased with increasing saponification degree of PC88A and agitation speed, and optimal saponification degree was $40\%$. Extraction rate of Nd and Sm was $19.6\%$ and $72.5\%$ respectively at retention time 10 minute, initial pH 1, saponification degree $40\%$ and agitation speed 120 rpm.

A Study on the Decoding of Hamming Codes using Soft Values on the Molecular Communication Channel (분자통신 채널에서 소프트 값을 이용한 해밍부호의 복호에 대한 연구)

  • Cheong, Ho-Young
    • The Journal of Korea Institute of Information, Electronics, and Communication Technology
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    • v.13 no.5
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    • pp.338-343
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    • 2020
  • In this paper, it was shown that the decoding method of Hamming codes using soft values can be applied to molecular communication channels. A soft value criterion that can be used for decoding of Hamming codes for a molecular communication channel was proposed, and it has been shown through simulation that the decoding method using these values can improve reliability even in the molecular communication channel. A diffusion-based molecular communication channel was assumed, and information symbols were transmitted using BCSK modulation. After demodulating the number of molecules absorbed by the receiver at each symbol interval with an appropriate threshold, the number of molecules is no longer used. In this paper, the BER performance of the decoder was improved by utilizing information on the number of molecules that are no longer used as soft values in the decoding process. Simulation was performed to confirm the improvement in BER performance. When the number of molecules per bit is 600, the error rate of the Hamming code (15,11) was improved about 5.0×10-3 to the error rate of the BCSK system without the Hamming code. It can be seen that the error rate of (15,11) Hamming code with the soft values was improved to the same extent. In the case of (7,4) Hamming code, the result is similar to that of (15,11) Hamming code. Therefore, it can be seen that the BER performance of the Hamming code can be greatly improved even in the molecular communication channel by using the difference between the number of molecules absorbed by the receiver and the threshold value as a soft value.

Edge-Enhanced Error Diffusion Halftoning using Local mean and Spatial Activity (국부 평균과 공간 활성도를 이용한 에지 강조 오차확산법)

  • Kwak Nae-Joung;Kwon Dong-Jin;Kim Young-Gil;Ahn Jae-Hyeong
    • The KIPS Transactions:PartB
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    • v.13B no.2 s.105
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    • pp.77-82
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    • 2006
  • Digital halftoning is the technique to obtain a bilevel-toned image from continuous-toned image. Among halftoning methods, the error diffusion method gives better subjective quality than other halftoning ones. But it also makes edges of objects blurred. To overcome the defect, we proposes the modified error diffusion to enhance the edges using the property that human vision perceives the local average luminance and doesn't perceive a little variation of the spatial variation. The proposed method computes a spatialactivity, which is the difference between a pixel luminance and the average of its $3{\times}3$ neighborhood pixels' Iuminance weighted according to the spatial positioning. The system also usesof edge enhancement (IEE), which is computed from the normalized spatial activitymultiplied by the average luminance. The IEE is added to the quantizer's input pixel and feeds into the halftoning quantizer. The quantizer produces the halftone image having the enhanced edge. The computer experimental results show that the proposed method produces clearer bilevel-toned images than conventional methodsand the edge of objects is preserved well. Also the performance of the preposed method is improved, compared with that of the conventional method by measuring the edge correlation and the local average accordance at some ranges of viewing distance.

Design of Naphtha Cracker Gas Splitter Process in Petlyuk Column (납사열분해 가스분리공정에서의 Petlyuk Column 설계)

  • Lee, Ju Yeong
    • Journal of the Korean Institute of Gas
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    • v.24 no.1
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    • pp.17-22
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    • 2020
  • Light Naphtha is distillated from crude oil unit and separated into the methane, ethylene and propylene by boiling point difference in sequence. This separation is conducted using a series of binary-like columns. This separation method is known that the energy consumed in the reboiler is used to separate the heaviest components and most of this energy is discarded as vapor condensation in the overhead cooler. In this study, the first two columns of the separation process are replaced with the Petlyuk column. A structural design was exercised by the stage computation with ideal tray efficiency in equilibrium condition. Compared with the performance of a conventional system of 3-column model, The design outcome shows that the procedure is simple and efficient because the composition of the liquid component in the column tray was designed to be similar to the equilibrium distillation curve. The performance of the new process indicates that an energy saving of 12.1% is obtained and the cost savings of 44 million won per day based on gross domestic product is reduced under same total number of trays and the initial investment cost is saved.