• Title/Summary/Keyword: beta transform

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Production of Useful Chemicals from Sunflower Oil by Microorganisms

  • El-Sharkawy, Saleh Hassan
    • Natural Product Sciences
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    • v.1 no.1
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    • pp.10-16
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    • 1995
  • A number of microorganisms have been screened for growth on sunflower oil as a sale carbon source for production of useful chemicals. Rhizopus stolonifer NRRL 1478 was found to transform the lipid contents of sunflower oil into dodecyl ${\beta}$-D-glucopyranoside and dodecanedioic acid in 15 and 25% yield respectively. The produced compounds were isolated and purified by column chromatography and its chemical identity were established using MS, IR, $^1H\;and\;^{13}C\;NMR$ spectroscopy.

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Transformation Pathway of the Progesterone by Rhizopus nigricans (Rhizopus nigricans에 의한 Progesterone 전환 반응의 경로)

  • 김명희;김말남
    • Korean Journal of Microbiology
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    • v.29 no.2
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    • pp.111-116
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    • 1991
  • Rhizopus nigricans produces 11.alpha.-hydroxyprogesternoe with a unidentified byproduct, which is hardly separated. Results of chromatography, IR and NMR spectroscopy identified the byproduct to be 11.alpha.-hydroxy-allopregnane-3,20-dione. R. nigricans was found to transform progesternoe into a monoform intermediate, 11.alpha.-hydroxyprogesterone, from which 11.alpha.-hydroxy-allopregnane-3,20-dione and 6.betha., 11.alpha. - dihydroxyprogesterone were formed respectively by 5.alpha.-reduction and 6.betha.-hydroxylation.

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ON PROPERTIES OF QUASI-CLASS A OPERATORS

  • Lee, Jae Won;Jeon, In Ho
    • Korean Journal of Mathematics
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    • v.16 no.3
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    • pp.349-353
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    • 2008
  • Let the set of all quasi-class A operators for which $ker(A){\subseteq}ker(A^*)$ be denoted by $A{\in}{\mathcal{Q}}A^*$. In this paper it is proved that an operator $T{\in}{\mathcal{Q}}A^*$ is normal if and only if the Duggal transform of T is normal.

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GENERALIZATION OF EXTENDED APPELL'S AND LAURICELLA'S HYPERGEOMETRIC FUNCTIONS

  • Khan, N.U.;Ghayasuddin, M.
    • Honam Mathematical Journal
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    • v.37 no.1
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    • pp.113-126
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    • 2015
  • Recently, Liu and Wang generalized Appell's and Lauricella's hypergeometric functions. Motivated by the work of Liu and Wang, the main object of this paper is to present new generalizations of Appell's and Lauricella's hypergeometric functions. Some integral representations, transformation formulae, differential formulae and recurrence relations are obtained for these new generalized Appell's and Lauricella's functions.

The Effect of CTAB on the Citrate Sol-gel Process for the Synthesis of Sodium Beta-Alumina Nano-Powders

  • Wang, Zaihua;Li, Xinjun;Feng, Ziping
    • Bulletin of the Korean Chemical Society
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    • v.32 no.4
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    • pp.1310-1314
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    • 2011
  • Sodium beta-alumina (SBA) nano-powders were synthesized by the citrate sol-gel process, and the effects of the cationic surfactant n-cetyltrimethylammonium bromide surfactant (CTAB) were investigated. The structure and morphology of the nano-powders were characterized by X-ray diffraction (XRD) and transmission electron microscope (TEM) techniques, respectively. The effects of CTAB on the citrate sol-gel process and the SBA formation were investigated by thermo gravimetric/differential thermal analysis (TG/DTA) and Fourier transform infrared spectroscopy (FTIR). The conductivity of ceramic pellets of SBA was measured by electrochemical impedance spectroscopy (EIS). The results showed that the CTAB inhibited the agglomeration of SBA powders effectively and consequently decreased the crystallization temperature of SBA, about $150^{\circ}C$ lower than that of the sample without CTAB. The measured conductivity of SBA was $1.21{\times}10^{-2}S{\cdot}cm^{-1}$ at $300^{\circ}C$.

Characterization of Achlya bisexualis $\beta$-Amylase Expression in an Amylolytic Industrial Strain of Saccharomyces cerevisiae (전분 분해성 산업용 Saccharomyces cerevisiae에서 Achlya bisexualis $\beta$-Amylase의 발현 특성 규명)

  • Lee, Ok-Hee;Lim, Mi-Hyeon;Kim, Ji-Hye;Ryu, Eun-Hye;Ko, Hyun-Mi;Chin, Jong-Eon;Bai, Suk
    • Korean Journal of Microbiology
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    • v.44 no.3
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    • pp.264-269
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    • 2008
  • To develop an amylolytic industrial yeast strain producing $\beta$-amylase, the BAMY gene encoding Achlya bisexualis $\beta$-amylase was constitutively expressed under the control of the alcohol dehydrogenase gene promoter (ADC1p) in an industrial strain of Saccharomyces cerevisiae. Yeast transformation was carried out by an integration system containing $\delta$-sequences as the recombination site. The integrative cassette devoid of bacterial DNA sequences was constructed that contains the BAMY gene and $\delta$-sequences. Industrial S. cerevisiae transformed with this integrative cassette secreted 45 kDa $\beta$-amylase into the culture medium. The $\beta$-amylase activity of the transformant was approximately 18.5-times higher than that of A. bisexualis. The multi-integrated BAMY genes in the transform ant were stable after 100 generations of growth in nonselective medium. Hydrolysis of soluble starch and various starches with the enzyme released maltose but not glucose or oligosaccharides.

Study of Macrophage Activation and Structural Characteristics of Purified Polysaccharides from the Fruiting Body of Hericium erinaceus

  • Lee, Jong-Seok;Min, Kyoung-Min;Cho, Jae-Youl;Hong, Eock-Kee
    • Journal of Microbiology and Biotechnology
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    • v.19 no.9
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    • pp.951-959
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    • 2009
  • Most, if not all, Basidiomycetes mushrooms have biologically active polysaccharides showing potent antitumor activity with immunomodulating properties. These polysaccharides have various chemical compositions and belong primarily to the $\beta$-glucan group. In this study, the crude water-soluble polysaccharide HEF-P, which was obtained from the fruiting body of Hericium erinaceus by hot water extraction and ethanol precipitation, was fractionated by DEAE-cellulose and Sepharose CL-6B column chromatographies. This process resulted in four polysaccharide fractions, named HEF-NP Fr I, HEF-NP Fr II, HEF-AP Fr I, and HEF-AP Fr II. Of these fractions, HEF-AP Fr II was able to upregulate the functional events mediated by activated macrophages, such as production of nitric oxide and expression ofcytokines (IL-1${\beta}$ and TNF-${\alpha}$). The molecular mass of HEF-AP Fr II was estimated by gel filtration to be 13 kDa. Its structural characteristics were investigated by a combination of chemical and instrumental analyses, including methylation, reductive cleavage, acetylation, Fourier transform infrared spectroscopy (FT-IR), and gas chromatography-mass spectrometry (GC-MS). Results indicate that HEF-AP Fr II is a low-molecular-mass polysaccharide with a laminarin-like triple helix conformation of a ${\beta}$-1,3-branched-${\beta}$-1,6-glucan.

Synthesis and characterization of poly(vinyl-alcohol)-poly(β-cyclodextrin) copolymer membranes for aniline extraction

  • Oughlis-Hammache, F.;Skiba, M.;Hallouard, F.;Moulahcene, L.;Kebiche-Senhadji, O.;Benamor, M.;Lahiani-Skiba, M.
    • Membrane and Water Treatment
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    • v.7 no.3
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    • pp.223-240
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    • 2016
  • In this study, poly(vinyl-alcohol) and water insoluble ${\beta}$-cyclodextrin polymer (${\beta}$-CDP) cross-linked with citric acid, have been used as macrocyclic carrier in the preparation of polymer inclusion membranes (PIMs) for aniline (as molecule model) extraction from aqueous media. The obtained membranes were firstly characterized by X-ray diffraction, Fourier transform infrared and water swelling test. The transport of aniline was studied in a two-compartment transport cell under various experimental conditions, such as carrier content in the membranes, stirring rate and initial aniline concentration. The kinetic study was performed and the kinetic parameters were calculated as rate constant (k), permeability coefficient (P) and flux (J). These first results demonstrated the utility of such polymeric membranes for environmental decontamination of toxic organic molecules like aniline. Predictive modeling of transport flux through these materials was then studied using design of experiments; the design chosen was a two level full factorial design $2^k$. An empirical correlation between aniline transport flux and independent variables (Poly ${\beta}$-CD membrane content, agitation speed and initial aniline concentration) was successfully obtained. Statistical analysis showed that initial aniline concentration of the solution was the most important parameter in the study domain. The model revealed the existence of a strong interaction between the Poly ${\beta}$-CD membrane content and the stirring speed of the source solution. The good agreement between the model and the experimental transport data confirms the model's validity.

Studies on the Michael Addition Reaction between Secondary Amino Groups on the Silica Surface with Poly(ethylene glycol) Diacrylates (실리카 나노입자 표면에 결합된 2차 아미노기와 Poly(ethylene glycol) Diacrylate의 마이클 부가반응에 대한 연구)

  • Jeon, Ha Na;Ha, KiRyong
    • Polymer(Korea)
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    • v.36 no.6
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    • pp.822-830
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    • 2012
  • We used dipodal type bis[3-(trimethoxysilyl)propyl]amine (BTMA) silane coupling agent to modify silica nanoparticles to introduce secondary amino groups on the silica surface. These N-H groups were reacted with three different molecular weights (M.W. = 258, 575, and 700) of poly(ethylene glycol) diacrylates to introduce different attached layer thicknesses on the silica surface by Michael addition reaction. After Michael addition reaction, we used several analytical techniques such as fourier transform infrared spectroscopy (FTIR), elemental analysis (EA) and solid state $^{13}C$ cross-polarization magic angle spinning (CP/MAS) nuclear magnetic resonance spectroscopy to characterize introduced structures. We found almost complete Michael addition reaction of both two acrylate groups of PDGDA with N-H groups of BTMA modified silica to form ${\beta}$-amino acid esters. Between equimolar ratio of pure BTMA and pure PEGDA reaction, only one acrylate group of two acrylate groups of PEGDA reacted with N-H groups of pure BTMA to form ${\beta}$-amino acid ester and the other remaining acrylate group can be used to form a polymer later.

Effect of EEG Wave Type of Visual Cortex on Conjugate Movement of Eyeball according to Movement of Visual Target (시 표적의 이동에 따른 안구의 동향운동이 대뇌 시피질의 뇌파에 미치는 영향)

  • Kim, Douk Hoon
    • Journal of Korean Ophthalmic Optics Society
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    • v.7 no.1
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    • pp.51-55
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    • 2002
  • This study was to investigate the effect of EEG wave type of visual cortex on conjugate movement of eyeball according to movement of visual target. Visual evoked potential(VEP) system used the Bio-Pag(production in USA) and recorded to 586 computer. The illumination of test room was 50lux and the visual target was red light dot of 3cm size. The results of dextroversion and levoversion as follows : The visual stimulation waves on the visual cortex have about 71% of delta wave, about 12% of beta wave, about 9% theta wave and about 6% of alpha wave respectively. The dextroversion and levoversion state was similar results on the histogram amplitude of EEG wave, frequency of EEG wave type, EEG wave style and phase diagram of amplitude. Expecially the histogram amplitude of EEG wave appeared almost the Gaussian shape and the phase analysis of amplitude of EEG wave was nearly linear shape. On the fast fourier transform of the amplitude and Hz, the frequency was almost low frequency under 20 Hz, and the dextroversion and levoversion shape was similar results.

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