• Title/Summary/Keyword: batch test

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A Study on the Application of Manganese Oxidizing Bacteria for Manganese Treatment in Acid Mine Drainage (산성광산배수의 망간처리를 위한 MOB 적용에 관한 연구)

  • Lee, Kang Yu;Jang, Min;Park, In Gun;Um, Tae Young;Lim, Kyeong Ho
    • Journal of Korean Society of Environmental Engineers
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    • v.35 no.8
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    • pp.564-570
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    • 2013
  • Domestic treatment facilities for acid mine drainage (AMD) mostly used a passive treatment process. But some passive treatment facility discharged high manganese concentrations because it is required high pH (>9) for abiotic oxidation of Mn(II) to Mn(IV). This study was focused on the feasibility of biological manganese treatment using the manganese-oxidizing bacteria (Pseudomonas sp. MN5) from AMD and economical application method of it. To investigate the various conditions of water quality the most part of the experiments were based on batch test. And result of it showed that maximum manganese oxidation rate were $10.4mg/L{\cdot}h$ at the pH7. We also performed small column tests in which MOB were attached to the functional polyurethane (FPU) media containing alkaline chemicals. Manganese concentration decreased 42 mg/L to below 6 mg/L. But anaerobic condition formed by excessive bacterial respiration in column resulted in increasing effluent manganese concentration.

Evaluation of Removal Characteristics of Taste and Odor Causing Compounds using Meso-Porous Absorbent (메조공극 흡착제를 이용한 상수원수내 맛·냄새 유발물질 제거특성 평가)

  • Kim, Jong-Doo;Park, Chul-Hwi;Yun, Yeo-Bog;Lee, Dae-Sung;Kim, Hyo-Jeon;Kang, Seok-Tae
    • Journal of Korean Society of Environmental Engineers
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    • v.39 no.1
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    • pp.26-33
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    • 2017
  • The objective of this study was to evaluate the characteristic of adsorption by using a meso-porous adsorbent (MPA), and investigate the removal efficiency of geosmin which taste and odor causing compounds in drinking water supplies through batch test. The results for the adsorption isotherm was analyzed by using the Langmuir equation and Freundlich equation, generally being applied. And the study showed that the both Langmuir and Freundlich equation explains the results better. Both of pseudo-first-order model and pseudo-second-order model were respectively applied for evaluation of kinetic sorption property of geosmin onto MPA. The adsorption experiment results using MPA showed that maximum adsorption capacity of MPA was lower 7 times than that of GAC, and adsorption rate of MPA was faster 11 times than that of GAC, on the basis of pseudo-first-order model. Therefore, it was determined that MPA was effectively able to remove geosmin in drinking water supplies in short EBCT condition, but regeneration cycle in MAP process was shorter than that in conventional process.

Influence of Specimen Geometries on the Compressive Strength of Lightweight Aggregate Concrete (경량골재 콘크리트의 압축강도에 대한 시험체 기하학적 특성의 영향)

  • Sim, Jae-Il;Yang, Keun-Hyeok
    • Journal of the Korea Concrete Institute
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    • v.24 no.3
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    • pp.333-340
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    • 2012
  • The current study prepared 9 laboratorial concrete mixes and 3 ready-mixed concrete batches to examine the size and shape effects in compression failure of lightweight aggregate concrete (LWC). The concrete mixes were classified into three groups: normal-weight, all-lightweight and sand-lightweight concrete groups. For each concrete mix, the aspect ratio of circular or square specimens was 1.0 and 2.0. The lateral dimension of specimens varied between 50 and 150 mm for each laboratorial concrete mix, whereas it ranged from 50 to 400 mm with an incremental variation of 50 mm for each ready-mixed concrete batch. Test observations revealed that the crack propagation and width of the localized failure zone developed in lightweight concrete specimens were considerably different than those of normal-weight concrete (NWC). In LWC specimens, the cracks mainly passed through the coarse aggregate particles and the crack distribution performance was very poor. As a result, a stronger size effect was developed in LWC than in NWC. Especially, this trend was more notable in specimens with aspect ratio of 2.0 than in specimens with that of 1.0. The prediction model derived by Kim et al. overestimated the size effect of LWC when lateral dimension of specimen is above 150 mm. On the other hand, the modification factors specified in ASTM and CEB-FIP provisions, which are used to compensate for the shape effect of specimen on compressive strength, were still conservative in LWC.

Removal of Volatile Organic Compounds (VOCs) of Deodorant by Adding a Metal Oxide to the Essential Oils (식물정유물질에 금속산화물을 첨가한 탈취제의 휘발성유기화합물질의 제거에 관한 연구)

  • Lim, You-Young;Lee, Min-Ho;Jeon, Soo-Bin;Yang, Kyeong-Soon;Jeong, Hae-Eun;Oh, Kwang-Joong
    • Clean Technology
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    • v.22 no.2
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    • pp.96-105
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    • 2016
  • VOCs emissions from industries cause the air pollution and odor. In the industrial facilities, the existing odor treatment techniques have limits and problems. In this study, the optimum essential oil and metal oxide selected by screening test. lavender oil, cypress oil and TiO2 were determined by deodorant materials and those were blended by 5%, 45%, 10%, respectively. In addition, the result of batch type experiments depending on the dilution rate, injection, rate, temperature showed that the optimum condition of deodorant is 6 mL of injection rate, and 200 times of dilution rate and the removal efficiency increased in proportion with temperature. In addition, the activation energy was calculated from the rate equation, which appeared in the 3-4 times lower than conventional deodorants.

A study on the denitrification and microbial community characteristics by the change of C/N ratio of molasses and nitrate nitrogen (당밀과 질산성 질소의 C/N ratio 변화에 따른 탈질 및 미생물 군집 특성에 관한 연구)

  • Eom, Hanki;Kim, Sungchul
    • Korean Journal of Microbiology
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    • v.54 no.2
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    • pp.105-112
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    • 2018
  • To compare the denitrification efficiency, this study used molasses and methanol were used as external carbon sources. Specific experimental conditions were classified according to C/N ratio conditions. The batch test showed that the denitrification efficiency increased as C/N ratios of molasses and methanol rose. The most suitable C/N ratio of molasses turned out 4:1 considering the concentration of the residue chemical oxygen demand (COD) and the denitrification efficiency, which was 91.4%. Specific denitrification rate (SDNR) drawn as a kinetic factor demonstrated that molasses and methanol showed similar SDNR values as C/N ratios of molasses and methanol increased. Under the condition of C/N ratio 4:1, 0.0292 g $NO_3{^-}-N$ removal/g mixed liquor volatile suspended solid (MLVSS)/day (molasses), 0.0299 g $NO_3{^-}-N$ removal/g MLVSS/day (methanol) were found. Sludge adapted to molasses showed that Bacterium Pseudomonas sp. and Bergeylla sp. dominated through an analysis of microbial community. In addition, some bacteria were high convergences than the variety of microbial community. Accordingly, it was assumed that molasses focus on growing microorganisms specialized in denitrification and applied as a replaceable external carbon source that can enhance denitrification performance.

Removal of Ionic and Non-ionic Pharmaceuticals Using Granular Activated Carbon (입상활성탄을 이용한 이온성 및 비이온성 의약품의 제거)

  • Oh, Hee-Kyong;Kagawa, Chie;Urase, Taro;Simazaki, Dai;Kunikane, Shoichi
    • Journal of Korean Society of Environmental Engineers
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    • v.28 no.11
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    • pp.1192-1197
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    • 2006
  • Adsorbability of ionic and nonionic pharmaceuticals was studied using granular activated carbon(GAC). In a batch adsorption test of muticomponent solution, 500 mg/L of GAC dose removed all target compounds between 94 and 98% at initial concentration of 10 ${\mu}g/L$. Adsorption of ionic pharmaceuticals increased as pH was lowered toward to pKa, however adsorption capacity of nonionic pharmaceuticals showed insignificant variation with the changing pH. The enhanced adsorption capacity of ionic pharmaceuticals at lower pH was attributed to the corresponding increase in the molecular form of ionic pharmaceuticals with carboxylic group at low pH. In addition, decrease of pH increased hydrogen ion concentration in the bulk solution and the protons bound to the available sites on the carbon enhanced the removal of the ionic pharmaceuticals from solution. After 40 days of continuous operation, GAC column showed the removal of target compounds were removed by $93{\sim}99%$ at 15 min of EBCT mainly due to adsorption mechanism of GAC. At shorter EBCT than 15 min, breakthrough of CA, IBP and GFZ occurred earlier than the other ionic and nonionic pharmaceuticals. effect of EBCT on adsorption of nonionic pharmaceuticals was greater than ionic ones. This study showed that persitent pharmaceuticals found in drinking water treatment could be effectively controlled by adsorption in GAC process.

Methodology Development for the Reuse of Sludge Generated from Fenton's Oxidation Process (펜톤산화 공정에서 발생하는 슬러지의 재활용 방안)

  • Koo, Tai-Wan;Cho, Soon-Haing;Choi, Young-Soo
    • Journal of Korean Society of Environmental Engineers
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    • v.22 no.6
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    • pp.1083-1091
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    • 2000
  • The objective of this study is to develop effective and economical treatment processes for the removal of non-biodegradable organics by reusing the sludge generated from Fenton's Oxidation Process. It was found that about 50% of coagulants and 50% of catalyst can be reduced by reusing the sludge generated from Fenton's Oxidation Process. It was also found that the amount of sludge generation can be reduced in coagulation process and Fenton's Oxidation Process. From the results of bench-scale test, it was found that the average removal efficiency increased to 8.5% and the amount of sludge generation was reduced up to 35% by reusing the sludge as coagulant. The average organic removal efficiency increased to 5.3% and the amount of sludge generation was reduced up to 14% by reusing the sludge as catalyst in Fenton's Oxidation. It can be concluded that the reuse of sludge generated from Fenton's Oxidation Process would be reduced cost of chemical consumption and Fenton's sludge treatment.

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Composite Oxidizing Agents Generation Using Electrolysis of Dilute Hydrochloric Acid (묽은 산 전기분해에 의한 복합 산화제 생성)

  • Kang, Shin-Young;Park, Jong-Hun;Kim, Sang-Hyoun
    • Journal of Korean Society of Environmental Engineers
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    • v.38 no.6
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    • pp.329-333
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    • 2016
  • Disinfection by electrolysis would be useful for small wastewater treatment plant, combined sewer overflow, ballast water, swimming pool, and fish farming, where the transport, storage, and the use of chlorine gas is limited. This study investigated the feasibility of the electrolysis of dilute hydrochloric acid (HCl) for disinfection. The effects of HCl concentration, voltage and reaction time on the generation of oxidizing agents, HOCl, $O_3$, and $H_2O_2$, were examined in a series of batch test. The highest current efficiency was 99.3% which was found at 2.2%, 3 V, and 5 min of HCl concentration, voltage, and reaction time, respectively. Continuous electrolysis at 2.2% HCl, 3 V, and 5 min of the hydraulic retention time showed 97.4% of the current efficiency. Addition of sodium chloride up to 20 g/L linearly increased the oxidizing agents production. 92.2% of total coliforms were removed by the contact with the electrolyzed water.

Investigation of the fate of inorganic nitrogens in the near field of bank filtration site (강둑여과지 주변의 밭에 살포된 무기질소의 거동 연구)

  • 공인철;배진희;안호준;권오억;김승현;이철희;박영규
    • Journal of Korea Soil Environment Society
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    • v.3 no.1
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    • pp.11-20
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    • 1998
  • Inorganic nitrogens resulting from fertilizers are possible contaminants of bank-filtered ground water, which is an alternative source of safe drinking water. We conducted a laboratory study to determine the fate of inorganic nitrogens in the near field of bank filtration sites and we consequently illustrated the effects of these possible contaminants on the water quailty of bank filtration. Soil properties were found to be well equivalent to those of other cultivated field soils in Korea. Surface soil pH was about 4.3 which is slightly lower than average level. Overall, diverse concentrations of $NO_3$-N and $NH_3$-N were measured, and $NO_2$-N was nearly undetected. $NH_3$-N level in the field decreased, while $NO_3$-N increased along with increasing depth of unsaturated zone. Numbers of viable and nitrifying bacteria ranged from 6.73$\times$$10^{6}$to 10.7$\times$$10^{6}$ and 0.44$\times$$10^{4}$ to 5.21$\times$$10^{4}$ respectively, and both of them were highly correlated ($R^{2}$=0.992). Nitrifying potential assayed by batch test showed relatively lower than other reported results. The oxygen uptake potential of surface and subsurface soil was measured in the presence of ${(NH_4)_2}$$SO_4$. The results demonstrated that surface soil required shorter lag period and uptaked more oxygen than subsurface's.

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Design of Counter current Extraction Process for the Separation of [Pr, Nd, Sm]/[La] using Cyanex 572 (Cyanex 572를 사용하여 [Pr, Nd, Sm]/[La]분리에 대한 향류추출공정 설계)

  • Lee, Joo-eun;So, Hong-Il;Jang, In-Hwan;Ahn, Jae-Woo;Kim, Hong-in;Lee, Jin-young
    • Resources Recycling
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    • v.27 no.4
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    • pp.50-56
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    • 2018
  • For the purpose of optimizing the counter current extraction process for separation of [Pr, Nd, Sm] group and [La] in mixed solution using Cyanex 572 as an extractant, the theory of Xu Guangxian was derived for calculating the optimized extraction factors. From the basic batch test result, the separation factor was 16.80 at extraction process and 21.48 at scrubbing process, and the loading capacity of 1.0 M Cyanex 572 was 0.12 M of rare earth element. The process parameters such as the stage number at extraction and scrubbing process, the flow rate ratio of feed and solvent solution can be calculated using an equation of optimum extraction ratio proposed by Xu Guangxian. From the result of calculation, 7 extraction stages and 4 scrubbing stages were required for rare earth separation, and the flow rate ratio of feed solution, solvent solution, scrubbing solution was 25 : 5.67 : 12.27.