• 한국전기전자재료학회:학술대회논문집
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• 한국전기전자재료학회 1997년도 추계학술대회 논문집
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• pp.211-216
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• 1997

ZnO and A1$_2$O$_3$ powders were mixed in 1 : 1 mole ratio and ball-milled with ethanol for 3 h. After the pressing process, the mixtures were sintered at $700^{\circ}C$~130$0^{\circ}C$ for 5 h in air to form ZnA1$_2$O$_4$. Structural properties were analyzed by X-ray diffraction patterns ; optical properties by absorption spectra with UV-VIS-H[R Spectrophotometer ; microstructural properties by SEM ; photoluminescent properties by using PL Measuring System. In result, ZnAl$_2$O$_4$ phosphor is crystallized at 110$0^{\circ}C$ and optical bandgap is calculated at 4.65 eV. PL spectrums were shifted to longer wavelengths with increasing temperature and was appeared around 780nm at 130$0^{\circ}C$ . Additionally, the peak intensity was veil strong at 80$0^{\circ}C$ and was declined with increasing temperature.

• 한국전기전자재료학회논문지
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• 제14권11호
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• pp.904-911
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• 2001

High-density lead zirconate titanate(Pb(Zr$\_$0.53/Ti$\_$0.47/)O$_3$, PZT) ceramics were fabricated by a new milling-precipitation(MP) process improved from the conventional solid state process. This process was progressed by a milling impregnation through mixing ZrO$_2$ and TiO$_2$ powders with lead nitrate(Pb(NO$_3$)$_2$) water solution in zirconia ball media, and then milling precipitation was induced from precipitation of PbC$_2$O$_4$ by adding ammonium of oxalate monohydrate((NH$_4$)$_2$C$_2$O$_4$$.$H$_2$O) as a precipitant. As a result of this process, single-phase perovskite structure was formed at the calcination temperature of 750$\^{C}$ for Pb(Zr$\_$0.53/Ti$\_$0.47/)O$_3$ powders. In addition, the highest density at the sintering temperature of 1100$\^{C}$ was obtained, because of the highly sinterable PZT Powders ground through the re-milling process. Piezoelectric and dielectric properties of sintered sample were improved by MP process.

• 한국전기전자재료학회논문지
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• 제15권1호
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• pp.46-55
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• 2002

10mo1% Gd$_2$O$_3$ doped CeO$_2$ fine powders were synthesized by the oxalate coprecipitation method. The characteristics and sintering behavior of fine powders were investigated. The oxalate precipitates had the specific surface area of 150$m^2$/g, and appeared to be fine and spherical primary particles with a size of approximately 5.5nm. The decomposition of the precipitates occurred from a temperature around 30$0^{\circ}C$ and it was completed below 40$0^{\circ}C$, resulted in the formation of the oxide. The calcination temperature of the fine powders was suitable at 77$0^{\circ}C$. By introducing fine powders washed with alcohol and ball-milling process after calcination, the sintered body was possible to attain the value of 97% of the theoretical density at low temperature of 130$0^{\circ}C$

• 한국전기전자재료학회:학술대회논문집
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• 한국전기전자재료학회 2005년도 하계학술대회 논문집 Vol.6
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• pp.7-8
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• 2005

Silicon(Si) nanowires have been grown by thermal chemical vapor deposition using the 20h ball-milled SiO powders under controlled conditions without the catalyst. For the synthesis of Si nanowires, $Al_2O_3$ substrates were used. Current-Voltage(I-V) and photoresponses were measured for the single Si nanowire in vacuum at room temperature. The light sources for these measurements were the 325 nm wavelength line from a He-Cd laser and the 633 nm wavelength line from a He-Ne laser. The intensity of the photoresponse is independent of the illumination time. And rise and decay times of the photoresponses are shorter than 1 sec.

• 한국표면공학회지
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• 제54권6호
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• pp.357-364
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• 2021

In this study, DLC films deposited by PECVD were evaluated to the properties of super-hydrophobic by CF₄ treatment. The structure of DLC films were confirmed by Raman Spectra whether or not mixed sp³ (like diamond) peak and sp² (like graphite) peak. And the hydrogen contents in the DLC films (F-DLC) were measured by RBS analysis. In addition, DLC films were analyzed by scratch test for adhesion, nano-indentation for hardness and tribo-meter of Ball-on-disc type for friction coefficient. In the result of analysis, DLC films had traditional structure regardless of variation of hardness at constant conditions. Also adhesion of DLC film was increased as higher material hardness. Otherwise, friction coefficient was increased as lower material hardness. The DLC films were treated by CF₄ plasma treatment to enhance the properties of super-hydrophobic. And the DLC films were measured by ESEM(Enviromental Scanning Electron Microscope) for water condensation.

• Corrosion Science and Technology
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• 제21권4호
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• pp.250-257
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• 2022

Transition metal sulfide materials have emerged as a new anode material for Li secondary batteries owing to their high capacity and rate capability facilitated by fast Li-ion transport through the layered structure. Among these materials, niobium disulfide (NbS₂) has attracted much attention with its high electrical conductivity and high theoretical capacity (683 mAh g^-1). In this study, we propose a facile synthesis of Fe_xNbS₂/C composite via simple ball milling and heat treatment. The starting materials of FeS and Nb were reacted in the first milling step and transformed into an Fe-Nb-S composite. In the second milling step, activated carbon was incorporated and the sulfide was crystallized into Fe_xNbS₂ by heat treatment. The prepared materials were characterized by X-ray diffraction, electron spectroscopies, and X-ray photoelectron spectroscopy. The electrochemical test results reveal that the synthesized Fe_xNbS₂/C composite electrode demonstrates a high reversible capacity of more than 600 mAh g^-1, stable cycling stability, and excellent rate performance for Li-ion battery anodes.

• Journal of Electrochemical Science and Technology
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• 제14권1호
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• pp.31-37
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• 2023

Owing to the rapid climate change, a high-performance energy storage system (ESS) for efficient energy consumption has been receiving considerable attention. ESS, such as capacitors, usually has issues with the ion diffusion of electrode materials, resulting in a decrease in their capacitance. Notably, appropriate pore diameter and large specific surface area (SSA) may result in an effective ion diffusion. Therefore, graphene and multi-walled carbon nanotube (graphene@MWCNT) hybrid nanomaterials, with covalent bonds between the graphene and MWCNT, were prepared via an edge-chemistry reaction. The properties of these materials, such as high porosity, large SSA, and high electroconductivity, make them suitable to be used as electrode materials for capacitors. The optimal ratio of graphene to MWCNT can affect the electrochemical performance of the electrode material based on its physical and electrochemical properties. The supercapacitor using optimal graphene-based hybrid electrode material exhibited highest specific capacitance value as 158 F/g and excellent cycle stability.

• Elastomers and Composites
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• 제57권4호
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• pp.157-164
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• 2022

Representative bulletproof materials, such as aramid or ultra-high molecular weight polyethylene(UHMWPE), have excellent strength and modulus in the plane direction but are very vulnerable to forces applied in the thickness direction. This paper reports a study on the effects of reinforcement in the thickness direction when bulletproof composite fabrics are prepared to improve their performance. Aramid and UHMWPE fabrics were combined using the film-bonding, needle-punching, or stitching methods and then subjected to low-velocity projectile and ball-drop impact tests. The results of the low-velocity projectile test indicated that the backface signature(BFS) decreased by up to 29.2% in fabrics obtained via the film-bonding method. However, the weight of the film-bonded fabric increased by approximately 23% compared with that obtained by simple lamination, and the fabric stiffened on account of the binder. Flexibility, light weight for wearability, and excellent bulletproof performance are very important factors in the development of bulletproof materials. When the needle-punching method was used, the BFS increased as the fibers sustained damage by the needle. When the composite fabrics were combined by stitching, no significant difference in weight and thickness was observed, and the BFS showed similar results. When a diagonal stitching pattern was employed, the BFS decreased as the stitching density increased. By contrast, when a diamond stitching pattern was used, the fabric fibers were damaged and the BFS increased as the stitching density increased.

• Journal of Biosystems Engineering
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• 제29권2호
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• pp.151-158
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• 2004

This research was conducted to study the offensive odor adhesion efficiency of filter bed materials using the experimental column that was designed and constructed in this work. The offensive odor adhesion experiment was conducted using mixture of high physical adhesion efficiency material, and the fixity of deodorization microorganism of selected filter bed material was tested using ammonia exclude microorganism A4-2 and sulfur oxidation microorganism S5-5.2 those were cultured at the Agricultural Chemical Department of Chungnam National University, and deodorization efficiency of selected filter bed material mixture was tested. Followings are summary of these tests results. 1) Amount of elimination of the offensive odor gas ammonia and hydrogen sulfide per unit volume were 0.054 and 0.016 $\ell$/㎤ in rice hull, 0.01 and 0.004 $\ell$/㎤ in rice straw, 0.158 and 0.01 $\ell$/㎤ in coconut, 0.014 and 0.02 $\ell$/㎤ in perlite, 0.004 and 0.003 $\ell$/㎤ in high road ball, and 0.112 and 0.015 $\ell$/㎤ chaff of pine, respectively. 2) Amount of elimination of offensive odor gas of ammonia and hydrogen sulfide per unit vloume were 0.079 and 0.016 $\ell$/㎤ in mixture 1, 0.045 and 0.014 $\ell$/㎤ in mixture 2, 0.123 and 0.017 $\ell$/㎤ in mixture 3, 0.055 and 0.016 $\ell$/㎤ in mixture 4, 0.031 and 0.015 $\ell$/㎤ in mixture 5, and 0.111 and 0.020 $\ell$/㎤ in mixture 6, respectively. 3) The offensive odor elimination microoraganism inoculated to the mixture of chaff of pine (70%) and pert (30%) showed the elimination efficiency of 99.06% and 96.61% against the ammonia and hydrongen sulfide, respectively, during 24 hours period.

• 한국재료학회지
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• 제19권7호
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• pp.349-355
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• 2009

Metal thin film patterns on a LTCC substrate, which was connected through inner via and metal paste for electrical signals, were formed by a screen printing process that used electric paste, such as silver and copper, in a conventional method. This method brought about many problems, such as non uniform thickness in printing, large line spaces, and non-clearance. As a result of these problems, it was very difficult to perform fine and high resolution for high frequency signals. In this study, the electric signal patterns were formed with the sputtered metal thin films (Ti, Cu) on an LTCC substrate that was coated with protective oxide layers, such as $TiO_2$ and $SiO_2$. These electric signal patterns' morphology, surface bonding strength, and effect on electro plating were also investigated. After putting a sold ball on the sputtered metal thin films, their adhesion strength on the LTCC substrate was also evaluated. The protective oxide layers were found to play important roles in creating a strong design for electric components and integrating circuit modules in high frequency ranges.