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Electrochemical Characteristics of H Adsorption Sites at the Poly-Pt/LiOH Aqueous Electrolyte Interface (다결정 Pt/LiOH 수성 전해질 계면에서 수소 흡착부위의 전기화학적 특성)

  • Chun Jang Ho;Cho Chong Dug
    • Journal of the Korean Electrochemical Society
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    • v.2 no.4
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    • pp.213-217
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    • 1999
  • The electrochemical characteristics of two distinct adsorption sites of H at the polycrystalline Pt/0.2 M LiOH aqueous electrolyte interface have been studied using the phase-shift method. At the forward and backward scans, the under-potentially deposited H (WD H) peak occurs on the cyclic voltammogram. The transition region on the phase-shift profile or the Langmuir adsorption isotherm occurs at ca. -0.66 to -0.96 V vs. SCE. At the transition region (ca. -0.66 to -0.96 V vs. SCE), the equilibrium constant (K) for H adsorption transits from 18.5 to $4.0\times10^{-5}$ and vice versa. Similarly, the standard free energy $({\Delta}G_{ads})$ of H adsorption transits from -7.2 to 25.1kJ/mol and vice versa. The under and over-potentially deposited H (UPD H and OPD H) on the poly-Pt surface act as two distinguishable electroadsorbed H species. An exothermic reaction occurs at the UPD H range. Both the UPD H peak and the transition region are attributed to the two distinct adsorption sites of the UPD H and OPD H on the poly-Pt surface.

Effect of Interfacial Properties on the Detergency in Dishwashing Agent Composition (식기용 세정제 조성에 있어서 계면물성이 세정력에 미치는 영향)

  • Oh, Hyun-Joo;Lim, Hyo-Seon;Kim, Young-Ho
    • Applied Chemistry for Engineering
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    • v.31 no.2
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    • pp.193-199
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    • 2020
  • The effects of the composition of the dishwashing detergent on interfaces of the oil (O) and the aqueous (W) solution in addition to the cleaning effects of interfacial properties were investigated. Also, the cleaning power of the oil contaminated on the surface of the dish according to each composition and the residuals of the contaminants and the cleaning agent after the washing rinses were evaluated. The removal of contaminated oil on the solid (S) surface in the composition of the cleaning agents used in this study was strongly related to the interfacial properties between the W/O/S, and was particularly dependent on the forward and backward dynamic contact angles. When both contact angles were low at the same time, the permeability of the cleaning solution was so high that the contaminated oil showed a high removal effect. The smaller the interfacial tension of O/W was, the better emulsification of the contaminated oil, the higher the interfacial tension, and the poorer emulsification were achieved. However, the emulsification effect did not significantly affect the cleaning power. In particular, in the case of the cleaner having low interfacial tension, the cleaning material remained on the surface of the solid after washing.

The Influence of Rosemary Oil Inhalation on Memory, Attention and Autonomic Nerve System on the Elderly by Different Concentration (농도별 로즈마리 오일 흡입이 노인의 기억력, 집중력 및 자율신경계 반응에 미치는 영향)

  • Yang, In Suk;Park, Myung Sook
    • Journal of Convergence for Information Technology
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    • v.9 no.3
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    • pp.56-67
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    • 2019
  • The aim of this study was to investigate the influence of rosemary oil inhalation on memory, attention and autonomic nervous system according to the concentration difference in the aged. The research design was non-equivalent control group non-synchronized design. Participants were 89 individuals aged 65 or older who live in the community. Participants inhaled almond carrier oil(control group), 10%(experimental group A) and 100%(experimental group B) rosemary oil. Memory, attention, and autonomic nervous system responses were measured. Data were analyzed by SPSS win 24.0. The differences of the group and time were analyzed through repeated measure ANOVA. There were no significant differences in immediate recall (F=.42, p =.656), delayed recall (F=.45, p=.639), recognition (F=1.45, p=.242), digit span-forward (F=1.53, p=.223), digit span-backward (F=.46, p=.636), activities of sympathetic nerve system (LF)(F=.19, p=.828), activities of parasympathetic nerve system (HF)(F=.37, p=.694), LH/HF(F=1.39, p=.256), systolic blood pressure (F=.37, p=.694), diastolic blood pressure (F=1.25, p=.291). The inhalation of 10% and 100% rosemary oil for five minutes showed no significant effects on memory, attention and automatic nervous system in the aged.

Probability-based Critical Path Estimation for PERT Networks of Repetitive Activities (반복작업 PERT 네트워크의 확률기반 주공정 산정기법)

  • Yi, Kyoo-Jin
    • Journal of the Korea Institute of Building Construction
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    • v.18 no.6
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    • pp.595-602
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    • 2018
  • Network-based scheduling methods can be classified into CPM method and PERT method. In the network scheduling chart, critical path can be estimated by performing the forward calculation and the backward calculation though the paths in the network chart. In PERT method, however, it is unreasonable to simply estimate the critical path by adding the sum of the activity durations in a specific path, since it does not incorporate probabilistic concept of PERT. The critical path of a PERT network can change according to the target period and deviation, and in some cases, the expected time of the critical path may not be the path with longest expected time. Based on this concept, this study proposes a technique to derive the most-likely critical path by comparing the sum of estimated time with the target time. It also proposes a method of systematically deriving all alternate paths for a network of repetitive activities. Case studies demonstrated that the most-likely critical path is not a fixed path and may vary according to the target period and standard deviation. It is expected that the proposed method of project duration forecasting will be useful in construction environment with varying target date situations.

Temporal distritution analysis of design rainfall by significance test of regression coefficients (회귀계수의 유의성 검정방법에 따른 설계강우량 시간분포 분석)

  • Park, Jin Heea;Lee, Jae Joon
    • Journal of Korea Water Resources Association
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    • v.55 no.4
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    • pp.257-266
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    • 2022
  • Inundation damage is increasing every year due to localized heavy rain and an increase of rainfall exceeding the design frequency. Accordingly, the importance of hydraulic structures for flood control and defense is also increasing. The hydraulic structures are designed according to its purpose and performance, and the amount of flood is an important calculation factor. However, in Korea, design rainfall is used as input data for hydrological analysis for the design of hydraulic structures due to the lack of sufficient data and the lack of reliability of observation data. Accurate probability rainfall and its temporal distribution are important factors to estimate the design rainfall. In practice, the regression equation of temporal distribution for the design rainfall is calculated using the cumulative rainfall percentage of Huff's quartile method. In addition, the 6th order polynomial regression equation which shows high overall accuracy, is uniformly used. In this study, the optimized regression equation of temporal distribution is derived using the variable selection method according to the principle of parsimony in statistical modeling. The derived regression equation of temporal distribution is verified through the significance test. As a result of this study, it is most appropriate to derive the regression equation of temporal distribution using the stepwise selection method, which has the advantages of both forward selection and backward elimination.

A 2×2 MIMO Spatial Multiplexing 5G Signal Reception in a 500 km/h High-Speed Vehicle using an Augmented Channel Matrix Generated by a Delay and Doppler Profiler

  • Suguru Kuniyoshi;Rie Saotome;Shiho Oshiro;Tomohisa Wada
    • International Journal of Computer Science & Network Security
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    • v.23 no.10
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    • pp.1-10
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    • 2023
  • This paper proposes a method to extend Inter-Carrier Interference (ICI) canceling Orthogonal Frequency Division Multiplexing (OFDM) receivers for 5G mobile systems to spatial multiplexing 2×2 MIMO (Multiple Input Multiple Output) systems to support high-speed ground transportation services by linear motor cars traveling at 500 km/h. In Japan, linear-motor high-speed ground transportation service is scheduled to begin in 2027. To expand the coverage area of base stations, 5G mobile systems in high-speed moving trains will have multiple base station antennas transmitting the same downlink (DL) signal, forming an expanded cell size along the train rails. 5G terminals in a fast-moving train can cause the forward and backward antenna signals to be Doppler-shifted in opposite directions, so the receiver in the train may have trouble estimating the exact channel transfer function (CTF) for demodulation. A receiver in such high-speed train sees the transmission channel which is composed of multiple Doppler-shifted propagation paths. Then, a loss of sub-carrier orthogonality due to Doppler-spread channels causes ICI. The ICI Canceller is realized by the following three steps. First, using the Demodulation Reference Symbol (DMRS) pilot signals, it analyzes three parameters such as attenuation, relative delay, and Doppler-shift of each multi-path component. Secondly, based on the sets of three parameters, Channel Transfer Function (CTF) of sender sub-carrier number n to receiver sub-carrier number l is generated. In case of n≠l, the CTF corresponds to ICI factor. Thirdly, since ICI factor is obtained, by applying ICI reverse operation by Multi-Tap Equalizer, ICI canceling can be realized. ICI canceling performance has been simulated assuming severe channel condition such as 500 km/h, 8 path reverse Doppler Shift for QPSK, 16QAM, 64QAM and 256QAM modulations. In particular, 2×2MIMO QPSK and 16QAM modulation schemes, BER (Bit Error Rate) improvement was observed when the number of taps in the multi-tap equalizer was set to 31 or more taps, at a moving speed of 500 km/h and in an 8-pass reverse doppler shift environment.

A New Secure Multicast Protocol in Micro-Mobility Environments using Secure Group Key (마이크로 모빌리티 환경에서 보안 그룹키를 이용한 안전한 멀티캐스트 프로토콜)

  • Kang, Ho-Seok;Shim, Young-Chul
    • The KIPS Transactions:PartC
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    • v.15C no.6
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    • pp.573-586
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    • 2008
  • The improved performance and miniaturization of computer and the improvement of wireless communication technology have enabled the emergence of many high quality services. Among them multicast services are receiving much attention and their usage is increasing due to the increase of Internet multimedia services such as video conference, multimedia stream, internet TV, etc. Security plays an important role in mobile multicast services. In this paper, we proposed a secure multicast protocol for a hierarchical micro-mobility environment. The proposed secure multicast protocol provides security services such as authentication, access control, confidentiality and integrity using mechanisms including symmetric/asymmetric key crypto-algorithms and capabilities. To provide forward/backward secrecy and scalability, we used sub-group keys based on the hierarchical micro-mobility environment. With this security services, it is possible to guard against all kinds of security attacks performed by illegal mobile nodes. Attacks executed by internal nodes can be thwarted except those attacks which delete packet or cause network resources to be wasted. We used simulator to measure the performance of proposed protocol. As a result, the simulation showed that effect of these security mechanisms on the multicast protocol was not too high.

Implementation of Intelligent Characters adapting to Action Patterns of Opponent Characters (상대캐릭터의 행동패턴에 적응하는 지능캐릭터의 구현)

  • Lee, Myun-Sub;Cho, Byeong-Heon;Jung, Sung-Hoon;Seong, Yeong-Rak;Oh, Ha-Ryoung
    • Journal of the Institute of Electronics Engineers of Korea TE
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    • v.42 no.3
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    • pp.31-38
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    • 2005
  • This paper proposes an implementation method of intelligent characters that can properly adapt to action patterns of opponent characters in fighting games by using genetic algorithm. For this intelligent characters, past actions patterns of opponent characters should be included in the learning process. To verify the effectiveness of the proposed method, two types of experiments are performed and their results are compared. In first experiment(exp-1), intelligent characters consider current action and its step of an opponent character. In second experiment (exp-2), on the other hands, they take past actions of an opponent characters into account additionally. As a performance index, the ratio of score obtained by an intelligent character to that of an opponent character is adopted. Experimental results shows that even if the performance index of exp-1 is better than that of exp-2 at the beginning of stages, but the performance index of exp-2 outperforms that of exp-1 as stages go on. Moreover, optimum solutions are always found in all experimental cases in exp-2. Futhermore, intelligent characters in exp-2 could learn moving actions (forward and backward) and waiting actions for getting more scores through self evolution.

Influence of Regularization Parameter on Algebraic Reconstruction Technique (대수적 재구성 기법에서 정규화 인자의 영향)

  • Son, Jung Min;Chon, Kwon Su
    • Journal of the Korean Society of Radiology
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    • v.11 no.7
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    • pp.679-685
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    • 2017
  • Computed tomography has widely been used to diagnose patient disease, and patient dose also increase rapidly. To reduce the patient dose by CT, various techniques have been applied. The iterative reconstruction is used in view of image reconstruction. Image quality of the reconstructed section image through algebraic reconstruction technique, one of iterative reconstruction methods, was examined by the normalized root mean square error. The computer program was written with the Visual C++ under the parallel beam geometry, Shepp-Logan head phantom of $512{\times}512$ size, projections of 360, and detector-pixels of 1,024. The forward and backward projection was realized by Joseph method. The minimum NRMS of 0.108 was obtained after 10 iterations in the regularization parameter of 0.09-0.12, and the optimum image was obtained after 8 and 6 iterations for 0.1% and 0.2% noise. Variation of optimum value of the regularization parameter was observed according to the phantom used. If the ART was used in the reconstruction, the optimal value of the regularization parameter should be found in the case-by-case. By finding the optimal regularization parameter in the algebraic reconstruction technique, the reconstruction time can be reduced.

A Deterministic User Optimal Traffic Assignment Model with Route Perception Characteristics of Origins and Destinations for Advanced Traveler Information System (ATIS 체계 구축을 위한 출발지와 도착지의 경로 인지 특성 반영 확정적 사용자 최적통행배정 모형)

  • Shin, Seong-Il;Sohn, Kee-Min;Lee, Chang-Ju
    • The Journal of The Korea Institute of Intelligent Transport Systems
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    • v.7 no.1
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    • pp.10-21
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    • 2008
  • User travel behavior is based on the existence of complete traffic information in deterministic user optimal principle by Wardrop(1952). According to deterministic user optimal principle, users choose the optimal route from origin to destination and they change their routes arbitrarily in order to minimize travel cost. In this principle, users only consider travel time as a factor to take their routes. However, user behavior is not determined by only travel time in actuality. Namely, the models that reflect only travel time as a route choice factor could give irrational travel behavior results. Therefore, the model is necessary that considers various factors including travel time, transportation networks structure and traffic information. In this research, more realistic deterministic optimal traffic assignment model is proposed in the way of route recognizance behavior. This model assumes that when users decide their routes, they consider many factors such as travel time, road condition and traffic information. In addition, route recognizance attributes is reflected in this suggested model by forward searching method and backward searching method with numerical formulas and algorithms.

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