• Fire Science and Engineering
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• v.33 no.5
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• pp.7-12
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• 2019

To investigate the influence of the char layer formed during the combustion process on the pyrolysis of wood combustibles, ISO 5660-1 cone calorimetry experiments and Fire dynamics simulator (FDS) simulations were performed, and the results from these two methods were compared. The wood combustible selected as the fuel for this study, Douglas fir, has been widely used for the production of building materials, furniture, etc. The heat release rate (HRR) measured from the cone calorimetry experiment was in good agreement with the result predicted by the FDS simulation. However, the FDS simulation failed to predict the heat released by the smoldering combustion process, due to the absence of the char surface reaction in the model. The FDS simulation results clearly indicate that the char layer formed on the surface of combustibles produces a thermal barrier which prevents heat transfer to the interior, thickening the thermal depth and thus reducing the pyrolysis rate of combustibles.

• Elastomers and Composites
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• v.46 no.1
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• pp.10-21
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• 2011

Recently, with developments in the automotive industry, sound and vibration damping have a considerable attraction with a diversified customer needs and advanced automobile. In general, among various materials, textile materials, such as felt and glass fibers, polyurethane foam, and PET fiber materials were used to reduce sound and vibration of the automobile. These materials were located in various main parts of the automobile to block sound and vibration, resulting in a comfortable ride. In addition, to improve fuel economy, weight reduction and cost saving for the automobile were also being considered together as well as the reduction of sound and vibration of the automobile. Therefore, in this paper, we focused on the need of interior sound and vibration absorption materials in the automobile and absorption materials-related technologies.

• Journal of Korea Society of Waste Management
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• v.35 no.8
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• pp.692-700
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• 2018

In this study, the results of PBDEs and HBCDs of the products and waste that contain BFRs such as domestic electronic products, automobiles and textile products were compared with international management standards, and their excess rates were calculated. Deca-BDE was detected among the PBDEs in TV rear cover plastics, car seats, automotive interior plastics, and automobile shredding residues of products and waste containing BFRs. The comparison with Basel Convention management standards (1,000 mg/kg) for PBDE-containing wastes (4 types in total) shows that the excess rate of all samples was less than 1.5%. The estimated excess rate compared to the EU and Basel convention management standards (1,000 mg/kg) for PBDEs (4 species + deca-BDE) and TV rear cover plastics was 37.5% (30 of 80 samples exceeded the standards). The estimated excess rate compared to the Basel convention management standards (1,000 mg/kg) for HBCD, building materials products and waste was 15.7% (17 of 108 samples exceeded the standards). In the case of PBDEs, it is necessary to remove only the rear cover of CRT TV among the electric and electronic products and treat it in the flame retardant treatment facility to improve the recycling collection system. In the case of HBCD, it is necessary to appropriately dispose of the recycled materials, heat insulation materials, TV plastics, and styrofoam in marine fishery among construction materials and restrict the use as recycled raw materials.

• Composites Research
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• v.24 no.3
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• pp.1-5
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• 2011

Since the environmental problems and new stricter regulations are forcing the industries to introduce more ecological materials for their products, biodegradable materials have attracted increasing attention. Among these materials, Polylactic acid(PLA) is a promising candidate for its modulus, strength, chemical resistance. However, PLA could not be used for automobile industries for its low heat resistance and impact strength. In this study natural fibers were (jute fiber was) introduced as reinforcements in order to improve heat resistance and impact strength of PLA. Especially for improving the adhesion between PLA and jute, various surface treatments were tried. With each treatment, we verified that the impact strength of composite was improved. With annealing treatment, we found a remarkable increase of heat resistance of PLA composite.

• Elastomers and Composites
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• v.59 no.2
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• pp.51-63
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• 2024

Polypropylene (PP) is a commodity plastic that is widely used owing to its cost-effectiveness, lightweight nature, easy processability, and outstanding chemical and thermomechanical characteristics. However, the imperative to address energy and environmental crises has spurred global initiatives toward a circular economy, necessitating sustainable alternatives to traditional fossil-fuel-derived plastics. In this study, we conducted a series of comparative investigations of bio-based polypropylene (bio-PP) blends with current PP of the same and different grades. An extrusion-based processing methodology was employed for the bio-PP composites. Talc was used as an active filler for the preparation of the composites. A comparative analysis with the current petroleum-based PP indicated that the thermal properties and tensile characteristics of the bio-PP blends and composites remained largely unaltered, signifying the feasibility of bio-PP as a potential substitute for the current PP. To achieve a higher Young's modulus, elongation at break (EAB), and melt flow index (MFI), we prepared different composites of PP of different grades and bio-PP with varying talc contents. Interestingly, at higher biomass contents, the composites exhibited higher MFI and EAB values with comparable Young's moduli. Notably, the impact strengths of the composites with various biomass and talc contents remained unaltered. In-depth investigations through surface analysis confirmed the uniform dispersion of talc within the composite matrix. Furthermore, the moldability of the bio-PP composites was substantiated by comprehensive rheological property assessments encompassing shear rate and shear viscosity. Thus, from these outcomes, the fabricated bio-PP-based composites could be an alternative to petroleum-based PP composites for sustainable automobile applications.

• Journal of the Korea Academia-Industrial cooperation Society
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• v.16 no.8
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• pp.5721-5727
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• 2015

Paint must be resistant to the wear and tear of the atmosphere and should maintain its color and finish for a long time. The solvents of paints were organic solvent and water, common artificial source of VOCs(Volatile organic Solvent) include organic solvent. Using of organic solvent paint was decreased in the interior parts of automotive, exterior parts were still used organic solvent paint. Adhesive strength of water-paint was poor to compare with organic solvent paint and peeled off from the base materials, it was big quality problem. In this study, adhesive characteristics of water-paint and silane mixture was investigated. To improve adhesive strength of water-paint, it was necessary to mixing of adhesive material. Adhesive strength was measured using UTM(Universal Test Instrument) by ASTM D1002 and Peeling off condition was by ASTM D3359. Optimal mixing condition of water-paint and silane adhesive were $25^{\circ}C$, 500rpm, 20min., concentration of silane adhesive was 5 wt%.

• Journal of the Korea Academia-Industrial cooperation Society
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• v.19 no.8
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• pp.562-570
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• 2018

New physical properties of polymer materials were obtained by blending two or three different type of polymers. TPE is used widely in the display, automotive and electronics industries. Consumers have sought emotionally more sensitive and advanced interior automotive parts. A polymer with high foamibility (Ed note: Please check this.) and flowability would be more plausible. TPE composed of foam is a good polymer material to satisfy these trends. In this research, two different TPE were tested, focusing on foamibility and flowability. Two type of TPE were prepared. The first was blended Homo-PP, oil and SEBS. The second was Co-PP, oil and SEBS. The blending temperatures were $180^{\circ}C$, $190^{\circ}C$, and $260^{\circ}C$(second one). The blending speed was 50rpm and blending time was 5 min. The MI of the blended material was affected by the MI of PP and not affected by the blending temperature. The hardness and tensile elasticity were less affected by the MI of PP and blending temperature. The hardness and tensile elasticity were lower at a higher SEBS/Oil content ratio. The soft touch feel was higher with high SEBS/Oil contents. The IPN (Interpenentration polymer network) structure was observed by dissolving the SEBS/Oil layer in xylene. Strain-hardening phenomena also was observed. TPE behaves in a rubber and foamed closed-cell improved its stability.

• Proceedings of the Korean Institute of Surface Engineering Conference
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• 2009.05a
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• pp.111-112
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• 2009

Diamond-like carbon (DLC) is a convenient term to indicate the compositions of the various forms of amorphous carbon (a-C), tetrahedral amorphous carbon (ta-C), hydrogenated amorphous carbon and tetrahedral amorphous carbon (a-C:H and ta-C:H). The a-C film with disordered graphitic ordering, such as soot, chars, glassy carbon, and evaporated a-C, is shown in the lower left hand corner. If the fraction of sp3 bonding reaches a high degree, such an a-C is denoted as tetrahedral amorphous carbon (ta-C), in order to distinguish it from sp2 a-C [2]. Two hydrocarbon polymers, that is, polyethylene (CH2)n and polyacetylene (CH)n, define the limits of the triangle in the right hand corner beyond which interconnecting C-C networks do not form, and only strait-chain molecules are formed. The DLC films, i.e. a-C, ta-C, a-C:H and ta-C:H, have some extreme properties similar to diamond, such as hardness, elastic modulus and chemical inertness. These films are great advantages for many applications. One of the most important applications of the carbon-based films is the coating for magnetic hard disk recording. The second successful application is wear protective and antireflective films for IR windows. The third application is wear protection of bearings and sliding friction parts. The fourth is precision gages for the automotive industry. Recently, exciting ongoing study [1] tries to deposit a carbon-based protective film on engine parts (e.g. engine cylinders and pistons) taking into account not only low friction and wear, but also self lubricating properties. Reduction of the oil consumption is expected. Currently, for an additional application field, the carbon-based films are extensively studied as excellent candidates for biocompatible films on biomedical implants. The carbon-based films consist of carbon, hydrogen and nitrogen, which are biologically harmless as well as the main elements of human body. Some in vitro and limited in vivo studies on the biological effects of carbon-based films have been studied [$2{\sim}5$].The carbon-based films have great potentials in many fields. However, a few technological issues for carbon-based film are still needed to be studied to improve the applicability. Aisenberg and Chabot [3] firstly prepared an amorphous carbon film on substrates remained at room temperature using a beam of carbon ions produced using argon plasma. Spencer et al. [4] had subsequently developed this field. Many deposition techniques for DLC films have been developed to increase the fraction of sp3 bonding in the films. The a-C films have been prepared by a variety of deposition methods such as ion plating, DC or RF sputtering, RF or DC plasma enhanced chemical vapor deposition (PECVD), electron cyclotron resonance chemical vapor deposition (ECR-CVD), ion implantation, ablation, pulsed laser deposition and cathodic arc deposition, from a variety of carbon target or gaseous sources materials [5]. Sputtering is the most common deposition method for a-C film. Deposited films by these plasma methods, such as plasma enhanced chemical vapor deposition (PECVD) [6], are ranged into the interior of the triangle. Application fields of DLC films investigated from papers. Many papers purposed to apply for tribology due to the carbon-based films of low friction and wear resistance. Figure 1 shows the percentage of DLC research interest for application field. The biggest portion is tribology field. It is occupied 57%. Second, biomedical field hold 14%. Nowadays, biomedical field is took notice in many countries and significantly increased the research papers. DLC films actually applied to many industries in 2005 as shown figure 2. The most applied fields are mold and machinery industries. It took over 50%. The automobile industry is more and more increase application parts. In the near future, automobile industry is expected a big market for DLC coating. Figure 1 Research interests of carbon-based filmsFigure 2 Demand ratio of DLC coating for industry in 2005. In this presentation, I will introduce a trend of carbon-based coating research and applications.